公开(公告)号：EP3383926A1

公开(公告)日：2018-10-10

申请号：EP16802041.0

申请日：2016-11-28

申请人： SABIC Global Technologies B.V.

发明人： ALMOHAMMADI, Bandar, Abdullah ,  MOMAN, Akhlaq ,  ALSHAIBAN, Ahmad, Abdullah ,  SIDDIQUI, Inaamul, Haq ,  PADMANABHAN, Sudhakar, R

IPC分类号： C08F110/06 ,  C08F4/651 ,  C08F10/06

CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F10/06 ,  C08F2500/01 ,  C08F2500/04

摘要： The present invention relates to a procatalyst for polymerization of olefins, which procatalyst is based on a magnesium compound of the formula MgR'R" wherein R' is an alkoxide or aryloxide group and wherein R" is an alkoxide or aryloxide group or halogen, preferably a magnesium dialkoxide compound, that has been reacted with a tetravalent titanium halide, an activator being a monoester and an internal donor represented by a compound according to formula B:wherein each R80 group is independently a linear, branched or cyclic hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 30 carbon atoms; R81, R82, R83, R84, R85, and R86 are each independently selected from hydrogen or a linear, branched or cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 20 carbon atoms; R87 is a hydrogen or a linear, branched or cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. Moreover, the present invention relates to a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; to a process of making a polyolefin, preferably a polypropylene by contacting an olefin with the catalyst system; to a polyolefin, preferably a polypropylene, obtained by or obtainable by the process; to a polyolefin, preferably a polypropylene, having a molecular weight distribution of between 3 and 15, a molecular weight (Mw) of between 200,000 to 1,000,000 g/mol, a melting temperature of more than 145 °C, a value for the xylene solubles of less than 4 wt.% and a shaped article therefrom.

公开(公告)号：EP3383925A1

公开(公告)日：2018-10-10

申请号：EP16801182.3

申请日：2016-11-23

申请人： SABIC Global Technologies B.V.

发明人： MOMAN, Akhlaq ,  HUMYDI-AL, Abdulaziz ,  SIDDIQUI, Inaamul, Haq ,  PADMANABHAN, Sudhakar, R ,  ALMOHAMMADI, Bandar, Abdullah ,  ALSHAIBAN, Ahmad, Abdullah

IPC分类号： C08F110/06 ,  C08F4/651 ,  C08F10/06

CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F4/6548 ,  C08F2500/04 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/01

摘要： as described herein. Also described is a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; a process of making a polyolefin, by contacting an olefin with the catalyst system; a polyolefin, obtained by or obtainable by the process; and a polyolefin, having a molecular weight distribution of between 4 and 15, a molecular weight (Mw) of between 300,000 to 1,500,000 g/mol, a melting temperature of more than 150° C., a value for the xylene solubles of less than 4 wt. % and a shaped article therefrom.