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    BRIDGED METALLOCENE COMPOUND, OLEFIN POLYMERIZATION CATALYST USING THE COMPOUND AND ETHYLENE POLYMER OBTAINED BY USING THE CATALYST
    4.
    发明公开
    BRIDGED METALLOCENE COMPOUND, OLEFIN POLYMERIZATION CATALYST USING THE COMPOUND AND ETHYLENE POLYMER OBTAINED BY USING THE CATALYST 有权
    烯烃基的桥连金属茂化合物和使用该催化剂GOT乙烯聚合物

    公开(公告)号：EP2218725A1

    公开(公告)日：2010-08-18

    申请号：EP08851276.9

    申请日：2008-11-19

    申请人： Mitsui Chemicals, Inc. ,  Prime Polymer Co., Ltd.

    发明人： BANDO, Hideki ,  SATOH, Yasuo ,  YUKITA, Takashi ,  HARADA, Yasuyuki ,  SONOBE, Yoshiho ,  TOHI, Yasushi ,  SEKIOKA, Yusuke ,  SUZUKI, Masao ,  TANIFUJI, Daisuke

    IPC分类号： C07F17/00 ,  C08F4/6592 ,  C07F7/00 ,  C07F7/08

    CPC分类号： C08F4/65927 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/11 ,  C08F2500/10 ,  C08F2500/24 ,  C08F210/14 ,  C08F210/08

    摘要： Metallocene compounds of the invention are useful as olefin polymerization catalysts or catalyst components. Olefin polymerization processes of the invention involve an olefin polymerization catalyst containing the metallocene compound. In detail, the olef in polymerization catalysts can catalyze with high polymerization activity the production of olefin polymers having high melt tension, excellent mechanical strength and good particle properties, and the olefin polymerization processes involve the catalysts. Ethylene polymers according to the invention are obtained by the polymerization processes and have higher processability and easy-opening properties and particularly excellent mechanical strength compared to conventional ethylene polymers. Thermoplastic resin compositions of the invention contain the ethylene polymers. In more detail, shaped articles or films are obtained from the ethylene polymers or the thermoplastic resin compositions containing the ethylene polymers, and laminate films include the films.
    According to the invention, a single or plural kinds of bridged metallocene compounds having differing cyclopentadienyl-derived groups afford macromonomers that are a source of long-chain branches and simultaneously catalyze the repolymerization of the macromonomers into olefin polymers having a large number of long-chain branches, small neck-in in the T-die extrusion, small take-up surge and superior mechanical strength. The olefin polymerization catalysts and the polymerization processes can efficiently produce the olefin polymers.

    摘要翻译： 本发明的金属茂化合物可用作烯烃聚合催化剂或催化剂组分是有用的。 本发明的烯烃聚合方法涉及烯烃聚合催化剂含有金属茂化合物。 详细地，在聚合催化剂的烯烃类能以高聚合活性催化生产具有高熔体张力，优异的机械强度和良好的颗粒性能的烯烃聚合物，以及烯烃聚合方法涉及催化剂。 乙烯聚合物gemäß到本发明的是通过聚合方法得到的，并具有较高的可加工性和易开封性和相对于传统的乙烯聚合物特别优异的机械强度。 本发明的热塑性树脂组合物含有乙烯聚合物。 更详细地，成型制品或膜被从乙烯聚合物或含乙烯聚合物的热塑性树脂组合物获得的，和层压膜包括膜。 。根据本发明，单一的或多种具有不同的环戊二烯基衍生的基团桥连的金属茂化合物的得到的大分子单体确实是长链分支的源极，同时催化大分子单体的再聚合成具有大量长链的烯烃聚合物 分支，小颈缩在T形模头挤出，小卷取浪涌和优异的机械强度。 的烯烃聚合催化剂和聚合方法可以有效地生产烯烃聚合物。

    METHOD FOR PREVENTING FOULING IN CHEMICAL EQUIPMENT AND FOULING INHIBITOR
    5.
    发明公开
    METHOD FOR PREVENTING FOULING IN CHEMICAL EQUIPMENT AND FOULING INHIBITOR 审中-公开
    化学品中的VERFAHREN ZURFÄULNISVERHINDERUNGGERÄTENUNDFÄULNISHEMMER

    公开(公告)号：EP2415787A1

    公开(公告)日：2012-02-08

    申请号：EP10758840.2

    申请日：2010-03-31

    申请人： Mitsui Chemicals, Inc.

    发明人： NAGAI, Naoshi ,  NAKATSUKA, Shiro ,  NAKAI, Kazuoki ,  SUGIMURA, Kenji ,  TOHI, Yasushi ,  YOSHITSUGU, Ken ,  BANDO, Hideki ,  HARADA, Yasuyuki

    IPC分类号： C08F2/00 ,  C08F10/00 ,  C08G65/329 ,  C10G75/04

    CPC分类号： C08G65/329 ,  C08F210/16 ,  C08G2261/126 ,  C08L71/02 ,  C08L2205/05 ,  C10G75/04 ,  C10G2300/1088 ,  C10G2300/4075 ,  C10G2400/22 ,  C08F2/005 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08L23/00

    摘要： The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer represented by the general formula (1) or the general formula (13) and having Mn of 30,000 or less to a component in the chemical equipment: (A: a group to which C 2 -C 20 olefins are polymerized; R 1 , R 2 , R 101 , and R 102 : H or a C 1 -C 18 alkyl group; X 1 and X 2 : a group represented by the general formula (2) or the general formula (4); E, E 101 , and E 112 : O or S; X 3 , X 7 , and X 8 : polyalkylene glycol group; R 3 : a hydrocarbon group; G: -OX 4 or -NX 5 X 6 (X 4 , X 5 , and X 6 : a polyalkylene glycol group); m: 1-10; A 101 : a group to which C 2 -C 20 olefms are polymerized; X 101 and X 102 : one represents a hydrogen atom or a group represented by the general formula (14) or the general formula (15), and the other represents a group represented by the general formula (16); R 104 : H, a hydrocarbon group, or an acyl group; R 105 and R 106 : hydrocarbon groups; and X 104 : a polyalkylene glycol group).

    摘要翻译： 本发明提供了一种防止化学设备中的结垢的方法，包括向化学品中的组分添加包含由通式（1）或通式（13）表示的Mn为30,000以下的Mn为30,000以下的聚氧化烯聚合物的防污剂 设备：（A：C 2 -C 20烯烃聚合的基团; R 1，R 2，R 101和R 102：H或C 1 -C 18烷基; X 1和X 2：一个基团 由通式（2）或通式（4）表示; E，E 101和E 112：O或S; X 3，X 7和X 8：聚亚烷基二醇基; R 3：烃基; G：-OX 4或-NX 5 X 6（X 4，X 5和X 6：聚亚烷基二醇基）; m：1-10; A 101：C 2 -C 20烯烃聚合的基团; X 101和X 102：一个表示氢原子或由通式（14）或通式（15）表示的基团，另一个表示由通式（16）表示的基团; R 104：H， 烃基或ac 基团 R 105和R 106：烃基; 和X 104：聚亚烷基二醇基团）。