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1.发明授权Method for inhibiting corrosion of iron and mild steel in contact with industrial waters by using hydroxamic acid containing polymers as corrosion inhibitors 失效通过使用含有聚合物作为腐蚀抑制剂的异羟肟酸铁和软钢在与工业用水接触的Korrosioninhibierung的方法
公开(公告)号：EP0526786B1
公开(公告)日：1997-10-22
申请号：EP92112244.6
申请日：1992-07-17
IPC分类号： C23F11/173 , C02F5/12
CPC分类号： C02F5/12 , C23F11/10 , C23F11/173
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2.发明公开Tagged polymers and their synthesis by post polymerization (trans) amidation reaction 失效标签聚合物及其通过聚合（转移）氨化反应合成
公开(公告)号：EP0475602A3
公开(公告)日：1992-07-01
申请号：EP91307591.7
申请日：1991-08-16
发明人： Fong, Dodd W. , Hoots, John E.
摘要： Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation derivatization, and polymers having pendant (sulfonated) napthalene moieties substituted to amide nitrogen are provided, with mer units of the Formula V :
wherein R 4 is C n H 2n and n is zero or an integer of from 1 to about 10, R 1 , R 2 and R 3 are independently hydrogen or a substituent other than hydrogen, wherein one of X 1 and X 2 is hydrogen and the other is an (alkylene) naphthalene having from 0 to 2 sulfonic acid substituents or salts thereof, or wherein X 1 and X 2 contain, separately or together, at least one organic fluorescent group.-
3.发明授权
公开(公告)号：EP0475602B1
公开(公告)日：1996-05-29
申请号：EP91307591.7
申请日：1991-08-16
发明人： Fong, Dodd W. , Hoots, John E.
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4.发明授权Method of producing sulfomethyl polyacrylamide polymers and sulfomethylamide unit containing polymers 失效制备含有聚丙烯酰胺聚合物的磺酰基聚酰胺和含有聚酰胺的磺酰胺单元的方法
公开(公告)号：EP0225596B1
公开(公告)日：1991-07-24
申请号：EP86116788.0
申请日：1986-12-03
发明人： Fong, Dodd W. , Kowalski, David J.
CPC分类号： C08F8/34 , C08F2800/10 , C08F8/44 , C08F20/56
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5.发明公开Cooling water corrosion inhibition composition 失效Korrosionsinhibierende ZusammensetzungenfürKühlwasser。
公开(公告)号：EP0244584A2
公开(公告)日：1987-11-11
申请号：EP87103070.6
申请日：1987-03-04
IPC分类号： C23F11/08
CPC分类号： C09D133/24 , C09D5/08 , C09D135/00 , C23F11/08 , C23F11/173
摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows:
where R. is hydrogen or methyl,
where R, is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-co-and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows:
where R,, R 2 and R 3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms, and substituted alkyl of from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide. (poly)carboxy and (poly)-hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.摘要翻译： 一种抑制工业冷却水中腐蚀的方法，其含有硬度和pH至少为6.5，通过用包含能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐和含有 具有如下酰胺结构的N-取代丙烯酰胺聚合物：其中R 2为氢或甲基的CHEM，其中R 1为氢或烷基，R为亚烷基或亚苯基，X为磺酸酯，（聚）羟基，（聚） 羧基或羰基，及其组合; 或含有具有N-取代马来酰胺酸单元，N-取代的马来酰亚胺单元和具有以下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物和三元共聚物：其中R 1，R 2和R 3各自独立地为 选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和1至10个碳原子的取代烷基，其中取代基是膦酸; 次膦酸 磷酸酯; 磺酸 硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。
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6.发明公开Sulfobetaine-containing polymers and their utility as calcium carbonate scale inhibitors 失效Sulfobetaine enthaltende Polymere und ihre Verwendung zum Inhibieren von Calcium Carbonatkesselstein
公开(公告)号：EP0832854A1
公开(公告)日：1998-04-01
申请号：EP97115195.6
申请日：1997-09-02
CPC分类号： C08G73/0611 , C02F5/12
摘要： The invention is a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of an N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine of the formula:
wherein R is selected from the group consisting of alkyl and aryl groups, and R 1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups,
and an anionic monomer.
The invention is also a method of inhibiting the precipitation and deposition of scale on metal surfaces in contact with industrial cooling waters comprising the addition of an effective, scale-inhibiting amount of a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of a betaine of the formula:
wherein R is selected from the group consisting of alkyl and aryl groups, and R 1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups,
and an anionic monomer.
A preferred polymer is a water-soluble copolymer of N,N-diallyl-N-methyl-N-(2-sulfoethyl) ammonium betaine and acrylic acid.摘要翻译： 本发明是一种水溶性N，N-二烯丙基-N-烷基-N-（磺基烷基）铵甜菜碱共聚物，其中所述共聚物是由N，N-二烯丙基-N-烷基-N-（ 磺基烷基）铵甜菜碱，其结构式为：CHEM，其中R选自烷基和芳基，R 1选自烷基，芳基和烷基芳基，和阴离子单体。 本发明还是一种抑制与工业冷却水接触的金属表面沉淀和沉积的方法，包括加入有效的阻垢量的水溶性N，N-二烯丙基-N-烷基-N - （磺基烷基）铵甜菜碱含量的共聚物，其中所述共聚物由下式的甜菜碱的聚合形成：其中R选自烷基和芳基，R 1选自由以下组成的组： 烷基，芳基和烷芳基，以及阴离子单体。 优选的聚合物是N，N-二烯丙基-N-甲基-N-（2-磺乙基）铵甜菜碱和丙烯酸的水溶性共聚物。
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7.发明授权Phosphinic acid-containing polymers and their use in preventing scale and corrosion 失效和次膦聚合物及其用途用于抑制结垢和腐蚀含酸
公开(公告)号：EP0517470B1
公开(公告)日：1996-04-24
申请号：EP92305023.1
申请日：1992-06-02
IPC分类号： C23F11/173 , C02F5/14 , C08F8/40
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8.发明公开Tagged polymers and their synthesis by post-polymerization (trans)amidation reaction 失效通过后聚合酰氨选择的聚合物和合成。
公开(公告)号：EP0657474A3
公开(公告)日：1995-08-02
申请号：EP95102339.9
申请日：1991-08-16
发明人： Fong, Dodd W. , Hoots, John E.
IPC分类号： C08F8/00
摘要： Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation derivatization, with a fluorescent composition of the Formula III
wherein one of R 5 and R 6 may be hydrogen and within one of R 5 and R 6 , or within R 5 and R 6 taken together, there is an organic fluorescent group, in the presence of a formaldehyde-bisulfite post-polymerization derivatization agent.-
9.发明公开Tagged polymers and their synthesis by post-polymerization (trans)amidation reaction 失效Markierte Polymere und Synthese durch Nach-Polymerisation-Transamidierung。
公开(公告)号：EP0657474A2
公开(公告)日：1995-06-14
申请号：EP95102339.9
申请日：1991-08-16
发明人： Fong, Dodd W. , Hoots, John E.
IPC分类号： C08F8/00
摘要： Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation derivatization, with a fluorescent composition of the Formula III
wherein one of R 5 and R 6 may be hydrogen and within one of R 5 and R 6 , or within R 5 and R 6 taken together, there is an organic fluorescent group, in the presence of a formaldehyde-bisulfite post-polymerization derivatization agent.摘要翻译： 用荧光基团标记的聚合物通过具有羰基型侧基的先前存在的聚合物的（反式）酰胺化衍生化来制备。 具有侧酰胺基团的聚合物，其中酰胺氮被荧光部分取代，通过（反式）酰胺化衍生化制备，其具有式III
的荧光组合物，其中R 5和R 6中的一个可以是氢并且在一个R5和R6 或在R5和R6中一起存在的情况下，存在有机荧光基团，在甲醛 - 亚硫酸氢盐后聚合衍生化试剂存在下。 -
10.发明授权Method for inhibiting calcium carbonate scale by using sulfobetaine-containing polymers 失效一种用于通过使用含磺基甜菜碱聚合物的抑制碳酸钙水垢方法
公开(公告)号：EP0832854B1
公开(公告)日：2001-12-12
申请号：EP97115195.6
申请日：1997-09-02
CPC分类号： C08G73/0611 , C02F5/12
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