摘要:
An aqueous dispersion of a substituted succinic anhydride comprising an aqueous soluble copolymer A, or an aqueous soluble copolymer A 2 or a mixture of these two copolymers, the copolymer A, having 50 to 98.5 per cent by mol of (meth)acrylamide (a), 1 to 49.5 per cent by mol of N,N-dialkylamidealkyl(meth)acrylamide (b), and 0.5 to 20 per cent by mol of (meth)acrylic acid (c) as monomer ingredients, the aqueous soluble copolymer A 2 having 70 per cent by weight or more of a mixture monomer ingredient having 50 to 98.5 per cent by mol of (meth)acrylamide (a), 1 to 49.5 per cent by mol of N,N-dialkylaminoalkyl(meth)acrylamide (b) and 0.5 to 20 per cent by mol of (meth)acrylic acid (c) and other copolymer monomer (d) as monomer ingredients. The dispersion is used as a sizing agent and shows a dilute stability in paper-making steps as well as a sufficient sizing effect in a low content addition range, even in acidic paper making without using a calcium carbonate filler, and in neutral paper making using alum.
摘要:
A process for making paper using a substituted succinic anhydride as a sizing agent which has the steps of preparing pulp slurry containing (a) an aqueous dispersion of a substituted succinic anhydride in which a cationic tapioca starch containing at least 0.3 percent by weight of basic nitrogen is added and mixed, and (b) a colloidal silica, and forming a paper sheet to improve the retentions of a fine fiber and a filler in the pulp slurry in the sheet forming step and to largely suppress the operation of decreasing the sizing performance of the substituted succinic anhydride with the colloidal silica (b) added as the retention aid, thereby preparing sheet paper having excellent sizing effect. Thus, the process for making paper can not only remarkably reduce the sizing cost but can also efficiently utilize the fine fiber and the filler in the pulp slurry.
摘要:
An aqueous dispersed solution of a substituted succinic anhydride which comprises an aqueous soluble copolymer (A) having 50 percent or more by mol of (meth)acrylamide (a) 1 percent or more by mol of N,N-dialkylamino.alkyl(methy)-acrylamide (b) as monomer ingredients, aqueous soluble copolymer (B) having 50 percent or more by mol of (meth)acrylamide (a), 1 percent or more by mold of N,N-dialkylamino.alkyl(meth)acrylamide (b) and 49 percent or less by mol of other copolymer monomer (c) as monomer ingredients, or both of the aqueous soluble copolymer (A) and the aqueous soluble copolymer (B), and a process for producing an aqueous dispersed solution of a substituted succinic anhydride prepared by dispersing the aqueous soluble copolymer (A) or the aqueous soluble copolymer (B) or a mixture (C) of 99 to 99.9 percent by weight of the substituted succinic anhydride (d) and 10 to 0.1 percent by weight of an oil-in-water type surfactant (e) in aqueous solution containing both the aqueous soluble copolymer (A) and the aqueous soluble copolymer (B). Thus, the aqueous dispersion can provide an excellent sizing effect in case applied as a sizing agent in paper making process but also has preferable dilute dispersibility of aqueous dispersion, does not possibly contaminate wires, rolls and carpets of a paper making machine when applied as a sizing agent in the practical paper making process with properties of capable of continuously operating for a long period of time.