公开(公告)号：EP1826223A1

公开(公告)日：2007-08-29

申请号：EP05795878.7

申请日：2005-10-20

申请人： Mitsui Chemicals Polyurethanes, Inc.

发明人： KUNIHIRO, Tamotsu ,  MATSUMOTO, Shinsuke ,  IWA, Tsuyoshi

IPC分类号： C08F283/06 ,  C08G18/63 ,  C09J151/06

CPC分类号： C08G18/26 ,  C08F283/06 ,  C08G18/10 ,  C08G18/6229 ,  C08G18/632 ,  C08G18/638 ,  C09J175/04 ,  C08G18/40

摘要： A polyether polyol grafted with hydroxyl group-containing (meth)acrylate related to the present invention has an ester group represented by formula (1) below in the molecule.

(In the formula, R 1 represents a hydrogen atom or a methyl group, and R 2 is an alkylene group having 1 to 18 carbon atoms.) This polyether polyol is suitably used as a raw material for polyurethane resin cured products excellent in mechanical strength and weather resistance.

摘要翻译： 接枝有本发明的含羟基的（甲基）丙烯酸酯的聚醚多元醇在分子中具有由下式（1）表示的酯基。 （式中，R 1表示氢原子或甲基，R 2表示碳原子数1〜18的亚烷基。）该聚醚多元醇适合用作机械强度优异的聚氨酯树脂固化物的原料 和耐候性。

公开(公告)号：EP1939231A1

公开(公告)日：2008-07-02

申请号：EP06797134.1

申请日：2006-08-31

申请人： Mitsui Chemicals Polyurethanes, Inc.

发明人： KUNIHIRO, Tamotsu ,  MATSUMOTO, Shinsuke ,  IWA, Tsuyoshi ,  MURAYAMA, Kouichi

IPC分类号： C08F283/06 ,  C08G18/63 ,  C09J151/08

CPC分类号： C08G18/632 ,  C08F283/06 ,  C08G18/638

摘要： A (meth)acrylate-grafted polyether polyol produced by reacting 40 to 95 parts by weight of a polyoxyalkylene polyol and 5 to 60 parts by weight of a vinyl monomer, both relative to 100 parts by weight of the sum total of the polyoxyalkylene polyol and the vinyl monomer, and 0.1 to 5 moles of an alkyl peroxide as a radical initiator per mole of the hydroxyl group in the polyoxyalkylene polyol, wherein the polyoxyalkylene polyol has a hydroxyl number of 25 mg KOH/g or less, and the vinyl monomer contains a (meth)acrylate and/or a hydroxyl-containing (meth)acrylate in an amount of 50% by weight or higher. The (meth)acrylate-grafted polyether polyol is excellent in colorless-transparency, compatibility, mechanical strength, weather resistance, and blending resistance, and therefore is useful as a raw material for a polyurethane resin cured article.

摘要翻译： 通过使40〜95重量份的聚氧化烯多元醇与5〜60重量份的乙烯基单体反应而制造的（甲基）丙烯酸酯接枝聚醚多元醇，相对于100重量份的聚氧化烯多元醇和 乙烯基单体和0.1〜5摩尔作为自由基引发剂的烷基过氧化物，相对于聚氧化烯多元醇中的每摩尔羟基，其中聚氧化烯多元醇的羟值为25mgKOH / g以下，乙烯基单体含有 （甲基）丙烯酸酯和/或含羟基的（甲基）丙烯酸酯的量为50重量％以上。 （甲基）丙烯酸酯接枝聚醚多元醇的无色透明性，相容性，机械强度，耐候性和混合阻力优异，因此可用作聚氨酯树脂固化物的原料。