摘要:
A process for producing a thermoplastic elastomer composition which comprises dynamically cross-linking an olefine copolymer rubber and an olefine plastic using a twin-screw extruder, said process being characterized in that said twin-screw extruder comprises one or more kneading zones within a dynamically cross-linking area and the first kneading zone among said zones comprises a screw with forward kneading disks having a minimum thickness (T min ) of less than 13 mm per disk. Said method enables production of a thermoplastic elastomer composition of good quality regardless of the scale of production.
摘要:
An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40 - 95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML1+4 100 DEG C) of 150 - 350 and 20 - 150 parts by weight of a mineral oil and (B) 5 - 60 % by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
摘要:
The present invention provides a thermoplastic elastomer composition excellent in oil resistance. This composition comprises a partially crosslinked mixture of (A) an ethylene copolymer rubber comprising ethylene and an acrylate ester or a methacrylate ester and (B) an olefin polymer and, if necessary, (C) an olefin copolymer rubber.
摘要:
An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40 - 95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML₁₊₄ 100°C) of 150 - 350 and 20 - 150 parts by weight of a mineral oil and (B) 5 - 60 % by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
摘要:
An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40 - 95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML1+4 100 DEG C) of 150 - 350 and 20 - 150 parts by weight of a mineral oil and (B) 5 - 60 % by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
摘要:
Thermoplastic elastomer compositions having excellent flexibility, mechanical properties and extrusion moldability are produced by directly feeding a particulate olefinic copolymer rubber (A) and an olefinic plastic (B) to a continuous kneading extruder to carry out melt kneading and, downstream, feeding an organic peroxide to the extruder to carry out dynamic crosslinking, the ratio of the bulk density of the particulate olefinic copolymer rubber (A) to the bulk density of the olefinic plastic (B) being in the range 0.1 to 0.9.
摘要:
An elastomer composition for covering materials excellent in light resistance and moldability, comprises a partially crosslinked mixture consisting of (A) an olefinic copolymer rubber, (B) an olefinic polymer, (C) a crystalline paraffin and (D) a mineral oil.
摘要:
A thermoplastic elastomer powder for powder molding, comprising an elastomer composition of an ethylene-a-olefin copolymer rubber and a polyolefin resin, wherein the elastomer composition has a complex dynamic viscosity η*(1) as measured at frequency of 1 radian/sec. in dynamic viscoelasticity measurement at 250°C, of 1.5 x 10 5 poise or less, a Newtonian viscosity index n calculated from the following formula by using the complex dynamic viscosity η*(1) at a frequency of 1 radian/sec. and the complex dynamic viscosity η*(100) at a frequency of 100 radian/sec. of 0.67 or less, and a hardness (shore D) of 45 or less :
摘要:
An elastomer composition for light-resistant covering materials, and covering materials for industrial parts which comprise the composition, are obtainable by partially cross-linking a mixture comprising (A) 100 parts by weight in total of at least one terpolymer rubber having a 100°C Mooney viscosity (ML₁₊₄ 100°C) of 30 to 350 selected from ethylene-propylene-dicyclopentadiene terpolymer rubbers and ethylene-butene-1-dicyclopentadiene terpolymer rubbers, (B) 5 to 150 parts by weight of an olefinic polymer and (C) 0 to 150 parts by weight of a mineral oil or a mixture comprising 40 to 95% by weight of an oil-extended ethylene terpolymer rubber and 5 to 60% by weight of an olefinic polymer, the oil-extended ethylene terpolymer rubber comprising a terpolymer rubber component comprising at least one ethylene terpolymer rubber having a 100°C Mooney viscosity (ML₁₊₄ 100°C) of 30 to 350 ethylene propylene-dicyclopentadiene terpolymer rubbers and ethylene-butene-1-dicyclopentadiene terpolymer rubbers and 150 parts by weight or less of a mineral oil per 100 parts by weight of the terpolymer rubber component.