摘要:
Methionine is produced in an improved yield while reducing the load of waste water disposal by a process including the steps of:
(A) adding at least one compound selected from potassium carbonate, potassium bicarbonate and potassium hydroxide to a solution containing 5-(β-methylmercaptoethyl)hydantoin, (B) saturating the resulting solution with carbon dioxide gas and separating deposited methionine while leaving a first filtrate behind, (C) transferring part or whole of the first filtrate to step (D), (D) heating the transferred filtrate, adding a water-miscible solvent to it and saturating it with carbon dioxide gas to deposit methionine and potassium bicarbonate, and separating these deposits while leaving a second filtrate behind, and (E) returning the second filtrate to step (A) if desired.
摘要:
It is aimed at to produce 1,4-dicyano-2-butene from 2-butene-1,4-diol and/or 3-butene-1,2-diol and hydrogen cyanide with a high reaction velocity and good selectivity. 2-Butene-1,4-diol and/or 3-butene-1,2-diol are (is) reacted with hydrogen cyanide in the presence of a catalyst comprising a cuprous halide and a non-aromatic organic amine hydrohalide.
摘要:
It is aimed at to produce 1,4-dicyano-2-butene from 2-butene-1,4-diol and/or 3-butene-1,2-diol and hydrogen cyanide with a high reaction velocity and good selectivity. 2-Butene-1,4-diol and/or 3-butene-1,2-diol are (is) reacted with hydrogen cyanide in the presence of a catalyst comprising a cuprous halide and a non-aromatic organic amine hydrohalide.
摘要:
The present invention provides a method for producing 3-amino-2,2,3trimethylbutanoate which comprises reacting 3,3,4,4-tetramethylazetidine-2-one with an alcohol in the presence of an acidic compound, which has excellent operability and high yield.
摘要:
The present invention provides a method for producing 3,3,4,4-tetramethyl-2-azetidinone comprising removing a chlorosulfonyl group from 1-chlorosulfonyl-3,3,4,4-tetramethyl-2-azetidinone using an alkali compound in the presence of a phase transfer catalyst, which has excellent operability and high yield and provides easy treatment of the waste liquid.
摘要:
Methionine is produced in an improved yield while reducing the load of waste water disposal by a process including the steps of: (A) adding at least one compound selected from potassium carbonate, potassium bicarbonate and potassium hydroxide to a solution containing 5-(β-methylmercaptoethyl)hydantoin, (B) saturating the resulting solution with carbon dioxide gas and separating deposited methionine while leaving a first filtrate behind, (C) transferring part or whole of the first filtrate to step (D), (D) heating the transferred filtrate, adding a water-miscible solvent to it and saturating it with carbon dioxide gas to deposit methionine and potassium bicarbonate, and separating these deposits while leaving a second filtrate behind, and (E) returning the second filtrate to step (A) if desired.