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1.
公开(公告)号:EP2352587A2
公开(公告)日:2011-08-10
申请号:EP09828131.4
申请日:2009-11-18
申请人: Rentech, Inc.
发明人: DEMIREL, Belma , BENHAM, Charles B. , FRAENKEL, Dan , BLEY, Richard , TAYLOR, Jesse, W. , REJAI, Bahman , ROLFE, Sara L. , WRIGHT, Harold, A.
CPC分类号: B01J37/18 , B01J21/08 , B01J23/745 , B01J23/78 , B01J37/03 , C10G2/332 , C10G2300/4006 , C10G2300/703
摘要: A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150°C to 250°C, introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270°C to 300°C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.
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公开(公告)号:EP2192981A2
公开(公告)日:2010-06-09
申请号:EP08798813.5
申请日:2008-08-27
申请人: Rentech, Inc.
发明人: DEMIREL, Belma , ROLFE, Sara, L. , WRIGHT, Harold, A. , BENHAM, Charles, B. , FRAENKEL, Dan , BLEY, Richard, A. , TAYLOR, Jesse, W.
CPC分类号: B01J23/78 , B01J21/005 , B01J21/08 , B01J37/03 , C10G2/331 , C10G2300/70
摘要: A method of strengthening a precipitated unsupported iron catalyst by: preparing a precipitated unsupported iron catalyst containing copper and potassium; adding a solution comprising a structural promoter to the previously prepared catalyst; drying the mixture; and calcining the dried catalyst.
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