公开(公告)号：EP0599348A1

公开(公告)日：1994-06-01

申请号：EP93119131.6

申请日：1993-11-26

申请人： SANYO ELECTRIC Co., Ltd.

发明人： Okoshi, Ryoji ,  Watanabe, Masato

IPC分类号： C08G18/32 ,  C08G18/66

CPC分类号： C08G18/6622 ,  C08G18/3275 ,  C08G18/5021 ,  C08G2101/0025

摘要： The present invention provides a heat insulating box comprising an outer box and an inner box, the gap therebetween being filled with a hard polyurethane foam prepared by the reaction of polyols and isocyanates in the presence of a foaming agent, in which a part or the whole of the polyols comprises one or more tertiary amino alcohols represented by the following formula (I):

wherein substituents represented by R₁, which may be the same or different, each represents a straight-chain or branched alkylene group having form 2 to 24 carbon atoms, an alicyclic alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted arylene group, an aralkylene group or -(CH₂CH₂O) p -(CH₂CH₂) q - (in which p represents 0 or a positive integer and q represents a positive integer); substituents represented by R₂, which may be the same or different, each represents a straight-chain or branched alkyl group having from 1 to 24 carbon atoms, an aryl group or an aralkyl group; and the average polymerization degree n represents a positive integer of 1 to 50.

摘要翻译： 本发明提供一种隔热箱，其包括外箱和内箱，其间的间隙填充有通过多元醇和异氰酸酯在发泡剂存在下反应制备的硬质聚氨酯泡沫，其中部分或全部 的多元醇包含一个或多个由下式（I）表示的叔氨基醇：其中由R 1表示的取代基可以相同或不同，表示直链或支链亚烷基，其具有2〜 24个碳原子，脂环族亚烷基，取代或未取代的亚环烷基，取代或未取代的亚芳基，亚芳基或 - （CH 2 CH 2 O）p - （CH 2 CH 2）q - （其中p表示0或正整数，q 表示正整数）; 由R2表示的取代基可以相同或不同，表示具有1至24个碳原子的直链或支链烷基，芳基或芳烷基; 平均聚合度n表示1〜50的正整数。