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公开(公告)号：EP0413469A2
公开(公告)日：1991-02-20
申请号：EP90308486.1
申请日：1990-08-01
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6388 , C08F4/6386
摘要： Polyolefins having better particle properties are obtained by polymerizing olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the said solid catalyst component being prepared by reacting the following components [I] and [II] and further reacting the resulting reaction product with the following component [III]:
[I] a reaction product obtained by reacting:
(1) a silicon oxide and/or an aluminum oxide, and
(2) a titanium compound, or a titanium compound and a vanadium compound, and further reacting the resulting reaction product with:
(3) an organoaluminum compound;
[II] a reaction product obtained by the reaction of:
(1) a magnesium halide, and
(2) a compound represented by the general formula Me(OR) n X z-n wherein Me represents an element of Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0
[III] a compound represented by the general formula Si(OR) m X 4-m wherein R is a hydrocarbon residue having 1 to 20 carbon atoms, X is a halogen atom, and m is 0 ≦ m ≦ 4.摘要翻译： 通过在包含固体催化剂组分和有机金属化合物的催化剂存在下聚合烯烃，获得具有更好颗粒性质的聚烯烃，所述固体催化剂组分通过使下列组分[I]和[II]反应并进一步使所得产物 （1）氧化硅和/或氧化铝，和（2）钛化合物，或钛化合物和钒化合物反应得到的反应产物，所述反应产物与下列组分[III]反应：[I] 并进一步使得到的反应产物与以下物质反应：（3）有机铝化合物; [II]由以下物质反应得到的反应产物：（1）卤化镁，和（2）由通式Me（OR）nXz-n表示的化合物，其中Me代表周期表第I至IV族的元素 表中，z表示元素Me的化合价，n为0
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公开(公告)号：EP0407143A2
公开(公告)日：1991-01-09
申请号：EP90307261.9
申请日：1990-07-03
CPC分类号： C08F10/00 , C08F2410/03 , C08F4/6385 , C08F4/6376
摘要： Polyolefin is prepared by using a catalyst comprising a solid catalyst component and an organometallic compound, the said solid catalyst component being prepared by the reaction of the following components [I] and [II] :
[I] a reaction product obtained by reacting:
(1) a silicon oxide and/or an aluminum oxide, and
(2) a titanium compound, or a titanium compound and a vanadium compound, and further reacting the resulting reaction product with:
(3) an organoaluminum compound; and
[II] a reaction product obtained by the reaction of:
(1) a magnesium halide,
(2) a compound represented by the general formula Me(OR) n X z-n wherein Me represents an element of I to IV in the Periodic Table, z represents the valence of the element Me, n is o
(3) a titanium compound, or a titanium compound and a canadium compound.摘要翻译： 通过使用包含固体催化剂组分和有机金属化合物的催化剂制备聚烯烃，所述固体催化剂组分通过以下组分[I]和[II]的反应制备：[I]通过以下反应获得的反应产物：（ 1）氧化硅和/或氧化铝，和（2）钛化合物或钛化合物和钒化合物，并进一步使所得反应产物与（3）有机铝化合物反应; 通过以下反应获得的反应产物：（1）卤化镁，（2）由通式Me（OR）n Xz-n表示的化合物，其中Me表示周期表中I至IV的元素 ，z表示元素Me的化合价，n为o
化合物。 一世 -
公开(公告)号：EP0407143B1
公开(公告)日：1994-10-12
申请号：EP90307261.9
申请日：1990-07-03
CPC分类号： C08F10/00 , C08F2410/03 , C08F4/6385 , C08F4/6376
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公开(公告)号：EP0407143A3
公开(公告)日：1991-11-06
申请号：EP90307261.9
申请日：1990-07-03
CPC分类号： C08F10/00 , C08F2410/03 , C08F4/6385 , C08F4/6376
摘要： Polyolefin is prepared by using a catalyst comprising a solid catalyst component and an organometallic compound, the said solid catalyst component being prepared by the reaction of the following components [I] and [II] :
[I] a reaction product obtained by reacting:
(1) a silicon oxide and/or an aluminum oxide, and (2) a titanium compound, or a titanium compound and a vanadium compound, and further reacting the resulting reaction product with: (3) an organoaluminum compound; and [II] a reaction product obtained by the reaction of:
(1) a magnesium halide, (2) a compound represented by the general formula Me(OR) n X z-n wherein Me represents an element of I to IV in the Periodic Table, z represents the valence of the element Me, n is o (3) a titanium compound, or a titanium compound and a canadium compound.摘要翻译： 通过使用包含固体催化剂组分和有机金属化合物的催化剂来制备聚烯烃，所述固体催化剂组分通过以下组分[I]和[II]的反应制备：[I]通过使 1）氧化硅和/或氧化铝，和（2）钛化合物或钛化合物和钒化合物，并进一步使得到的反应产物与以下物质反应：（3）有机铝化合物; 和[II]通过以下反应获得的反应产物：（1）卤化镁，（2）由通式Me（OR）nXz-n表示的化合物，其中Me代表元素周期表中的I至IV z表示元素Me的化合价，n为o
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公开(公告)号：EP0413469B1
公开(公告)日：1995-06-21
申请号：EP90308486.1
申请日：1990-08-01
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6388 , C08F4/6386
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公开(公告)号：EP0413469A3
公开(公告)日：1991-11-13
申请号：EP90308486.1
申请日：1990-08-01
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6388 , C08F4/6386
摘要： Polyolefins having better particle properties are obtained by polymerizing olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the said solid catalyst component being prepared by reacting the following components [I] and [II] and further reacting the resulting reaction product with the following component [III]:
[I] a reaction product obtained by reacting:
(1) a silicon oxide and/or an aluminum oxide, and (2) a titanium compound, or a titanium compound and a vanadium compound, and further reacting the resulting reaction product with: (3) an organoaluminum compound; [II] a reaction product obtained by the reaction of:
(1) a magnesium halide, and (2) a compound represented by the general formula Me(OR) n X z-n wherein Me represents an element of Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0 [III] a compound represented by the general formula Si(OR) m X 4-m wherein R is a hydrocarbon residue having 1 to 20 carbon atoms, X is a halogen atom, and m is 0 ≦ m ≦ 4.
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