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1.发明公开Cyclohexenone derivative, process for producing the same and herbicides comprising the same as active ingredient 失效环己酮衍生物，其制备方法和包含其的除草剂作为活性成分
公开(公告)号：EP0297757A3
公开(公告)日：1990-01-24
申请号：EP88305529.5
申请日：1988-06-17
发明人： Arai, Kenji , Mito Nobuaki , Morita, Kouichi , Hirata, Naonori
IPC分类号： C07C323/47 , C07C333/06 , C07D333/38 , C07F9/117 , A01N39/00 , A01N43/10 , A01N47/18 , A01N57/12 , A01N53/00
摘要： A cyclohexenone derivative is represented by the formula,
wherein R¹ represents a (C₁-C₃)alkyl group, R² represents a (C₁-C₃)alkyl, (C₃-C₄)alkenyl, propargyl or chloroallyl group, and R³ represents a (C₁-C₁₂)alkyl, (C₃-C₅)alkenyl, propargyl, halo(C₂-C₃)alkyl, halo(C₃-C₄)alkenyl, (C₃-C₆)cycloalkyl, (C₅-C₇)cycloalkenyl, (C₁-C₈)alkoxy(C₁-C₂)alkyl, methylthiomethyl, halo(C₂-C₄)alkoxymethyl, benzyloxymethyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom), carboxy(C₁-C₄)alkyl, (C₁-C₅)alkoxycarbonyl(C₁-C₄)alkyl, di(C₁-C₃)alkylcarbamoyl, di(C₁-C₃)alkylthiocarbamoyl, O,O-di(C₁-C₃)alkoxyphosphinyl, (C₁-C₁₁)alkylcarbonyl, (C₂-C₄)alkenylcarbonyl, (C₃-C₆)cycloalkylcarbonyl, (C₃-C₆)cycloalkylacetyl, chrysanthemoyl, benzoyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom), naphthalenecarbonyl, pyridinecarbonyl, furoyl or thenoyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom). The compounds have a high herbicidal activity against various weeds in soil treatment and foliage treatment in plough fields as well as in treatment under flooded conditions in paddy fields. Furthermore they exhibit a high selectivity to the undesired weeds as compared with the desired crops, so that they can be used in various applications as active ingredients for herbicides.-
公开(公告)号：EP0323915A1
公开(公告)日：1989-07-12
申请号：EP89300125.5
申请日：1989-01-06
IPC分类号： C07C323/22
CPC分类号： C07C319/20 , C07C323/22
摘要： Compounds of the present invention are represented by the formula,
wherein X represents a lower alkyl, lower alkoxy, lower haloalkyl or lower haloalkoxy group or a halogen atom, and R¹ and R², which may be the same or different, represent a hydrogen atom or a methyl group. They are useful intermediates for preparing herbicidal compounds of the formula
which compounds are obtained by dehydrating the corresponding compounds (I) with any of a certain number of acids.
The compounds (I) are prepared by reaction of an aldehyde
with an acetoacetic acid salt in the presence of a C₁₋₆ carboxylic acid salt.摘要翻译： 本发明化合物由下式表示，其中X代表低级烷基，低级烷氧基，低级卤代烷基或低级卤代烷氧基或卤素原子，R 1和R 2可以是 相同或不同，表示氢原子或甲基。 它们是用于制备式CHEM的除草化合物的有用中间体，该化合物通过用一定数量的酸中的任何一种脱水相应的化合物（I）而获得。 化合物（I）通过在C 1-6羧酸盐的存在下使醛
与乙酰乙酸盐反应来制备。 -
3.发明公开
公开(公告)号：EP0700907A1
公开(公告)日：1996-03-13
申请号：EP95113328.9
申请日：1995-08-24
发明人： Uekawa, Toru , Hirata, Naonori , Arai, Kenji
IPC分类号： C07D239/34 , C07D239/42
CPC分类号： C07D401/12 , C07D239/52 , C07D239/60
摘要： A process for producing a pyrimidine derivative represented by the following formula:
wherein R is an aromatic ring, etc.; X is an oxygen atom, etc.; R¹ , R² and R³ respectively represent a hydrogen atom, etc; and R⁹ and R¹⁰ respectively represent a halogen atom, etc.
which comprises reacting a cyclic compound represented by the following formula:
wherein R, X, R¹, R² and R³ are as defined above
with a pyrimidinyltrimethylammonium chloride compound represented by the following formula:
wherein R⁹ and R¹⁰ are as defined above.
The above-mentioned pyrimidine derivative can be easily produced according to the process of the present invention.摘要翻译： 一种制备由下式表示的嘧啶衍生物的方法：其中R为芳环等的CHEM; X是氧原子等; R 1，R 2和R 3分别表示氢原子等; R 9和R 10分别表示卤素原子等，它们包括使由下式表示的环状化合物：其中R，X，R 1，R 2， 和R 3如上定义，与下式表示的嘧啶基三甲基氯化铵化合物：其中R 9和R 1如上定义的
。 上述嘧啶衍生物可以根据本发明的方法容易地制备。 -
4.发明公开Isothiazolone derivative and microbicidal composition comprising the same as active ingredient 失效异噻唑酮衍生物及其衍生物Aktivbestandteile enthaltende Mikrobizide。
公开(公告)号：EP0648757A1
公开(公告)日：1995-04-19
申请号：EP94115456.9
申请日：1994-09-30
发明人： Kakimizu, Akiko , Arai, Kenji , Kimura, Norio , Teramae, Tomohiro
IPC分类号： C07D275/03 , C07C323/60 , A01N43/80
CPC分类号： C07D275/03 , A01N43/80 , C07C323/60
摘要： There is disclosed a novel isothiazolone derivative of the formula:
wherein X¹ and X² are the same or different and are independently hydrogen, chlorine or bromine; and R is haloalkoxy. The isothiazolone derivative is effective as a microbicide. Also disclosed are a microbicidal composition containing the isothiazolone derivative as an active ingredient, and an intermediate compound for use in the production of the isothiazolone derivative.摘要翻译： 公开了下式的新型异噻唑酮衍生物：其中X 1和X 2相同或不同并且独立地为氢，氯或溴; 和R是卤代烷氧基。 异噻唑酮衍生物作为杀微生物剂是有效的。 还公开了含有异噻唑酮衍生物作为活性成分的杀微生物组合物和用于制备异噻唑酮衍生物的中间体化合物。
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公开(公告)号：EP0323915B1
公开(公告)日：1992-04-08
申请号：EP89300125.5
申请日：1989-01-06
IPC分类号： C07C323/22
CPC分类号： C07C319/20 , C07C323/22
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公开(公告)号：EP0414572A1
公开(公告)日：1991-02-27
申请号：EP90309347.4
申请日：1990-08-24
发明人： Ito, Yoshikazu , Manabe, Akio , Mizutani, Masato , Hirata, Naonori , Uwayokote, Sachiko , Izumi, Kazuo , Arai, Kenji
IPC分类号： C07D207/46 , C07D209/48 , C07C259/06 , C07C259/10 , A01N37/32
CPC分类号： C07D209/48 , A01N37/36 , C07C259/10 , C07D207/46
摘要： Plant growth regulators comprising, as an active ingredient, a substituted dicarboxylic acid derivative having the formula:
wherein R¹, R², R³, R⁴, D and G are the same as defined in the present specification, the substituted dicarboxylic acid derivatives, and processes for preparing the same, are disclosed. The plant growth regulators provided according to the present invention have a regulating activity on plant growth; more specifically, an action thereof of lowering the content of endogenous ethylene in a plant is utilized.摘要翻译： 植物生长调节剂包含作为活性成分的具有下式的取代二羧酸衍生物：其中R 1，R 2，R 3，R 4，D和G的取代二羧酸衍生物与 在本说明书中定义，取代的二羧酸衍生物及其制备方法。 根据本发明提供的植物生长调节剂对植物生长具有调节活性; 更具体地，利用了降低植物中内源性乙烯含量的作用。
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7.发明公开Cyclohexenone derivative, process for producing the same and herbicides comprising the same as active ingredient 失效环己烯酮衍生物，含有它们作为活性成分的它们的制备方法和除草剂。
公开(公告)号：EP0297757A2
公开(公告)日：1989-01-04
申请号：EP88305529.5
申请日：1988-06-17
发明人： Arai, Kenji , Mito Nobuaki , Morita, Kouichi , Hirata, Naonori
IPC分类号： C07C323/47 , C07C333/06 , C07D333/38 , C07F9/117 , A01N39/00 , A01N43/10 , A01N47/18 , A01N57/12 , A01N53/00
摘要： A cyclohexenone derivative is represented by the formula,
wherein R¹ represents a (C₁-C₃)alkyl group, R² represents a (C₁-C₃)alkyl, (C₃-C₄)alkenyl, propargyl or chloroallyl group, and R³ represents a (C₁-C₁₂)alkyl, (C₃-C₅)alkenyl, propargyl, halo(C₂-C₃)alkyl, halo(C₃-C₄)alkenyl, (C₃-C₆)cycloalkyl, (C₅-C₇)cycloalkenyl, (C₁-C₈)alkoxy(C₁-C₂)alkyl, methylthiomethyl, halo(C₂-C₄)alkoxymethyl, benzyloxymethyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom), carboxy(C₁-C₄)alkyl, (C₁-C₅)alkoxycarbonyl(C₁-C₄)alkyl, di(C₁-C₃)alkylcarbamoyl, di(C₁-C₃)alkylthiocarbamoyl, O,O-di(C₁-C₃)alkoxyphosphinyl, (C₁-C₁₁)alkylcarbonyl, (C₂-C₄)alkenylcarbonyl, (C₃-C₆)cycloalkylcarbonyl, (C₃-C₆)cycloalkylacetyl, chrysanthemoyl, benzoyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom), naphthalenecarbonyl, pyridinecarbonyl, furoyl or thenoyl (which may be substituted with a (C₁-C₂)alkyl group or halogen atom).
The compounds have a high herbicidal activity against various weeds in soil treatment and foliage treatment in plough fields as well as in treatment under flooded conditions in paddy fields. Furthermore they exhibit a high selectivity to the undesired weeds as compared with the desired crops, so that they can be used in various applications as active ingredients for herbicides.摘要翻译： 甲环己烯酮衍生物由式，
其中，R <1>表示（C1-C3）烷基，R <2>表示（C1-C3）烷基，（C3-C4）链烯基，炔丙基或氯代代表 基，且R <3>表示（C1-C12）烷基，（C3-C5）链烯基，炔丙基，卤代（C2-C3）烷基，卤代（C3-C4）烯基，（C3-C6）环烷基，（C5 C7）环烯基，（C1-C8）烷氧基（C1-C2）烷基，甲硫基甲基，卤代（C2-C4）烷氧基甲基，苄氧基甲基（可被取代的具有（C1-C2）烷基或卤原子），羧基（ C1-C4）烷基，（C1-C5）烷氧基羰基（C1-C4）烷基，二（C1-C3）烷基氨基甲酰基，二（C1-C3）烷基硫代氨基甲，O，O-二（C1-C3）alkoxyphosphinyl，（C 1 -C C11）烷基羰基，（C2-C4）链烯基羰，（C3-C6）环烷基羰基，（C3-C6）cycloalkylacetyl，菊，苯甲酰基（可被一个（C1-C2取代）烷基或卤原子），萘甲，吡啶羰 ，呋喃甲酰基或噻吩甲酰基（其可以是具有（C1-C2）烷基或卤素原子取代）。 所述化合物具有抗在土壤处理和茎叶处理中犁领域以及在帕迪·菲尔兹淹没条件下处理各种杂草具有高的除草活性。 进一步它们表现出高的选择性，以与所希望的作物相比，不希望的杂草，所以thatthey可以在各种应用中作为除草剂的活性成分一起使用。 -
8.发明公开
公开(公告)号：EP0659847A1
公开(公告)日：1995-06-28
申请号：EP94120598.1
申请日：1994-12-23
发明人： Tsuboi, Makoto , Yuki, Shuhei , Kakimizu, Akiko , Arai, Kenji , Mizutani, Masato
CPC分类号： A01N43/80 , C09D5/1625
摘要： There are disclosed a controlling agent and an antifouling composition against harmful aquatic organisms, which include a particular N-phenylisothiazolone derivative of the formula:
wherein X¹ and X² are the same or different and are independently hydrogen, chlorine or bromine; and R is haloalkoxy. Also disclosed is a method for preventing or inhibiting the adhesion of harmful aquatic organisms to water-exposed articles, which includes applying the antifouling composition to the water-exposed articles.摘要翻译： 有圆盘游离缺失的控制剂和防污组合物对有害水生物，其中包括下式的一个特别是N- phenylisothiazolone衍生物：
worin X <1>和X <2>是相同的或不同的并且是unabhängig氢， 氯或溴; 且R为卤代烷氧基。 所以圆盘游离缺失是用于防止或抑制有害水生生物体暴露于水的物品，其包括将所述防垢组合物的暴露于水的物品的密合性的方法。 -
9.发明公开
公开(公告)号：EP0644243A2
公开(公告)日：1995-03-22
申请号：EP94114600.3
申请日：1994-09-16
IPC分类号： C09D5/14
CPC分类号： C09D5/1625 , A01N43/80 , C08K5/47
摘要： There are disclosed a controlling agent and an antifouling composition against harmful aquatic organisms, which include a particular N-phenylbenzoisothiazolone derivative of the formula:
wherein R's are the same or different and are independently halogen, alkyl or alkoxy; n is an integer of 0 to 5; X's are the same or different and are independently halogen, nitro, alkyl or alkoxy; and m is an integer of 0 to 4; with the proviso that when the R's are all alkyl or all alkoxy, n is an integer of 1 to 3, and when all of the R's are different, n is an integer of 2 or 3. Also disclosed is a method for preventing or inhibiting the adhesion of harmful aquatic organisms to water-exposed articles, which includes applying the antifouling composition to the water-exposed articles.摘要翻译： 有盘的游离缺失对有害水生物，其中包括下式的一个特别是N- phenylbenzoisothiazolone衍生物的控制剂和防污组合物：worin的r是相同的或不同的，并且是卤素unabhängig
，烷基或烷氧基; n为0〜5的整数; X可相同或不同，是卤素unabhängig，硝基，烷基或烷氧基; 且m是0〜4的整数; 其条件没有当将R的都是烷基或全部烷氧基，n为1〜3的整数，并且当所有的R的是不同的，n是或的整数2 3。因此游离缺失盘是用于防止的方法或抑制 的有害水生生物体粘附于水中物体，其包括将所述防垢组合物的暴露于水的物品。 -
公开(公告)号：EP0254514B1
公开(公告)日：1990-10-10
申请号：EP87306397.8
申请日：1987-07-20
发明人： Arai, Kenji , Mito, Nobuaki , Morita, Kouichi , Hirata, Naonori
IPC分类号： C07C323/47 , A01N35/10
CPC分类号： A01N39/00
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