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公开(公告)号:EP1848664A1
公开(公告)日:2007-10-31
申请号:EP05855617.6
申请日:2005-12-26
申请人: SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , JUTTU, Gopalakrishnan G. , Khanmamedova, Alla Konstantin , MITCHELL, Scott F.
发明人: SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , JUTTU, Gopalakrishnan G. , Khanmamedova, Alla Konstantin , MITCHELL, Scott F.
IPC分类号: C01F7/00
CPC分类号: C01B39/06 , B01J29/04 , B01J2229/20 , C01B39/38 , C01B39/40 , Y10S423/22
摘要: This invention relates to a process for making a germanium-zeolite without using fluoride compounds. The zeolite is preferably a MFI-type structure, most preferably a ZSM-5 MFI zeolite. The germanium-zeolite is synthesized essentially in the absence of fluoride compounds from an aqueous gel containing a silica source, a germanium source, an aluminum source and a structure directing agent in the presence of an acid which does not contain fluorine, such as sulfuric acid, acetic acid, nitric acid, phosphoric acid hydrochloric acid or formic acid.
摘要翻译: 本发明涉及不使用氟化物化合物制造锗 - 沸石的方法。 沸石优选为MFI型结构,最优选ZSM-5 MFI沸石。 锗 - 沸石基本上在不含氟化物的情况下由含有二氧化硅源,锗源,铝源和结构导向剂的含水凝胶在不含氟的酸例如硫酸 ,醋酸,硝酸,磷酸盐酸或甲酸。
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公开(公告)号:EP1848664B1
公开(公告)日:2018-12-19
申请号:EP05855617.6
申请日:2005-12-26
申请人: SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , JUTTU, Gopalakrishnan G. , Khanmamedova, Alla Konstantin , MITCHELL, Scott F.
CPC分类号: C01B39/06 , B01J29/04 , B01J2229/20 , C01B39/38 , C01B39/40 , Y10S423/22
摘要: This invention relates to a process for making a germanium-zeolite without using fluoride compounds. The zeolite is preferably a MFI-type structure, most preferably a ZSM-5 MFI zeolite. The germanium-zeolite is synthesized essentially in the absence of fluoride compounds from an aqueous gel containing a silica source, a germanium source, an aluminum source and a structure directing agent in the presence of an acid which does not contain fluorine, such as sulfuric acid, acetic acid, nitric acid, phosphoric acid hydrochloric acid or formic acid.
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