摘要:
An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.
摘要:
The present invention relates to a method for producing lithium fluorosulfonate, which comprises reacting a lithium salt and fluorosulfonic acid in a nonaqueous solvent, wherein the lithium salt is a lithium salt not generating water through the reaction; a lithium fluorosulfonate comprising sulfate ion, in which the molar content of sulfate ion is 1.0 × 10 -5 mol/kg to 2.5 × 10 -1 mol/kg, relative to the weight of a lithium fluorosulfonate; the use of a lithium fluorosulfonate in a nonaqueous electrolytic solution, wherein the molar content of sulfate ion is 1.0 × 10 -5 mol/kg or more to 2.5 × 10 -1 mol/kg or less, relative to the weight of a lithium fluorosulfonate; and a nonaqueous electrolytic solution comprising: lithium fluorosulfonate; and halide ion except fluoride ion in an amount of from 1.0 × 10 -7 mol/L to 1.0 × 10 -3 mol/L.
摘要:
The present invention relates to a method for producing lithium fluorosulfonate, which comprises reacting a lithium salt and fluorosulfonic acid in a nonaqueous solvent, wherein the lithium salt is a lithium salt not generating water through the reaction; a lithium fluorosulfonate comprising sulfate ion, in which the molar content of sulfate ion is 1.0 × 10 -5 mol/kg to 2.5 × 10 -1 mol/kg, relative to the weight of a lithium fluorosulfonate; the use of a lithium fluorosulfonate in a nonaqueous electrolytic solution, wherein the molar content of sulfate ion is 1.0 × 10 -5 mol/kg or more to 2.5 × 10 -1 mol/kg or less, relative to the weight of a lithium fluorosulfonate; and a nonaqueous electrolytic solution comprising: lithium fluorosulfonate; and halide ion except fluoride ion in an amount of from 1.0 × 10 -7 mol/L to 1.0 × 10 -3 mol/L.
摘要:
The present invention relates to a nonaqueous electrolyte mainly comprising an electrolyte and a nonaqueous solvent dissolving the electrolyte, the nonaqueous electrolyte comprising: a monofluorophosphate and/or a difluorophosphate; and further at least one compound selected from the group consisting of compounds represented by the following general formula (1), nitrile compounds, isocyanate compounds, phosphazene compounds, disulfonic acid ester compounds, sulfide compounds, disulfide compounds, acid anhydrides, lactone compounds having a substituent in the α-position, and compounds having a carbon-carbon triple bond:
[wherein R 1 , R 2 , and R 3 each independently represent a fluorine atom, an alkyl group which has 1-12 carbon atoms and may be substituted with a fluorine atom, or an alkoxy group which has 1-12 carbon atoms and may be substituted with a fluorine atom].
摘要:
The present invention relates to a nonaqueous electrolytic solution secondary battery in which a positive electrode and a negative electrode capable of occluding and releasing lithium ion, and a nonaqueous electrolytic solution are sealed in an outer packaging case; wherein the nonaqueous electrolytic solution contains lithium fluorosulfonate and sulfate ion, the molar content of the sulfate ion in the nonaqueous electrolytic solution is from 1.0 × 10 -7 mol/L to 1.0 × 10 -2 mol/L, and the outer packaging case is a laminate film.
摘要:
An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.
摘要:
The present invention relates to a nonaqueous electrolyte mainly comprising an electrolyte and a nonaqueous solvent dissolving the electrolyte, the nonaqueous electrolyte comprising: a monofluorophosphate and/or a difluorophosphate; and further at least one compound selected from the group consisting of compounds represented by the following general formula (1), nitrile compounds, isocyanate compounds, phosphazene compounds, disulfonic acid ester compounds, sulfide compounds, disulfide compounds, acid anhydrides, lactone compounds having a substituent in the α-position, and compounds having a carbon-carbon triple bond:
[wherein R 1 , R 2 , and R 3 each independently represent a fluorine atom, an alkyl group which has 1-12 carbon atoms and may be substituted with a fluorine atom, or an alkoxy group which has 1-12 carbon atoms and may be substituted with a fluorine atom].
摘要翻译:本发明涉及一种非水电解质主要包含电解质和非水溶剂的电解质,所述电解质包含非水溶解:difluorophosphates单氟磷酸盐和/或; 并进一步选自由下述通式(1),腈化合物,异氰酸酯化合物,磷腈化合物,二磺酸酯化合物,硫醚化合物,二硫化物化合物,酸酐表示的化合物中选择的至少一种化合物内酯具有化合物 取代基在±位置,和具有碳 - 碳三键的化合物:[worin R 1,R 2和R 3各自独立地表示氟原子,烷基具有1-12个碳原子的并且具有可以是与取代 氟原子,或其中有1至12个碳原子和可以被氟原子substituiertem]烷氧基。