公开(公告)号：EP2140938A1

公开(公告)日：2010-01-06

申请号：EP08739235.3

申请日：2008-03-28

申请人： Meidensha Corporation

发明人： YAMADA, Shinichi ,  YAMADA, Tomohiro ,  OGAWA, Yuji ,  HATAGISHI, Takuya ,  YAMAMOTO, Yo ,  SUGIYAMA, Yoshio

IPC分类号： B01J29/48 ,  B01J37/08 ,  C07C2/76 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07B61/00

CPC分类号： C07C2/76 ,  B01J23/686 ,  B01J29/068 ,  B01J29/076 ,  B01J29/44 ,  B01J29/48 ,  B01J29/7876 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/08 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/32 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/78 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/24 ,  C07C15/08 ,  C07C15/04 ,  C07C15/00

摘要： A catalyst for aromatizing a lower hydrocarbon, in order to increase the amount of production of useful aromatic compounds, such as benzene and toluene, by improving the methane conversion rate, the benzene formation rate, the naphthalene formation rate and the BTX formation rate (or a total formation rate of benzene, toluene and xylene) is such that molybdenum and silver are loaded on a metallosilicate as a substrate. It is more preferable to obtain the aromatizing catalyst by loading molybdenum and silver after modifying a zeolite formed of the metallosilicate with a silane compound that has a molecular diameter larger than a pore diameter of the zeolite and that has an amino group, which selectively reacts at a Bronsted acid point of the zeolite, and a straight-chain hydrocarbon group. When producing a process for producing aromatic compounds, these aromatizing catalysts are reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas.

摘要翻译： 一种用于芳构化低级烃，以提高生产有用的芳族化合物，发色的量催化剂：通过改善甲烷转化率，苯生成速率，评价萘生成和BTX生成速率，如苯和甲苯（或 的苯，甲苯和二甲苯中的总生成速率）正在寻求并钼和银被装载在金属硅酸盐作为底物。 更优选修改与硅烷化合物形成的金属硅酸盐的沸石后以获得由钼和银负载在芳构化催化剂确实具有分子直径比沸石的孔隙直径大，也具有至氨基酸基团，其选择性地反应在 沸石的布朗斯台德酸点，和直链烃基。 当生产用于制备芳族化合物的方法，论文芳构催化剂进行反应与含有低级烃和碳酸气的反应气。