AN IMPROVED MAGNESIUM DICHLORIDE SUPPORTED TITANIUM CATALYST COMPOSITION FOR POLYOLEFIN POLYMERIZATION
    4.
    发明公开
    AN IMPROVED MAGNESIUM DICHLORIDE SUPPORTED TITANIUM CATALYST COMPOSITION FOR POLYOLEFIN POLYMERIZATION 审中-公开
    VERBESSERTEMAGNESIUMDICHLORIDGETRÄGERTETITANKATALYSATORZUSAMMENSETZZZUR OLEFINPOLYMERISATION

    公开(公告)号:EP2958950A2

    公开(公告)日:2015-12-30

    申请号:EP14754662.6

    申请日:2014-01-22

    摘要: In the present disclosure, a Ziegler-Natta catalyst composition for the polymerization of olefin monomers to produce polyolefin with controlled molecular weight distribution is provided wherein said controlled molecular weight distribution ranges from narrow to broad. The desired control over the molecular weight distribution of polyolefin is accomplished by using a Ziegler-Natta catalyst composition having enhanced self-extinguishing property. In the Zeigler-Natta catalyst composition of the present disclosure, in addition to a titanium and magnesium containing pro-catalyst component, a mixture of tri-alkyl aluminum compounds as a co-catalyst mixture is used. The particular combination of tri-alkyl aluminum compounds in a pre-determined weight proportion provides desirable control over the molecular weight distribution of polyolefin.

    摘要翻译: 在本公开内容中,提供了用于聚合烯烃单体以制备具有受控分子量分布的聚烯烃的齐格勒 - 纳塔催化剂组合物,其中所述受控分子量分布范围从窄到宽。 通过使用具有增强的自熄性的齐格勒 - 纳塔催化剂组合物来实现对聚烯烃的分子量分布的所需控制。 在本公开的Zeigler-Natta催化剂组合物中,除了含有钛和镁的前催化剂组分之外,还使用作为助催化剂混合物的三烷基铝化合物的混合物。 三烷基铝化合物以预定重量比例的特定组合提供了对聚烯烃分子量分布的理想控制。