公开(公告)号：EP2184104A1

公开(公告)日：2010-05-12

申请号：EP07832125.4

申请日：2007-11-19

申请人： NATIONAL UNIVERSITY CORPORATION OITA UNIVERSITY

发明人： NAGAOKA, Katutoshi ,  TAKITA, Yuusaku ,  SATOU, Katutoshi ,  NISHIGUTI, Hiroyasu

IPC分类号： B01J23/76 ,  B01J23/63 ,  C01B3/38 ,  H01M8/06

CPC分类号： B01J37/0201 ,  B01J23/63 ,  B01J23/83 ,  C01B3/40 ,  C01B3/46 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0844 ,  C01B2203/1082 ,  H01M8/0612 ,  Y02P20/52

摘要： The drive of direct-heat-supply type reforming of hydrocarbon at ordinary temperature is necessary in order to realize a self-sustaining, on-site reforming type fuel cell system which does not necessitate the supply of energy from the outside. According to the invention, an oxide, CeO 2 or Pr 6 O 11 , or a Ce/Zr or Ce/Zr/Y double oxide is used as the oxide containing a rare earth element capable of changing the oxidation number with an active metal and oxygen defects are introduced into the oxide or double oxide by activating the oxide or double oxide with a reducing gas at high temperature. When a reaction gas containing hydrocarbon and oxygen is passed though the catalyst at low temperature, the oxygen defects react with oxygen and thereby return to the original oxide. Since this return reaction is an exothermic reaction, the catalyst itself is heated, which acts as the driving force for advancing the combustion of the hydrocarbon, whereby the catalyst layer is further heated and the reforming is advanced to from hydrogen. Thus, the hydrogen-producing reaction can be driven even at low temperature, particularly ordinary temperature.

摘要翻译： 直接供热型在常温下的烃的重整的驱动器是必要的，以便实现自持，现场重整型燃料电池系统，该系统不必要的能量从外面供给。 。根据本发明，或氧化物的CeO 2镨6 O 11，或铈/锆或Ce / Zr的/ Y双氧化物被用作包含能够在活性金属与改变氧化数的稀土元素氧化物和 氧缺陷被引入到在高温下激活所述氧化物或双氧化物与还原气体的氧化物或双氧化物。 当含有烃和氧的反应气体通过但在低温下的催化剂中，氧缺陷与氧反应，从而返回到原来的氧化物。 由于该返回反应是氢的放热反应，该催化剂本身被加热，其中作为用于推进烃的燃烧，由此所述催化剂层被加热，并且进一步重整前进到从驱动力作用。 因此，制氢反应甚至可以在低温下，特别是常温下被驱动。