摘要:
A flame retardant polymer composition comprising at least one polymer and a hypophosphite salt is disclosed, wherein: - the hypophosphite salt is so heat stabilized that, when it is heated for 3 hours at 298℃ under a flow of argon flushing at rate 58 mL/min, it generates less than 0.5 mL of phosphine per gram of hypophosphite salt; and - the flame retardant polymer composition further comprises at least an additive improving the flame retardant properties of the composition.
摘要:
A process for stabilizing hypophosphite salt is provided, which comprises the following steps: a) washing the hypophosphite salt at least one time under a controlled pH value of 4-11, preferably 5-8, as the said hypophosphite salt in an aqueous solution and/or in a solid state; and b) drying the said hypophosphite salt under reduced pressure to remove the volatiles. The process can prevent or minimize the formation of a dangerous quantity of phosphine from hypophosphite salts, more particularly in the flame retardant of the application. The flame retardant polymer composition is also provided, which comprises a polymer and the hypophosphite salt stabilized by the above process.
摘要:
The present invention discloses the use of a heat stabilized calcium hypophosphite as a filler to increase the mechanical properties of a polyamide composition. Said composition may also comprise reinforcing and/or bulking filler and/or impact modifier agents. The invention permits to obtain polyamide composition providing very good mechanical performances with the use of a calcium hypophosphite having a low degree of phoshpine generation.
摘要:
A flame retardant polymer composition is described. The composition can include at least one polymer and a hypophosphite salt, wherein the hypophosphite salt is heat stabilized so that when it is heated for 3 hours at 298° C. under a flow of argon flushing at rate 58 mL/min, it generates less than 0.5 mL of phosphine per gram of hypophosphite salt. The polymer can be an epoxy resin, a phenolic resin, an acrylonitrile-butadiene-styrene resin, a styrene-acrylonitrile resin, a mixture of high impact polystyrene and polyphenylene oxides, a styrene-butadiene rubber, a polylactic acid or a polyvinyl chloride.
摘要:
The current invention relates to a process for stabilizing a hypophosphite salt, comprising the step of heating the hypophosphite salt at a temperature of between 150 and 370° C. during a sufficient period of time to prevent the formation of a dangerous quantity of phosphine in their application as FR in polymers and a flame retardant polymer composition comprising a polymer and 0.1 to 30 weight percent based on the total weight of the composition of the hypophosphite salt thermally stabilized by the above process.