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公开(公告)号：EP1173409A1
公开(公告)日：2002-01-23
申请号：EP00906769.5
申请日：2000-02-24
发明人： BESEMER, Arie, Cornelis , JETTEN, Jan, Matthijs , JASCHINSKI, Thomas , VAN DEN DOOL, Ronald, Tako, Marinus
IPC分类号： C07C239/08 , C12P7/24
摘要： A process for producing nitrosonium ions is described, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine. The process is useful for the oxidation of carbohydrates containing at least 1 cyclic monosaccharide chain group carrying a carbaldehyde group per 100 or per 25 monosaccharide units and per molecule.
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公开(公告)号：EP1155039B1
公开(公告)日：2004-07-14
申请号：EP00906770.3
申请日：2000-02-24
发明人： JETTEN, Jan, Matthijs , VAN DEN DOOL, Ronald , VAN HARTINGSVELDT, Wim , BESEMER, Arie, Cornelis
摘要： A process for oxidising cellulose, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine, or an oxidative enzyme, and the resulting nitrosonium ion is used to selectively oxidise the cellulose 6-hydroxy-methylene groups to carbaldehyde groups and carboxylic acid groups.
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3.发明公开
公开(公告)号：EP1155040A1
公开(公告)日：2001-11-21
申请号：EP00907622.5
申请日：2000-02-24
发明人： JASCHINSKI, Thomas , GUNNARS, Susanna , BESEMER, Arie, Cornelis , BRAGD, Petter , JETTEN, Jan, Matthijs , VAN DEN DOOL, Ronald , VAN HARTINGSVELDT, Willem
CPC分类号： D21H11/20 , C08B15/02 , D21C9/002 , Y10T428/234
摘要： The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) and a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.
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公开(公告)号：EP1155039A1
公开(公告)日：2001-11-21
申请号：EP00906770.3
申请日：2000-02-24
发明人： JETTEN, Jan, Matthijs , VAN DEN DOOL, Ronald , VAN HARTINGSVELDT, Wim , BESEMER, Arie, Cornelis
摘要： A process for oxidising cellulose, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine, or an oxidative enzyme, and the resulting nitrosonium ion is used to selectively oxidise the cellulose 6-hydroxy-methylene groups to carbaldehyde groups and carboxylic acid groups.
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5.发明授权
公开(公告)号：EP1155040B1
公开(公告)日：2006-04-26
申请号：EP00907622.5
申请日：2000-02-24
发明人： JASCHINSKI, Thomas , GUNNARS, Susanna , BESEMER, Arie, Cornelis , BRAGD, Petter , JETTEN, Jan, Matthijs , VAN DEN DOOL, Ronald , VAN HARTINGSVELDT, Willem
CPC分类号： D21H11/20 , C08B15/02 , D21C9/002 , Y10T428/234
摘要： The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) and a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.
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公开(公告)号：EP1173409B1
公开(公告)日：2005-11-02
申请号：EP00906769.5
申请日：2000-02-24
发明人： BESEMER, Arie, Cornelis , JETTEN, Jan, Matthijs , JASCHINSKI, Thomas , VAN DEN DOOL, Ronald, Tako, Marinus
IPC分类号： C07C239/08 , C12P7/24
摘要： A process for producing nitrosonium ions is described, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine. The process is useful for the oxidation of carbohydrates containing at least 1 cyclic monosaccharide chain group carrying a carbaldehyde group per 100 or per 25 monosaccharide units and per molecule.
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