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1.发明公开Catalysts for hydrotreating of hydrocarbons and methods of preparing the same 失效Kohlenwasserstoffbehandlungskatalysatoren和Verfahren zu deren Herstellung。
公开(公告)号：EP0357295A2
公开(公告)日：1990-03-07
申请号：EP89308329.5
申请日：1989-08-15
IPC分类号： C10G49/04
摘要： Disclosed are catalysts for hydrotreating hydrocarbons and methods for preparing the same, and the catalyst is composed of a carrier substance consisting essentially of an oxide of aluminium and/or an oxide hydrate of aluminium, at least one selected from water-soluble compounds of metals of Group VI and Group VIII of the Periodic Table and at least one organic compounds selected from mercapto-carboxylic acids of formula HS-(CH₂) n -COOR (where n is 1 to 3; R is H, alkali metal, alkaline earth metal or ammonium gorup or alkyl group with 1-10 carbons), thio-acids of formula R′-COSH (where R′ is monovalent hydorcarbon with 1-15 carbons), amino-substituted mercaptans of formula H₂N-R˝-SH (R˝ is divalent hydrocarbon with 1-15 carbons), dimercaptans of formula HS-R˝-SH (R˝ is same as above) and mercapto-alcohols of formula (RaS-R‴-(OH) n (where R‴ is hydrocarbon with 1-15 carbons; Ra is H or alkyl group with 1-2 carbons; and n is 1-2), and optionally phosphoric acid. The catalyst requires neither presulfurization nor heat-treatment and can directly be applied to hydrotreating hydrocarbons.
摘要翻译： 公开了用于加氢处理烃的催化剂及其制备方法，催化剂由主要由铝的氧化物和/或铝的氧化物水合物组成的载体物质组成，至少一种选自水溶性金属化合物 元素周期表第VI族和第VIII族和选自式HS-（CH 2）n -COOR（其中n为1至3; R为H，碱金属，碱土金属或碱金属）的巯基羧酸的至少一种有机化合物 氨基铵或具有1-10个碳的烷基），式R min -COSH（其中R min是具有1-15个碳的一价氢碳）的硫代酸，式H2N-R sec -SH的氨基取代的硫醇（R sec 是具有1-15个碳原子的二价烃），式HS-R sec -SH的二硫醇（R sec与上述相同）和式（RaS-R“ - （OH）n（其中R” '是具有1-15个碳原子的烃; R a是H或具有1-2个碳的烷基; n是1-2），和任选地是磷酸。 催化剂既不需要预硫化也不需要热处理，可以直接用于加氢处理烃。
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2.发明公开Catalysts for hydrotreating hydrocarbons and method of activating the same 失效Katalysatoren zur hydrierenden Behandlung von Kohlenwasserstoffen und deren Aktivierung。
公开(公告)号：EP0289211A1
公开(公告)日：1988-11-02
申请号：EP88303592.5
申请日：1988-04-21
IPC分类号： B01J31/02 , B01J37/20 , B01J27/049 , B01J27/051 , C10G45/08 , C10G49/04
CPC分类号： B01J31/0217 , B01J21/04 , B01J23/85 , B01J23/883 , B01J27/188 , B01J31/0237 , B01J31/0271 , B01J31/28 , B01J35/1019 , B01J35/1042 , B01J37/20 , C10G45/08
摘要： New supported catalysts for hydrotreating hydrocarbons comprise (a) at least one member selected from the group consisting of oxides of metals in the Periodic Table's Groups VI and VIII, and (b) at least one organic compound having a mercapto radical or radicals ( -SH ) selected from the group consisting of mercapto-carboxylic acids ( including alkali metal, alkaline earth metal and ammonium salts thereof, and esters thereof ), bivalent mercaptans, amino-substituted mercaptans, and thiocarboxylic acids. These new catalysts can be easily activated by treatment in the presence of hydrogen gas at a temperature in the range from room temperature to 400°C, showing higher activity than those activated by conventional methods.
摘要翻译： 用于加氢处理烃的新的负载催化剂包括（a）选自周期表第VI和VIII族中的金属氧化物中的至少一种，和（b）至少一种具有巯基或基团的有机化合物（-SH ），选自巯基羧酸（包括碱金属，碱土金属及其铵盐及其酯），二价硫醇，氨基取代的硫醇和硫代羧酸。 这些新催化剂可以通过在室温至400℃的温度下在氢气存在下进行处理而容易地活化，显示比通过常规方法活化的活性更高的活性。
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3.发明公开Catalyst for hydrotreatment of hydrocarbons and method for production thereof 失效Katalysator zur Wasserstoffbehandlung von Kohlenwasserstoffen und Methode zu dessen Herstellung。
公开(公告)号：EP0300629A1
公开(公告)日：1989-01-25
申请号：EP88306010.5
申请日：1988-07-01
CPC分类号： B01J31/0217 , B01J23/88 , B01J23/882 , B01J23/888 , B01J27/188 , B01J31/04 , B01J31/34 , B01J37/20 , C10G49/02 , C10G49/04
摘要： A catalyst for the hydrotreatment of a hydrocarbon oil comprises a carrier of an inorganic oxide and an active component supprted on the carrier and formed of at least one member selected from the group consisting of water-soluble compounds of molybdenum, tungsten, and the metal of Group 8 in the Periodic Table of Elements and at least one mercapto (-SH) group-containing organic compound selected from the group consisting a mercaptocarboxylic acids represented by the general formula:
HS-(CH₂) n -COOR
(wherein n stands for an integer in the range of 1 to 3 and R for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched naphthenic alkyl group having 1 to 10 carbon atoms), amino-substituted mercaptans represented by the general formula:
H₂N-R′-SH
(wherein R′ stands for a divalent hydrocarbon group), divalent mercaptans represented by the general formula:
HS-R′-SH
(wherein R′ stands for a divalent hydrocarbon group), and thio acids represented by the general formula:
R˝-COSH
(wherein R˝ stands for a monovalent hydrocarbon group).摘要翻译： 用于烃油的加氢处理的催化剂包括无机氧化物的载体和载体上的活性成分，并由至少一种选自钼，钨的水溶性化合物和 元素周期表中的第8族和选自由以下通式表示的巯基羧酸的至少一种巯基（-SH）基的有机化合物：HS-（CH 2）n -COOR（其中n表示 1〜3的整数，R 1为氢原子，碱金属，碱土金属，铵或碳原子数1〜10的直链状或支链状的环烷基），由通式 式中：H 2 N-R min -SH（其中R min表示二价烃基），由通式HS-R min -SH（其中R min表示二价烃基）表示的二价硫醇，硫代酸 由下式通式表示：R sec -COSH（其中R sec表示一价烃基）。
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公开(公告)号：EP0289211B1
公开(公告)日：1993-09-29
申请号：EP88303592.5
申请日：1988-04-21
IPC分类号： B01J31/02 , B01J37/20 , B01J27/049 , B01J27/051 , C10G45/08 , C10G49/04
CPC分类号： B01J31/0217 , B01J21/04 , B01J23/85 , B01J23/883 , B01J27/188 , B01J31/0237 , B01J31/0271 , B01J31/28 , B01J35/1019 , B01J35/1042 , B01J37/20 , C10G45/08
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5.发明公开A catalyst for hydrotreating hydrocarbons and methods of activating the same 失效催化剂用于烃的加氢处理和加氢工艺进行激活。
公开(公告)号：EP0506206A1
公开(公告)日：1992-09-30
申请号：EP92201346.1
申请日：1988-04-21
CPC分类号： B01J31/0217 , B01J21/04 , B01J23/85 , B01J23/883 , B01J27/188 , B01J31/0237 , B01J31/0271 , B01J31/28 , B01J35/1019 , B01J35/1042 , B01J37/20 , C10G45/08
摘要： New supported catalysts for hydrotreating hydrocarbons comprise (a) at least one member selected from the group consisting of oxides of metals in the Periodic Table's Groups VI and VIII, and (b) at least one organic compound having a mercapto radical or radicals (-SH) selected from bivalent mercaptans, amino-substituted mercaptans, and thiocarboxylic acids. These new catalysts can be easily activated by treatment in the presence of hydrogen gas at a temperature in the range from room temperature to 400°C, showing higher activity than those activated by conventional methods.
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6.发明授权
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公开(公告)号：EP0338788B1
公开(公告)日：1992-04-22
申请号：EP89303855.4
申请日：1989-04-19
CPC分类号： B01J31/26 , B01J21/04 , B01J23/85 , B01J23/883 , B01J31/0217 , B01J31/0218 , B01J31/04 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J37/20 , C10G45/08
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8.发明授权
公开(公告)号：EP0300629B1
公开(公告)日：1991-01-23
申请号：EP88306010.5
申请日：1988-07-01
CPC分类号： B01J31/0217 , B01J23/88 , B01J23/882 , B01J23/888 , B01J27/188 , B01J31/04 , B01J31/34 , B01J37/20 , C10G49/02 , C10G49/04
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9.发明公开
公开(公告)号：EP0357295A3
公开(公告)日：1990-03-28
申请号：EP89308329.5
申请日：1989-08-15
IPC分类号： C10G49/04
摘要： Disclosed are catalysts for hydrotreating hydrocarbons and methods for preparing the same, and the catalyst is composed of a carrier substance consisting essentially of an oxide of aluminium and/or an oxide hydrate of aluminium, at least one selected from water-soluble compounds of metals of Group VI and Group VIII of the Periodic Table and at least one organic compounds selected from mercapto-carboxylic acids of formula HS-(CH₂) n -COOR (where n is 1 to 3; R is H, alkali metal, alkaline earth metal or ammonium gorup or alkyl group with 1-10 carbons), thio-acids of formula R′-COSH (where R′ is monovalent hydorcarbon with 1-15 carbons), amino-substituted mercaptans of formula H₂N-R˝-SH (R˝ is divalent hydrocarbon with 1-15 carbons), dimercaptans of formula HS-R˝-SH (R˝ is same as above) and mercapto-alcohols of formula (RaS-R‴-(OH) n (where R‴ is hydrocarbon with 1-15 carbons; Ra is H or alkyl group with 1-2 carbons; and n is 1-2), and optionally phosphoric acid. The catalyst requires neither presulfurization nor heat-treatment and can directly be applied to hydrotreating hydrocarbons.
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10.发明公开Catalyst for hydrotreating hydrocarbons 失效Katalysator zur Wasserstoffbehandlung von Kohlenwasserstoffen。
公开(公告)号：EP0338788A1
公开(公告)日：1989-10-25
申请号：EP89303855.4
申请日：1989-04-19
CPC分类号： B01J31/26 , B01J21/04 , B01J23/85 , B01J23/883 , B01J31/0217 , B01J31/0218 , B01J31/04 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J37/20 , C10G45/08
摘要： There is disclosed a catalyst which hydrotreats hydrocarbons without need of presulfiding The catalyst comprises a carrier of an inorganic oxide containing a sulfurizing agent and a water-soluble compound of two metals one of which belongs to the Group VI of the Periodic Table, while the other belongs to the Group VIII. The carrier has pores in which a precursor of a sulfide is formed. The coordination number of the closest Group VI metal found from the radial distribution function around the Group VI metal is less than 0.25. The function is obtained from the Fourier transform of the extended x-ray absorption fine structure of the precursor.
摘要翻译： 公开了不需要预硫化氢化烃的催化剂。该催化剂包含含有硫化剂的无机氧化物的载体和两种金属的水溶性化合物，其中一种属于周期表第VI族，而另一种 属于第八组。 载体具有形成硫化物前体的孔。 从VI族金属周围的径向分布函数中发现的最接近的VI族金属的配位数小于0.25。 该功能从前体的扩展的x射线吸收精细结构的傅里叶变换获得。
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