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    Process for producing olefin polymers, olefin-polymerizing catalyst and polypropylene for biaxially oriented film produced with said catalyst
    1.
    发明公开
    Process for producing olefin polymers, olefin-polymerizing catalyst and polypropylene for biaxially oriented film produced with said catalyst 失效
    一种用于生产聚烯烃，烯烃聚合催化剂和聚丙烯与此催化剂制备双轴取向膜的方法。

    公开(公告)号：EP0657477A2

    公开(公告)日：1995-06-14

    申请号：EP94118697.5

    申请日：1994-11-28

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Ebara, Takeshi ,  Mizunuma, Koji ,  Sasaki, Toshio ,  Wakamatsu, Kazuki ,  Kimura, Junichi ,  Obata, Yoichi

    IPC分类号： C08F10/06 ,  C08F4/645

    CPC分类号： C08F110/06 ,  C08F4/6465 ,  C08F10/06 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F2500/18 ,  C08F2500/15

    摘要： An olefin polymerizing catalyst consisting of (A) a solid catalyst component containing magnesium, titanium, halogen and electron donative compound as essential components, (B) an organoaluminum compound and (C) at least two electron donative compounds including electron donative compounds (α) and (β), provided that the pentad stereoirregularity index (mmrr/mmmm) of 105°C xylene-insoluble fraction of a homopolypropyelene obtained by carrying out polymerization by the use of electron donative compound (α) together with the above-mentioned solid catalyst component (A) and organoaluminum compound (B) satisfies the following condition: 0 ≦ mmrr/mmmm ≦ 0.0068 and the pentad stereoirregularity index (mmrr/mmmm) of 105°C xylene-insoluble fraction of a homopolypropylene obtained by carrying out polymerization by the use of electron donative compound (α) together with the above-mentioned solid catalyst component (A) and organoaluminum compound (B) satisfies the following condition: 0.0068 a process for producing an olefin polymer using the catalyst; a polypropylene for use in production of a biaxially oriented film, the polypropylene being obtained by carrying out polymerization by the use of the polymerizing catalyst wherein:

    (1) 23°C decalin-soluble fraction content of the polypropylene is in the range of from 3.0 to 10.0% by weight,
    (2) the temperature at which the polypropylene shows a complex elastic modulus of 1.0 × 10⁹ dynes/cm² when a vibration of 110 Hz is applied to the polypropylene is in the range of from 134 to 152°C, and
    (3) melt flow rate (MFR) of the polypropylene at 230°C is in the range of from 0.5 to 10.0 g/10 minutes; and a biaxially oriented film obtained by subjecting the polypropylene to a stretching processing.

    摘要翻译： 一种烯烃聚合催化剂选自（A）的固体催化剂组分含有镁，钛，卤素和给电子化合物为主要成分，（B）有机铝化合物和（C）包括给电子化合物的至少两种给电子化合物（阿尔法）的 和（测试版），提供DASS管芯105°通过使用给电子化合物（阿尔法）进行聚合得到的均聚丙烯的二甲苯不溶级分的五元组立构指数（MMRR / MMMM）连同上述固体催化剂 组分（A）和有机铝化合物（B）SATIS外资企业以下条件：0 达因/厘米<2>当110赫兹的振动被施加到所述聚丙烯是在从范围 134至152℃，和（3）熔体流动速率的聚丙烯的（MFR）在230℃下为0.5〜10.0克/ 10分钟的范围内; 和双轴取向膜得到的通过对聚丙烯拉伸加工。

    Alpha-olefin polymers, alpha-olefin polymerizing catalyst and process for producing alpha-olefin polymers
    2.
    发明公开
    Alpha-olefin polymers, alpha-olefin polymerizing catalyst and process for producing alpha-olefin polymers 失效
    α-烯烃聚合物，Katalysator zur Alpha烯烃聚合和Verfahren zur Herstellung von Alphafinspolymeren。

    公开(公告)号：EP0657476A2

    公开(公告)日：1995-06-14

    申请号：EP94118696.7

    申请日：1994-11-28

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Ebara, Takeshi ,  Mizunuma, Koji ,  Sasaki, Toshio ,  Wakamatsu, Kazuki ,  Kimura, Junichi ,  Obata, Yoichi

    IPC分类号： C08F10/00 ,  C08F10/06 ,  C08F4/645

    CPC分类号： C08F110/06 ,  C08F10/00 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F4/6465

    摘要： An α-olefin polymer well balanced between stiffness, stickiness, processability, etc., which intrinsic viscosity [η] is in the range of from 0.5 to 10 and which 20°C xylene-soluble fraction (CXS) content (% by weight) and 105°C xylene-insoluble fraction (XIS) content (% by weight) satisfy a condition of XIS ≦ 70.00 - 3.64CXS, provided that CXS is not smaller than 0 and not greater than 15; a specified α-olefin polymerizing catalyst for producing the polymer; a process for producing the polymer using the specified α-olefin polymerizing catalyst; a polypropylene for use in the production of a biaxially oriented film excellent in stretchability and satisfying the conditions (1)-(3) mentioned below; and a biaxially oriented film excellent in stiffness and dimensional stability obtained by stretching the polypropylene:

    (1) the content of 20°C xylene-soluble fraction (CXS) is 3.5% by weight or less,
    (2) the content of 20°C xylene-soluble fraction (CXS, % by weight) and the content of 105°C xylene-insoluble fraction (XIS, % by weight) satisfy the following condition: XIS ≦ 70.00 - 3.64CXS, and
    (3) melt flow rate (MFR) at 230°C is from 0.5 to 10.0 g/10 minutes.

    摘要翻译： 在特性粘度η在0.5至10范围内以及20℃二甲苯可溶级分（CXS）含量（重量％）的硬度，粘性，加工性等之间良好平衡的α-烯烃聚合物， 和105℃二甲苯不溶级分（XIS）含量（重量％）满足XIS≤70.00-3.64CXS的条件，条件是CXS不小于0且不大于15; 用于制备聚合物的特定的α-烯烃聚合催化剂; 使用特定的α-烯烃聚合催化剂制备聚合物的方法; 用于生产拉伸性优异并满足下述条件（1） - （3）的双轴取向膜的聚丙烯; 和通过拉伸聚丙烯获得的刚性和尺寸稳定性优异的双轴取向膜：（1）20℃二甲苯可溶成分（CXS）的含量为3.5重量％以下，（2）20℃ 二甲苯可溶级分（CXS，重量％）和105℃二甲苯不溶级分（XIS，重量％）的含量满足以下条件：XIS = 70.00-3.64CXS，和（3）熔体流动速率 （MFR）在230℃为0.5〜10.0g / 10分钟。

    Polypropylene laminated film
    4.
    发明公开
    Polypropylene laminated film 失效
    Schichtfilm aus聚丙烯。

    公开(公告)号：EP0659552A1

    公开(公告)日：1995-06-28

    申请号：EP94309384.9

    申请日：1994-12-15

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Wakamatsu, Kazuki ,  Kimura, Junichi ,  Satoh, Makoto ,  Obata, Yoichi ,  Takane, Minoru

    IPC分类号： B32B27/32 ,  C08L23/16

    CPC分类号： B32B27/08 ,  B32B27/32 ,  B32B2250/242 ,  B32B2307/516 ,  B32B2307/518 ,  B32B2307/704 ,  B32B2309/02 ,  B32B2309/105 ,  B32B2309/12 ,  C08F210/06 ,  C08L23/14 ,  C08L23/142 ,  Y10T428/2495 ,  Y10T428/26 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31938 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/26

    摘要： A polypropylene laminated film containing a crystalline polypropylene layer and, laminated on at least one side of the layer of the crystalline polypropylene, a layer of a copolymer of propylene and at least one α-olefin of from 4 to 10 carbon atoms having a specific composition, melt flow rate and molecular weight distribution in which the α-olefin content in the cold xylene soluble portion of the random copolymer is less than 1.7 times the α-olefin content in the copolymer and the random copolymer satisfies the mathematical expression, B ≦ 1.05A - 10,
    wherein A is a weight percentage of the content of said at least one α-olefin having from 4 to 10 carbon atoms in the random copolymer and B is a weight percentage of the cold xylene soluble portion in the random copolymer, is superior in low temperature heat sealability and hot tack property and moreover has a good transparency, blocking resistance and printability, wherein the random copolymer is obtained by gas phase polymerization substantially in the absence of a liquid medium, and using a catalyst system comprising (i) a solid catalyst component containing magnesium, titanium and a halogen as essential constituents, (ii) an organoaluminum compound and (iii) an electron donative compound.

    摘要翻译： 一种聚丙烯层压膜，其含有结晶聚丙烯层，层压在该结晶聚丙烯层的至少一侧上，具有丙烯与至少一种具有特定组成的4-10个碳原子的至少一种α-烯烃的共聚物层 ，熔体流动速率和分子量分布，其中无规共聚物的冷二甲苯可溶部分中的α-烯烃含量小于共聚物中α-烯烃含量的1.7倍，无规共聚物满足数学表达式， 其中A是无规共聚物中所述至少一种具有4至10个碳原子的α-烯烃的含量的重量百分比，B是无规共聚物中冷二甲苯可溶部分的重量百分比，在低温下是优异的 热封性和热粘性，而且具有良好的透明性，耐粘连性和可印刷性，其中无规共聚物由气相聚 并且使用包含（i）含有镁，钛和卤素作为必要组分的固体催化剂组分的催化剂体系，（ii）有机铝化合物和（iii）给电子化合物。

    Alpha-olefin polymers, alpha olefin-polymerizing catalyst and process for producing alpha-olefin polymers
    6.
    发明公开
    Alpha-olefin polymers, alpha olefin-polymerizing catalyst and process for producing alpha-olefin polymers 失效
    α-烯烃聚合物，α-烯烃聚合催化剂和生产α-烯烃聚合物的方法

    公开(公告)号：EP0844259A1

    公开(公告)日：1998-05-27

    申请号：EP97118079.9

    申请日：1994-11-28

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Ebara, Takeshi ,  Mizunuma, Koji ,  Sasaki, Toshio ,  Wakamatsu, Kazuki ,  Kimura, Junichi ,  Obata, Yoichi

    IPC分类号： C08F10/00 ,  C08F10/06 ,  C08F4/645

    CPC分类号： C08F110/06 ,  C08F10/00 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F4/6465

    摘要： There is described an α-olefin polymerizing catalyst consisting of

    (A) a solid catalyst component containing magnesium, titanium, halogen and an electron donative compound as essential components,
    (B) an organoaluminum compound, and
    (C) an electron donative compound component,
    for use in the production of an α-olefin polymer which is an α-olefin polymer obtained by polymerizing an α-olefin having 3 or more carbon atoms and satisfying the following conditions:

    the intrinsic viscosity [η] of said polymer is not lower than 0.5 and not higher than 10, and
    20°C xylene-soluble fraction (CXS) content (% by weight) and 105°C xylene-insoluble fraction (XIS) content (% by weight) of said polymer satisfy the following condition: XIS ≤ 70.00 - 3.64CXS provided that CXS is not smaller than 0 and not greater than 15.

    摘要翻译： （A）含有镁，钛，卤素和电子给体化合物作为必需组分的固体催化剂组分，（B）有机铝化合物和（C）给电子化合物组分组成的α-烯烃聚合催化剂， 用于生产α-烯烃聚合物，该α-烯烃聚合物是通过聚合具有3个或更多个碳原子的α-烯烃并且满足以下条件而获得的α-烯烃聚合物：所述聚合物的特性粘度[η]不低于 0.5且不高于10，并且所述聚合物的20℃二甲苯可溶部分（CXS）含量（重量％）和105℃二甲苯不溶部分（XIS）含量（重量％）满足以下条件：XIS 只要CXS不小于0且不大于15，则≤70.00 - 3.64CXS。

    Process for producing olefin polymers, olefin-polymerizing catalyst and polypropylene for biaxially oriented film produced with said catalyst
    7.
    发明公开
    Process for producing olefin polymers, olefin-polymerizing catalyst and polypropylene for biaxially oriented film produced with said catalyst 失效
    一种用于生产聚烯烃，烯烃聚合催化剂和聚丙烯与此催化剂制备双轴取向膜的方法。

    公开(公告)号：EP0657477A3

    公开(公告)日：1995-11-22

    申请号：EP94118697.5

    申请日：1994-11-28

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Ebara, Takeshi ,  Mizunuma, Koji ,  Sasaki, Toshio ,  Wakamatsu, Kazuki ,  Kimura, Junichi ,  Obata, Yoichi

    IPC分类号： C08F10/06 ,  C08F4/645

    CPC分类号： C08F110/06 ,  C08F4/6465 ,  C08F10/06 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26 ,  C08F2500/18 ,  C08F2500/15

    摘要： An olefin polymerizing catalyst consisting of (A) a solid catalyst component containing magnesium, titanium, halogen and electron donative compound as essential components, (B) an organoaluminum compound and (C) at least two electron donative compounds including electron donative compounds (α) and (β), provided that the pentad stereoirregularity index (mmrr/mmmm) of 105°C xylene-insoluble fraction of a homopolypropyelene obtained by carrying out polymerization by the use of electron donative compound (α) together with the above-mentioned solid catalyst component (A) and organoaluminum compound (B) satisfies the following condition: 0 ≦ mmrr/mmmm ≦ 0.0068 and the pentad stereoirregularity index (mmrr/mmmm) of 105°C xylene-insoluble fraction of a homopolypropylene obtained by carrying out polymerization by the use of electron donative compound (α) together with the above-mentioned solid catalyst component (A) and organoaluminum compound (B) satisfies the following condition: 0.0068 a process for producing an olefin polymer using the catalyst; a polypropylene for use in production of a biaxially oriented film, the polypropylene being obtained by carrying out polymerization by the use of the polymerizing catalyst wherein:
    (1) 23°C decalin-soluble fraction content of the polypropylene is in the range of from 3.0 to 10.0% by weight, (2) the temperature at which the polypropylene shows a complex elastic modulus of 1.0 × 10⁹ dynes/cm² when a vibration of 110 Hz is applied to the polypropylene is in the range of from 134 to 152°C, and (3) melt flow rate (MFR) of the polypropylene at 230°C is in the range of from 0.5 to 10.0 g/10 minutes; and a biaxially oriented film obtained by subjecting the polypropylene to a stretching processing.