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1.
公开(公告)号:EP4371934A1
公开(公告)日:2024-05-22
申请号:EP21949806.0
申请日:2021-07-30
发明人: ZHANG, Zhibing , ZHOU, Zheng , TIAN, Hongzhou , LI, Lei , ZHANG, Feng , MENG, Weimin , WANG, Baorong , YANG, Gaodong , LUO, Huaxun , YANG, Guoqiang , CAO, Yu
IPC分类号: C01B15/023 , B01J8/00
摘要: The invention provides a micro-interface enhanced oxidation system and an oxidation method for preparing hydrogen peroxide, wherein the micro-interface enhanced oxidation system includes: an oxidation reactor, wherein a top portion of a side surface of the oxidation reactor is provided with a liquid phase pipeline for delivering hydrogenated anthraquinone, and a bottom portion of the side surface of the oxidation reactor is provided with a gas phase pipeline for delivering air; and a liquid distributor, a packing section, a seal pan and a hybrid micro-interface unit that are arranged in order from top to bottom are arranged in the oxidation reactor, wherein the hybrid micro-interface unit comprises a upper-mounted micro-interface generator and a lower-mounted micro-interface generator that are communicated with each other up and down, and the hydrogenated anthraquinone delivered in goes down in turn until being mixed with the air in the hybrid micro- interfacial unit to be dispersed and crushed after being distributed through the liquid distributor. By adopting the micro-interface enhanced oxidation system of the present invention, the utilization rate of oxygen can be improved, and the occupied area is small, and the operation is simple.
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2.
公开(公告)号:EP4431939A1
公开(公告)日:2024-09-18
申请号:EP22888879.8
申请日:2022-07-01
发明人: ZHANG, Zhibing , ZHOU, Zheng , ZHANG, Feng , LI, Lei , TIAN, Hongzhou , WEI, Gelin , LU, Wenjun , LI, Xiabing , LI, Yongqiang
IPC分类号: G01N33/00 , C01B15/023
CPC分类号: B01J10/002 , C01B15/023
摘要: The invention provides an evaluation method for micro-bubble strengthening in a hydrogen peroxide system prepared by anthraquinone method, including the following steps: (a) establishing an oxidation reaction equation; (b) constructing a macroscopic reaction kinetic equation of reaction gas; (c) constructing a mathematical expression of an oxygen reaction enhancement factor EB; (d) constructing the calculation method of the concentration of each reaction components in the liquid phase, and calculating the concentration of each reaction component in the liquid phase. The present invention discusses the influence of bubble size on gas-liquid phase interface area, volume mass transfer coefficient and macroscopic reaction rate by constructing a structure-effect controlled mathematical model of a hydrogen peroxide oxidation reaction system prepared by anthraquinone method and evaluates the strengthening effect of micro-interface oxidation reaction. It provides a basis for the design and operation of micro-interface reaction strengthening reactors. The reactor designed by the evaluation method of the present invention can solve the problem of uneven gas-liquid distribution and enhance mass transfer at the same time, thereby maximizing the space-time yield and realizing the micro-interface economics of reaction strengthening technology.
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公开(公告)号:EP4393589A1
公开(公告)日:2024-07-03
申请号:EP21962105.9
申请日:2021-11-16
发明人: ZHANG, Zhibing , HU, Xingbang , YAO, Chenfei , ZHOU, Zheng , LI, Lei
CPC分类号: Y02P20/584
摘要: Provided in the present invention is an iridium-based catalyst, which is characterized in that the chemical structural formula of the iridium-based catalyst is:
wherein Ph is a phenyl, R is a methyl or an ethyl, and X is one or more of CH3CO2, NO3, Cl, BF4, PF6 and SbF6. In the present invention, a rhodium-based catalyst in the prior art is replaced with the iridium-based catalyst, such that the reaction cost is reduced, and the yield of reactants is increased.-
公开(公告)号:EP4432292A1
公开(公告)日:2024-09-18
申请号:EP22871088.5
申请日:2022-07-01
发明人: ZHANG, Zhibing , ZHOU, Zheng , ZHANG, Feng , LI, Lei , TIAN, Hongzhou , WEI, Gelin , LU, Wenjun , LI, Xiabing , LI, Yongqiang
摘要: The invention provides an evaluation method for a strengthening degree of a micro-interface reaction of propylene hydro-formylation to produce butyraldehyde, comprising the following steps: (A) establishing an expression of a reaction rate of propylene hydro-formylation; (B) constructing a macroscopic reaction kinetics equation of a reaction gas; (C) establishing a mathematical expression of a reaction enhancement factor; (D) calculating a concentration of each reaction component in a liquid phase. The invention aims at realizing the economy of the micro-interface reaction strengthening technology, and improves the space-time yield to the greatest extent by determining the evaluation method of the oxidation reaction micro-interface reaction strengthening, which is beneficial to optimize the design and operation of the butyraldehyde synthesis reactor.
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公开(公告)号:EP4424661A1
公开(公告)日:2024-09-04
申请号:EP21962104.2
申请日:2021-11-16
发明人: HU, Xingbang , ZHANG, Zhibing , YAO, Chenfei , LI, Lei , ZHOU, Zheng
摘要: The present invention discloses a method for catalyzing olefin carbonylation, including the following steps: using cyclic alkylcarbene iridium as a catalyst and an olefin as a raw material to carry out carbonylation reaction to generate aldehydes, wherein a structural formula of the cyclic alkylcarbene iridium is as follows:
wherein Dipp is 2,6-diisopropylbenzene; R1 and R2 are methyl or ethyl; X is Cl, Br, CH3CO2, NO3, BF4, PF6 or SbF6; wherein the olefin comprises one or more of ethylene, propylene, butylene and higher carbon olefins. According to the method for catalyzing olefin carbonylation of the present invention, by adopting an iridium catalyst, the catalytic activity is good, reaction energy consumption is reduced, and reaction temperature is fully lowered.
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