公开(公告)号：EP2924046A4

公开(公告)日：2016-07-13

申请号：EP13856069

申请日：2013-11-20

申请人： RIKEN

发明人： HOU ZHAOMIN ,  SHIMA TAKANORI ,  HU SHAOWEI ,  ENDO YOSHINORI

IPC分类号： C07F17/00 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C01C1/02 ,  C07F7/00 ,  C07F7/28

CPC分类号： C07F7/28 ,  B01J8/02 ,  B01J31/1805 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2208/00805 ,  B01J2231/62 ,  B01J2531/0222 ,  B01J2531/46 ,  C01C1/0411 ,  C07F7/00 ,  C07F7/006 ,  C07F9/00 ,  C07F9/5022 ,  C07F9/5045 ,  C07F11/005 ,  C07F17/00 ,  Y02P20/52

摘要： A novel complex capable of fixing dinitrogen and use thereof are provided. A complex represented by formula (1A) or (1B) or a cationic or anionic complex from the complex: wherein M1 to M4 (M1 to M3 in the case of formula (1A)) are each independently Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, or W, and L1 to L4 (L1 to L3 in the case of formula (1A)) are each independently a ligand selected from among a ligand (Cp) including a substituted or unsubstituted cyclopentadienyl derivative, a diphenylamine ligand, a diphenylphosphine ligand, and a carboimideamide ligand.