摘要:
A process for preparing an olefin polymerization catalyst which comprises halogenating a magnesium-di-(3- halo or 3-C 1 to C 8 alkoxy-phenoxide) with a halide of tetravalent titanium in the presence of a halohydrocarbon, recovering the solid reaction product from the reaction mixture and combining the solid reaction product with an organo aluminium compound and an electron donor.
摘要:
A process for preparing a solid catalyst component which comprises halogenating a magnesium compound in the formula MgRR¹.nCO₂ in which R and R¹ are the same or different alkoxy or phenoxy groups and n is a number of from 0 to 2 with a halide of tetravalent titanium in the presence of dialkylester of a dihydric aromatic carboxylic acid and an inert hydrocarbon diluent by reacting at a temperature of from 120 to 136 °C and recovering the solid reaction product from the reaction mixture.
摘要:
A process for the preparation of polyisoprene by polymerizing isoprene in the presence of a beta-TiCl 3 containing catalyst and an activator prepared by reacting a hydrocarbylaluminium compound and a hydroxy-aromatic compound, having at both ortho-places with respect to the hydroxy-group a secondary or tertiary alkyl-group.
摘要:
Composite polymers, especially composite polyols containing active hydrogen atoms can be prepared by polymerizing one or more olefinically unsaturated compounds in the presence of a liquid polymer containing active hydrogen atoms and a modified initiator; the modification comprising the reaction between a liquid polymer containing one or more groups which can react with isocyanate groups and a compound containing two or more isocyanate groups which has been partially converted by reacting it with an organic hydroperoxide or a free-radical initiator also containing additional active hydrogen atoms. The composite polymers exhibit a stable dispersed polymer phase and can be suitably applied as starting materials for polyurethane foams.
摘要:
A process for preparing a solid catalyst component which comprises halogenating a magnesium compound in the formula MgRR¹.nCO₂ in which R and R¹ are the same or different alkoxy or phenoxy groups and n is a number of from 0 to 2 with a halide of tetravalent titanium in the presence of dialkylester of a dihydric aromatic carboxylic acid and an inert hydrocarbon diluent by reacting at a temperature of from 120 to 136 °C and recovering the solid reaction product from the reaction mixture.
摘要:
A solid catalyst component for alkene polymerization comprising a magnesium halide, an electron donor and a phenoxy-titanium halide, the latter being a dihalophenoxy-titanium halide or a dialkoxyphenoxy-titanium halide in which the alkoxy groups each have from 1 to 8 carbon atoms.
摘要:
A process for preparing spherical particles of a compound with the general formula Mg(OR) 2-a (OR') a in which R is an alkyl group with from 2 to 8 carbon atoms, R' is an alkyl group with from 1 to 7 carbon atoms and a is a number of from 0 to 0.5, which comprises preparing a homogeneous solution of a compound Mg(OR)₂ in an aliphatic alcohol with the general formula R'OH spray-drying the solution at a temperature of from 15 to 85 °C, suspending the spray-dried solid particles in an aliphatic alcohol with the formula ROH in which R is the same alkyl group as present in the said compound Mg(OR)₂ heating the suspension in order to remove an alcohol with the formula R'OH from the liquid phase by distillation and separating the solid particles from the liquid phase.