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公开(公告)号：EP2963161B1
公开(公告)日：2017-06-21
申请号：EP14757202.8
申请日：2014-02-26
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2.发明公开GLOSSY PILLING-RESISTANT ACRYLIC FIBER, METHOD FOR PRODUCING SAME, AND SPUN YARN AND KNITTED FABRIC INCLUDING SAID ACRYLIC FIBER 审中-公开光泽抗压腈纶纤维，其生产方法及包括所述丙烯酸纤维在内的棉纱和针织织物
公开(公告)号：EP3187629A1
公开(公告)日：2017-07-05
申请号：EP15837071.8
申请日：2015-08-25
IPC分类号： D01F6/18
CPC分类号： D01F6/18 , D04B21/00 , D10B2321/10 , D10B2401/20
摘要： The present invention provides: an acrylic fiber having a fineness of 0.5 to 3.5 dtex and having excellent gloss, pilling resistance, and texture; a method for producing said acrylic fiber; and a spun yarn and a knitted fabric containing said acrylic fiber. Provided is an acrylic fiber having a filament fineness of 0.5 to 3.5 dtex, wherein the product K of the value of knot strength (cN/dtex) and the value of knot elongation (%) is from 8 to 30 inclusive, and the number of recesses having a depth of 0.1 µm or greater is 10 or fewer. In this method for producing said acrylic fiber, an acrylonitrile-based copolymer containing 92 to 96.8 mass% of an acrylonitrile unit, 2 to 6 mass% of a vinyl-based monomer unit, and 0.2 to 2.0 mass% of a sulfonic acid group-containing vinyl monomer unit is dissolved in an organic solvent, to prepare a spinning dope. A coagulated fiber bundle is formed by discharging the spinning dope from discharge holes into a coagulation bath having a solvent concentration of 40 to 60 mass% and a temperature of 35 to 50 °C. The coagulated fiber bundle is drawn in hot water at a draw ratio of 2 to 3.8 times, an oil agent is applied, the fiber bundle is dried, and then the fiber bundle is drawn under dry heat at a draw ratio of 1.2 to 3 times.
The product S of said draw ratio in hot water and said draw ratio under dry heat is from 4 to 6 times. Further, the fiber bundle is subjected to a thermal relaxation treatment.摘要翻译： 本发明提供：纤度为0.5〜3.5分特，且具有优异的光泽，耐起球性和质感的丙烯酸类纤维， 一种生产所述丙烯酸纤维的方法; 以及包含所述丙烯酸纤维的细纱和针织物。 本发明提供细度为0.5〜3.5分特的丙烯酸系纤维，其中，结节强度（cN / dtex）和结节伸长率（％）的值为8以上且30以下， 深度为0.1μm以上的凹部为10个以下。 在该制造上述丙烯酸系纤维的方法中，使用丙烯腈系单体92〜96.8质量％，乙烯系单体单元2〜6质量％，磺酸基单体0.2〜2.0质量％ 将含乙烯基单体单元溶解在有机溶剂中，制备纺丝原液。 将纺丝原液从排出孔排出到溶剂浓度为40〜60质量％，温度为35〜50℃的凝固浴中，形成凝固纤维束。 将凝固的纤维束以2〜3.8倍的拉伸倍率在热水中拉伸，涂布油剂，将纤维束干燥后，以1.2〜3倍的拉伸倍率在干热下拉伸纤维束 。 所述热水拉伸比S和所述干热拉伸比S乘以4至6倍。 此外，纤维束经受热松弛处理。
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3.发明公开ACRYLIC FIBERS, METHOD FOR MANUFACTURING SAME, AND SPUN YARN AND KNITTED FABRIC USING SAID FIBERS 审中-公开丙烯酸纤维，其制造方法及纺纱和针织面料所述纤维
公开(公告)号：EP3138940A1
公开(公告)日：2017-03-08
申请号：EP15786320.0
申请日：2015-04-28
CPC分类号： D01F8/08 , D01D1/02 , D01D5/06 , D01D5/32 , D02G1/004 , D02G3/045 , D02J1/22 , D02J1/228 , D04B1/20 , D10B2401/046 , D10B2401/061 , D10B2401/16
摘要： Provided are: acrylic fibers having 2-7% boiling water shrinkage and formed by the side-by-side conjugation of a copolymer A, which contains 5-10 mass% of an unsaturated monomer that can form a copolymer with acrylonitrile units, and a copolymer B, which contains 2-5 mass% of unsaturated monomer units that can form a copolymer with acrylonitrile units and 0.2-1.5 mass% of sulfonic acid group-containing monomer units; a method for manufacturing said fibers; a spun yarn containing said fibers; and a knitted fabric obtained from said spun yarn. The single fiber fineness of the heat-treated acrylic fibers is 1.7-6.6 dtex, the bulkiness is at least 380 cm3/g, the percentage of crimp is at least 15%, and the product (DKSDKE) of the knot strength (cN/dtex) and the knot elongation (%) is 10-25. The acrylic fibers have excellent crimp characteristics and anti-pilling properties.
摘要翻译： 本发明提供：具有2-7％的沸水收缩率的丙烯酸纤维和由侧由端缀合的共聚物A的，其中含有5-10％的不饱和单体的质量也可以形成与丙烯腈单元的共聚物形成，并且 共聚物B，其含有2-5％的不饱和单体单元的质量也可形成具有丙烯腈单元和含磺酸基的单体单元的0.2-1.5质量％的共聚物; 用于制造所述纤维的方法; 细纱含有所述纤维; 和从所述获得的针织物细纱。 经热处理的丙烯酸类纤维的单纤维纤度是分特1.7-6.6，膨松度是至少380立方厘米/ g时，卷曲的百分比是至少15％，该产品的结节强度（DKSDKE）（CN / 分特）和结节伸长（％）为10-25。 所述丙烯酸类纤维具有优异的卷曲特性和抗起球性能。
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4.发明公开SPINNING NOZZLE, PROCESS FOR PRODUCING FIBROUS MASS, FIBROUS MASS, AND PAPER 有权SPINNDÜSEUND VERFAHREN ZUR HERSTELLUNG VON FASERBUNDEN
公开(公告)号：EP2963161A1
公开(公告)日：2016-01-06
申请号：EP14757202.8
申请日：2014-02-26
摘要： A spinning nozzle (1) which has a perforated part (2) in which ejection holes (3) have been arranged in a density as high as 600-1,200 holes/mm 2 . This process for producing a fibrous bundle comprises ejecting a spinning dope having a viscosity as measured at 50°C of 30-200 P from the ejection holes (3) of the spinning nozzle (1) to produce a fibrous bundle. This fibrous bundle has a single-fiber fineness of 0.005-0.01 dtex. By the wet-process direct spinning, a mass of nanofibers which are stably uniform and continuous can be produced at a high efficiency.
摘要翻译： 一种具有多孔部分（2）的纺丝喷嘴（1），其中排出孔（3）的密度高达600-1200个孔/ mm 2。 制造纤维束的方法包括从纺丝喷嘴（1）的喷孔（3）喷出在50℃下测得的粘度为30〜200p的纺丝原液，制成纤维束。 该纤维束的单纤维细度为0.005-0.01分特。 通过湿式直接纺丝，可以高效率地制造稳定均匀且连续的纳米纤维。
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