公开(公告)号：EP3023419B1

公开(公告)日：2018-01-31

申请号：EP14825786.8

申请日：2014-07-18

申请人： Maruzen Petrochemical Co., Ltd. ,  National Institute of Advanced Industrial Science and Technology

发明人： NANIKI, Takashi ,  HAYASHI, Yasunori ,  SAWADA, Goro ,  FURUKAWA, Takuro ,  HARUNA, Takeshi ,  TAKAHASHI, Toshikazu ,  YASUDA, Hiroyuki ,  YAMAMOTO, Shouji

IPC分类号： C07D317/38 ,  B01J31/02 ,  B01J27/08

CPC分类号： C07D317/38 ,  B01J27/08 ,  B01J31/0231 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J2231/341 ,  B01J2531/90

摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification. A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.

公开(公告)号：EP3023419A1

公开(公告)日：2016-05-25

申请号：EP14825786.8

申请日：2014-07-18

申请人： Maruzen Petrochemical Co., Ltd. ,  National Institute of Advanced Industrial Science and Technology

发明人： NANIKI, Takashi ,  HAYASHI, Yasunori ,  SAWADA, Goro ,  FURUKAWA, Takuro ,  HARUNA, Takeshi ,  TAKAHASHI, Toshikazu ,  YASUDA, Hiroyuki ,  YAMAMOTO, Shouji

IPC分类号： C07D317/38 ,  B01J31/02

CPC分类号： C07D317/38 ,  B01J27/08 ,  B01J31/0231 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J2231/341 ,  B01J2531/90

摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification.
A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.

公开(公告)号：EP2186837B1

公开(公告)日：2014-04-16

申请号：EP08765753.2

申请日：2008-06-19

申请人： Maruzen Petrochemical Co., Ltd.

发明人： YOSHIDA, Norihiro ,  AOKI, Hijiri ,  MITA, Takahito ,  YAMAGUCHI, Ami ,  HABA, Kazuhiko ,  SAWADA, Goro

IPC分类号： C08F297/00 ,  C08F16/14

CPC分类号： C08F297/00 ,  C08F212/14 ,  C08F216/14

公开(公告)号：EP2186837A1

公开(公告)日：2010-05-19

申请号：EP08765753.2

申请日：2008-06-19

申请人： MARUZEN PETROCHEMICAL CO., LTD.

发明人： YOSHIDA, Norihiro ,  AOKI, Hijiri ,  MITA, Takahito ,  KAMADA, Ami ,  HABA, Kazuhiko ,  SAWADA, Goro

IPC分类号： C08F297/00 ,  C08F16/14

CPC分类号： C08F297/00 ,  C08F212/14 ,  C08F216/14

摘要： To provide a novel ABA-type triblock copolymer of vinyl ether series, comprising polyvinyl ether and an oxystyrene-series unit, and a process of producing the ABA-type copolymer at a series of steps. The invention relates to a novel ABA-type triblock copolymer comprising Segment A comprising an oxystyrene-series repeat unit (a) and Segment B comprising a vinyl ether-series repeat unit (b), in which the Segment A and the Segment B are bonded together with a single bond, and to a simple process of producing the same. The triblock copolymer can be produced at a series of steps in a simple manner, comprising living cationic polymerization of a vinyl ether-series monomer such as ethyl vinyl ether in the presence of a bifunctional initiator and a Lewis acid, and subsequently adding an oxystyrene-series monomer such as p-hydroxystyrene for living cationic polymerization.

摘要翻译： 提供包含聚乙烯基醚和氧化苯乙烯系单元的乙烯基醚系列的新型ABA型三嵌段共聚物，以及通过一系列步骤制备ABA型共聚物的方法。 本发明涉及一种新的ABA型三嵌段共聚物，其包含含有氧化苯乙烯系列重复单元（a）的链段A和含有乙烯基醚系列重复单元（b）的链段B，其中链段A和链段B键合 连同一个单键，以及生产该单键的简单过程。 三嵌段共聚物可以通过一系列步骤以简单的方式制备，包括在双官能引发剂和路易斯酸的存在下，乙烯基醚类单体如乙基乙烯基醚的活性阳离子聚合，随后加入氧化苯乙烯 - 系列单体如对羟基苯乙烯用于活性阳离子聚合。