公开(公告)号：EP2676729A4

公开(公告)日：2014-12-24

申请号：EP12747413

申请日：2012-02-15

Applicant: NAT INST OF ADVANCED IND SCIEN

Inventor： SAYAMA KAZUHIRO ,  KONISHI YOSHINARI

IPC: B01J35/02 ,  A61L9/00 ,  A61L9/01 ,  B01D53/86 ,  B01J23/85 ,  B01J23/89 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J23/34 ,  B01D53/8668 ,  B01D2255/2045 ,  B01D2255/206 ,  B01D2255/2063 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/20792 ,  B01D2257/708 ,  B01J23/30 ,  B01J23/31 ,  B01J23/888 ,  B01J23/8993 ,  B01J35/004 ,  B01J37/0201 ,  B01J37/088 ,  C11D3/0063 ,  C11D3/1213 ,  C23C18/1216

Abstract: To provide a novel visible light-responsive photocatalyst or tungsten oxide visible light-responsive semiconductor improved in environmental resistance under an alkaline condition. The tungsten oxide visible light-responsive semiconductor unstable under an alkaline condition is improved in environmental resistance without losing photocatalytic function thereof by adding thereto at least one element selected from the group consisting of copper, tantalum, niobium, lanthanum, bismuth, calcium, chromium, manganese and zinc. The obtained environmental resistant visible light-responsive photocatalyst is subjected to an alkaline treatment to thereby be improved in photocatalytic activity.

公开(公告)号：EP1339129A4

公开(公告)日：2006-10-25

申请号：EP01999017

申请日：2001-11-28

Applicant: NAT INST OF ADVANCED IND SCIEN

Inventor： HARA KOHJIROU ,  SAYAMA KAZUHIRO ,  ARAKAWA HIRONORI ,  SUGA SADAHARU ,  SHINPO AKIRA ,  OOGA YASUYO ,  KUSANO HAJIME

IPC: H01L31/04 ,  H01L51/00 ,  H01G9/20 ,  H01L51/30 ,  H01L51/42 ,  H01M14/00

CPC classification number: H01L51/0073 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0064 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549

Abstract: Disclosed are semiconductor thin film electrodes made by using specific organic dyes as the photosensitizer, high-efficiency dye-sensitized photoelectric conversion devices made by using the electrodes, and dye-sensitized photoelectrochemical solar cells made by using the devices. The thin film electrodes are characterized by being made of a semiconductor sensitized with an organic dye represented by the general formula (1): (1) wherein Z is an optionally substituted heterocyclic group; L is an electron-attracting group; R1 to R3 are each hydrogen or a substituent, or any adjacent two of R1 to R3 may be united to form a cyclic structure; M is hydrogen or a salt-forming cation; and n is an integer of 0 to 3.

Abstract translation: 使用特定的有机染料敏化剂，使用该电极的高效率的染料敏化光电转换元件，以及使用该元件的染料敏化光电化学太阳能电池的半导体薄膜电极进行说明。 半导体膜电极通过包含与有机染料具有由下式表示的结构敏化的半导体表征（1）： worinŽdarstellt的杂环基团，其可以具有取代基，吸电子基团L的darstellt，R1 3. -R3各自表示采取组合的氢原子或取代基或两个相邻的R1-R3来代表一个环中，M darstellt氢原子或一个成盐阳离子，并且n为0至