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1.发明公开Capacitor having an electrolyte containing a mixture of dinitriles 失效Kondensator mit Elektrolyt，der ein Gemisch von Dinitrilenenthält
公开(公告)号：EP0694935A1
公开(公告)日：1996-01-31
申请号：EP95102348.0
申请日：1995-02-20
IPC分类号： H01G9/038
摘要： An electrical capacitor includes an organic electrolyte to provide high power, high energy density, and a broad operating temperature range. The capacitor includes electrodes and an electrolyte system comprising a salt combined with a solvent containing a nitrile. The electrolyte system is selected to be relatively nonreactive and difficult to oxidize or reduce so as to produce a high electric potential range. As examples, the electrolyte may include a solvent selected from the group consisting of acetonitrile, succinonitrile, glutaronitrile, propylene carbonate, and ethylene carbonate; a salt cation selected from the group consisting of tetraalkylammonium (R₄N⁺) and alkali metals; and an anion selected from the group consisting of trifluoromethylsulfonate (CF₃SO₃⁻), bistrifluoromethylsulfurylimide (N(CF₃SO₂)₂⁻), tristrifluoromethylsulfurylcarbanion (C(CF₃SO₂)₃⁻), tetrafluoroborate (BF₄⁻), hexafluorophosphate (PF₆⁻), hexafluoroarsenate (AsF₆⁻), and perchlorate (ClO₄⁻).
摘要翻译： 电容器包括由电解液分离的一对电极，该电极包括盐和溶剂。 琥珀腈与第二丁腈混合以形成液体。 在室温 还要求的是：（a）上述电容器，其中至少一个电极具有氧化物层; 和（b）电化学双层电容器，其中至少一个电极包括选自碳泡沫，碳纤维，碳复合材料，金属填充复合材料，金属和导电金属氧化物的材料。
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公开(公告)号：EP0774889A1
公开(公告)日：1997-05-21
申请号：EP96112962.4
申请日：1996-08-12
IPC分类号： H05K3/20
CPC分类号： C25D7/123 , C25D5/024 , C25D7/0635 , H05K3/205
摘要： A photoelectrochemical method and apparatus are disclosed for fabricating electronic circuits. An electroplating solution (12) is applied to the surface of a reverse biased p-type semiconductor material (16), such as NiO. The solution-covered (14) NiO surface (16) is illuminated with a light beam (20) directed by computer aided design data to photoelectrochemically deposit a seed layer of metal in an electronic circuit pattern. The seed layer may be thickened by further deposition in a plating bath (24) to form metallic circuit traces on the NiO (16). If desired, the metallic circuitry may be transferred from the NiO (16) to an alternate substrate having a low dielectric constant. The porosity of the NiO surface (16) can be adjusted to optimize the metallic circuit adhesion for image retention or ease of transfer. The metallic traces may also be treated to reduce adhesion of subsequently deposited metal that can be transferred readily. If sufficient residual metal remains on the NiO surface (16) after circuit transfer, the trace can be rethickened to transfer multiple circuits of the same pattern without reimaging. An old metallic image can be electro-dissolved by changing the bias of the NiO with respect to the plating bath, thereby erasing the old image so that a new circuit pattern can be formed by photoelectrochemical deposition. The process can be performed on a rotating cylinder (18) so that electronic circuits can be produced in a continuous process of photoelectrochemical deposition, seed metal thickening, adhesion reduction, circuit transfer, and image erasure that provides advantages in cost, circuit resolution, and environmental protection.
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公开(公告)号：EP0389879B1
公开(公告)日：1995-03-01
申请号：EP90104941.1
申请日：1990-03-15
IPC分类号： G02F1/35 , C07C335/02 , C07D213/89 , C07F3/06
CPC分类号： G02F1/3619
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公开(公告)号：EP0389879A3
公开(公告)日：1991-12-18
申请号：EP90104941.1
申请日：1990-03-15
IPC分类号： G02F1/35 , C07C335/02 , C07D213/89 , C07F3/06
CPC分类号： G02F1/3619
摘要： A crystal of a complex salt containing a neutral nonlinear optical organic ligand coordinated to a metal ion is used as the nonlinear element in a nonlinear optical device. In one embodiment, the crystal of a complex salt comprises a crystal of tris(thiourea)zinc sulfate. In another embodiment, the crystal of a complex salt comprises a crystal of (4-nitropyridine-N-oxide)mercury(II) chloride.
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5.发明公开Production of polypyrrole gel suitable for casting conductive polypyrrole films 失效聚苯乙烯聚吡咯啉和丹麦Gegossene elektrischleitfähige聚吡咯片。
公开(公告)号：EP0380726A1
公开(公告)日：1990-08-08
申请号：EP89101654.5
申请日：1989-01-31
CPC分类号： C08G61/124 , H01B1/127
摘要： Production of polypyrrole gel applicable for casting on an impermeable substrate, such as glass, to form a conductive film thereon, by reaction of a pyrrole with an oxidant/dopant, e.g., ferric or cupric alkylbenzenesulfonate in an aprotic solvent, particularly methylene chloride or 1,2-dichloroethane. Specific examples of such alkylbenzenesulfonates include ferric ethylbenzenesulfonate and cupric dodecylbenzenesulfonate. The viscosity of the gel can be adjusted by solvent addition so that it can be readily applied to a substrate surface, such as glass. Upon subsequent solvent evaporation, a dark coherent textured film of conductive polypyrrole remains on the substrate surface.
摘要翻译： 通过吡咯与氧化剂/掺杂剂例如三价或二价烷基苯磺酸盐在非质子传递溶剂（特别是二氯甲烷或1,1-二氯甲烷）中的反应，适用于在不透水基材如玻璃上铸造的聚吡咯凝胶的生产，以形成导电膜。 1,2-二氯乙烷。 这种烷基苯磺酸盐的具体实例包括三乙基苯磺酸铁和十二烷基苯磺酸铜。 可以通过溶剂添加来调节凝胶的粘度，使得其可以容易地施加到诸如玻璃的基底表面上。 在随后的溶剂蒸发之后，导电聚吡咯的暗相干纹理膜保留在基材表面上。
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公开(公告)号：EP0693704B1
公开(公告)日：2002-08-28
申请号：EP95109113.1
申请日：1995-06-13
CPC分类号： G02F1/3619 , C07F5/04
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8.发明公开Semi-organic crystals for nonlinear optical devices 失效Halborganische KristallinefürNichtlinear optische Vorrichtungen
公开(公告)号：EP0693704A1
公开(公告)日：1996-01-24
申请号：EP95109113.1
申请日：1995-06-13
CPC分类号： G02F1/3619 , C07F5/04
摘要： A nonlinear optical material includes a noncentrosymmetric crystal of an anionic boron complex salt containing a cation and at least one organic ligand coordinated to a boron atom. The nonlinear optical crystal may consist of a compound having the formula A[BC₂] where A is a monocation, B is boron, and C is the organic ligand, or a compound having the formula A[BC₂]₂ where A is a dication, B is boron, and C is the organic ligand. The organic ligands may also be organic molecules having α-dihydroxy functionalities. Furthermore, the organic ligands may be selected from the group consisting of α-hydroxy carboxylic acids and 1, 2 - diols or from the group consisting of -malic acid, -lactic acid, -tartaric acid, dimethyl- -tartrate, diethyl- -tartrate, ℓ-malic acid, ℓ-lactic acid, ℓ-tartaric acid, dimethyl-ℓ-tartrate, diethyl-ℓ-tartrate, and ethylene glycol. The anionic boron complex may be selected from the group consisting of boro-di(ℓ-malate), boro-di(ℓ-tartrate), boro-di(ℓ-lactate), boro-di(diethyl-ℓ-tartrate), boro-di(dimethyl-l-tartrate), boro-di( -malate), boro-di( -tartrate), boro-di( -lactate), boro-di(diethyl- -tartrate), boro-di(dimethyl-d-tartrate) and boro-di(ethylene glycolate). The cation may be selected from the group consisting of alkali metals, alkaline earth metals, ammonium ions, and Group 2B dications. The cation may be further selected from the group consisting of lithium, sodium, potassium, the ammonium NH₄⁺ ion, the guanidinium C(NH₂)₃⁺ ion, calcium, and zinc.
摘要翻译： 非线性光学材料包括含有阳离子和至少一种与硼原子配位的有机配体的阴离子硼配盐的非中心对称晶体。 非线性光学晶体可以由具有式AÄBC2的化合物组成，其中A是单取代基，B是硼，C是有机配体，或具有式A a B 2/2的化合物，其中A是二价键，B是硼，C是 有机配体。 有机配体也可以是具有α-二羟基官能团的有机分子。 此外，有机配体可以选自α-羟基羧酸和1,2-二醇，或者由α-马来酸，β-乳酸，β-酒石酸，二甲基-β-酒石酸 ，酒石酸二乙酯，1-山梨酸，1-乳酸，l-酒石酸，酒石酸二甲酯，酒石酸二乙酯和乙二醇。 阴离子硼络合物可以选自硼酸二（1-苹果酸酯），硼 - 二（1-酒石酸），硼 - 二（1-乳酸），硼 - 二（二乙基-1-酒石酸酯）， 硼酸二（2-酒石酸二甲酯），硼酸二（±苹果酸酯），硼 - 二（@酒石酸盐），硼 - 二（β-乳酸） （二甲基 - 酒石酸二乙酯）和硼 - 二（乙醇酸乙酯）。 阳离子可以选自碱金属，碱土金属，铵离子和2B族二次元。 阳离子可以进一步选自锂，钠，钾，NH 4 +离子，C（NH 2）3+离子，钙和锌。
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9.发明公开Semi-organic crystals for nonlinear optical devices 失效Halborganische Kristallefürnicht-lineare optische Vorrichtungen。
公开(公告)号：EP0389879A2
公开(公告)日：1990-10-03
申请号：EP90104941.1
申请日：1990-03-15
IPC分类号： G02F1/35 , C07C335/02 , C07D213/89 , C07F3/06
CPC分类号： G02F1/3619
摘要： A crystal of a complex salt containing a neutral nonlinear optical organic ligand coordinated to a metal ion is used as the nonlinear element in a nonlinear optical device. In one embodiment, the crystal of a complex salt comprises a crystal of tris(thiourea)zinc sulfate. In another embodiment, the crystal of a complex salt comprises a crystal of (4-nitropyridine-N-oxide)mercury(II) chloride.
摘要翻译： 在非线性光学器件中，使用含有与金属离子配位的中性非线性光学有机配体的复盐的晶体作为非线性元件。 在一个实施方案中，复盐的晶体包含三（硫脲）硫酸锌的晶体。 在另一个实施方案中，复盐的晶体包含（4-硝基吡啶-N-氧化物）氯化汞（II）的晶体。
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10.发明公开Chemical synthesis of conducting polypyrrole using uniform oxidant/dopant reagents 失效使用氧化和掺杂剂的导电聚吡咯的化学合成。
公开(公告)号：EP0380725A1
公开(公告)日：1990-08-08
申请号：EP89101653.7
申请日：1989-01-31
CPC分类号： C08G61/124 , H01B1/127
摘要： A method for producing oxidant/dopant reagent solutions which comprises reacting a basic ferric carboxylate, preferably basic ferric acetate, with an alkyl or aryl sulfonic acid, e.g., benzenesulfonic acid, to produce the corresponding ferric sulfonate in solution. Oxidant/dopant solutions can also be prepared containing cupric or ceric sulfonates. The oxidant/dopant solution is employed in situ for reaction with a pyrrole to produce electrically conductive polypyrrole. A porous substrate, such as fiberglass cloth, can be dipped in the oxidant/dopant solution, dried and then treated with a pyrrole to produce an electrically conductive polypyrrole deposit in the interstices of the substrate.
摘要翻译： 一种用于生产氧化剂/掺杂剂的试剂溶液，其包括在烷基或芳基磺酸，E. G.，苯磺酸反应的基本铁羧酸盐，乙酸盐优选在碱性硫酸铁，用方法，以产生在溶液中相应铁磺酸盐。 因此氧化剂/掺杂剂溶液可以制备含有铜或铈磺酸盐。 氧化剂/掺杂剂溶液被用在原位反应与吡咯以产生导电聚吡咯。 一种多孔衬底，颜色：例如玻璃纤维布，可以在氧化剂/掺杂剂溶液中浸泡，干燥，然后用吡咯处理，产生在基片的间隙中在导电聚吡咯沉积。
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