公开(公告)号：EP2115035A1

公开(公告)日：2009-11-11

申请号：EP08704589.4

申请日：2008-01-04

申请人： SK CHEMICALS CO., LTD.

发明人： LEE, Young-Rok ,  CHA, Il-Hoon ,  CHO, Jun-Sang ,  SHIN, Yong-Jun

IPC分类号： C08G75/04

CPC分类号： C08G75/14 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0263 ,  C08L81/02 ,  C08L2666/22 ,  C08L81/00

摘要： The present invention relates to a polyarylene sulfide that is prepared from a composition including 100 parts by weight of solid sulfur, 500 to 10,000 parts by weight of iodinated aryl compounds, and 0.03 to 30 parts by weight of a sulfur-containing polymerization terminator with respect to 100 parts by weight of the solid sulfur, and has a melting temperature (Tm) of 255 to 285 °C, and luminosity of 40 or higher as defined by the CIE Lab color model, and a process of preparing the same. The PAS resin is prepared from a composition including a sulfur-containing polymerization terminator and thus has excellent thermal properties and luminosity.

公开(公告)号：EP2097470A1

公开(公告)日：2009-09-09

申请号：EP08704591.0

申请日：2008-01-04

申请人： SK CHEMICALS CO., LTD.

发明人： LEE, Young-Rok ,  CHA, Il-Hoon ,  CHO, Jun-Sang

IPC分类号： C08G75/04

CPC分类号： C08G75/0263 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0281 ,  C08L81/02 ,  C08L81/00

摘要： The present invention relates to a process of producing polyarylene sulfide (PAS) and PAS resin produced therefrom, and more specifically, to a process of preparing polyarylene sulfide with better thermal properties and luminosity than conventional PAS and the PAS resin produced therefrom, including the steps of: a) melting and mixing a composition including solid sulfur, iodinated aryl compounds, and a polymerization terminator; b) polymerizing the molten mixture of step a) for 1 to 30 hours while increasing the temperature and decreasing the pressure from initial reaction conditions of a temperature of 180 to 250 °C and a pressure of 50 to 450 Torr to final reaction conditions of a temperature of 270 to 350 °C and a pressure of 0.001 to 20 Torr; and c) heating the reaction product of step b) at a temperature of 270 to 350 °C for 1 to 25 hours. The process of polyarylene sulfide resin further includes a step of heating the polymerized product at a high temperature following the polymerization step, and uses the polymerization terminator in a suitable amount to control the molecular weight of polyarylene sulfide, thereby producing polyarylene sulfide with excellent thermal properties and luminosity.

公开(公告)号：EP2115035B1

公开(公告)日：2018-04-25

申请号：EP08704589.4

申请日：2008-01-04

申请人： SK Chemicals Co., Ltd.

发明人： LEE, Young-Rok ,  CHA, Il-Hoon ,  CHO, Jun-Sang ,  SHIN, Yong-Jun

IPC分类号： C08G75/0209 ,  C08G75/0231 ,  C08G75/0263 ,  C08G75/14 ,  C08L81/02

CPC分类号： C08G75/14 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0263 ,  C08L81/02 ,  C08L2666/22 ,  C08L81/00

摘要： The present invention relates to a polyarylene sulfide that is prepared from a composition including 100 parts by weight of solid sulfur, 500 to 10,000 parts by weight of iodinated aryl compounds, and 0.03 to 30 parts by weight of a sulfur-containing polymerization terminator with respect to 100 parts by weight of the solid sulfur, and has a melting temperature (Tm) of 255 to 285° C., and luminosity of 40 or higher as defined by the CIE Lab color model, and a process of preparing the same. The PAS resin is prepared from a composition including a sulfur-containing polymerization terminator and thus has excellent thermal properties and luminosity.

公开(公告)号：EP2097470B1

公开(公告)日：2017-03-22

申请号：EP08704591.0

申请日：2008-01-04

申请人： SK CHEMICALS CO., LTD.

发明人： LEE, Young-Rok ,  CHA, Il-Hoon ,  CHO, Jun-Sang

IPC分类号： C08G75/0209 ,  C08G75/0231 ,  C08G75/0263 ,  C08G75/0281 ,  C08L81/02

CPC分类号： C08G75/0263 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0281 ,  C08L81/02 ,  C08L81/00