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1.发明公开
公开(公告)号：EP2069298A1
公开(公告)日：2009-06-17
申请号：EP07818425.6
申请日：2007-09-20
发明人： MINISCI, Francesco , PORTA, Ombretta , RECUPERO, Francesco , PUNTA, Carlo , GAMBAROTTI, Cristian , PIERINI, Monica
IPC分类号： C07C407/00 , C07C29/09
CPC分类号： C07C409/10 , C07C37/08 , C07C407/00 , Y02P20/52 , C07C39/04
摘要： The invention relates to a process for the preparation of phenol which comprises the aerobic oxidation of cumene to hydroperoxide with high conversions and selectivities, in the presence of new catalytic systems, extremely mild conditions and the subsequent acid decomposition of the hydroperoxide to phenol and acetone.
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2.发明公开CATALYTIC PROCESS FOR THE PREPARATION OF HYDROPEROXIDES OF ALKYLBENZENES BY AEROBIC OXIDATION UNDER MILD CONDITIONS 审中-公开催化方法使用有氧氧化温和条件下ALKYLBENZOLHYDROPEROXIDEN PRODUCING
公开(公告)号：EP2257525A1
公开(公告)日：2010-12-08
申请号：EP09723524.6
申请日：2009-03-13
发明人： MINISCI, Francesco , PUNTA, Carlo , RECUPERO, Francesco , GAMBAROTTI, Cristian , SPACCINI, Raffaele
IPC分类号： C07C407/00 , C07C409/08
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkyibenzene reacts with oxygen in the presence of a catalytic system consisting of an N-hydroxyimide associated with a peroxide activator having a peracid or dioxyrane structure, possibly generated in situ.
摘要翻译： 由烷基苯与氧在催化系统，由与具有过酸或dioxyrane结构的过氧化物活化剂关联的N- hydroximides的的存在下反应的特点factthat烷基苯的氢过氧化物的制备方法，原位可能生成。
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3.发明公开PROCESS FOR THE PRODUCTION OF ALKYLBENZENE HYDROPEROXIDES UNDER MILD CONDITIONS AND IN THE PRESENCE OF NEW CATALYTIC SYSTEMS 审中-公开用于生产ALKYLBENZOLHYDROPEROXIDEN在温和条件下以及在新的催化系统PRESENCE
公开(公告)号：EP2265577A1
公开(公告)日：2010-12-29
申请号：EP09721827.5
申请日：2009-03-13
发明人： MINISCI, Francesco , PUNTA, Carlo , RECUPERO, Francesco , GAMBAROTTI, Cristian , SPACCINI, Raffaele
IPC分类号： C07C407/00 , C07C409/08
CPC分类号： C07C409/08 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C2601/18 , C07C2601/20
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkylbenzene reacts with oxygen in the presence of a catalytic system which includes an N-hydroxyimide or an N-hydroxysulfamide and a polar solvent.
摘要翻译： 由factthat烷基苯特点烷基苯的氢过氧化物的制备方法与在催化系统，该系统包括N hydroximides或N- hydroxysulfamide和极性溶剂的存在下的氧反应。
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公开(公告)号：EP2448889A1
公开(公告)日：2012-05-09
申请号：EP10748132.7
申请日：2010-06-23
发明人： BENCINI, Elena , GAMBAROTTI, Cristian , MELONE, Lucio , PASTORI, Nadia , PROSPERINI, Simona , PUNTA, Carlo , RECUPERO, Francesco
IPC分类号： C07C2/66 , C07C2/74 , C07C37/08 , C07C39/04 , C07C13/28 , C07C49/403 , C07C45/53 , C07C409/16
CPC分类号： C07C2/66 , C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403
摘要： Process for the preparation of phenol and cyclohexanone which comprises : a. the synthesis of cyclohexylbenzene by the hydro- alkylation of benzene by contact with hydrogen or the alkylation of benzene with cyclohexene using Y zeolites; b. the selective aerobic oxidation of cyclohexylbenzene to the corresponding hydroperoxide catalyzed by N- hydroxy-derivatives in the presence of polar solvents; and c. the scission of the hydroperoxide of cyclohexylbenzene to phenol and cyclohexanone by homogeneous or heterogeneous acid catalysts; characterized in that the synthesis of cyclohexylbenzene takes place in the presence of a catalytic system comprising a Y zeolite and an inorganic ligand wherein the Y zeolite has a crystalline structure with openings consisting of (12) tetrahedra and the inorganic ligand is γ-alumina, and wherein said catalytic composition is characterized by a pore volume, obtained by adding the mesoporosity and macroporosity fractions, greater than or equal to 0.7 cm /g, wherein at least 30% of said volume consists of pores with a diameter greater than 100 nanometers.
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