摘要:
An electrolyte for a secondary battery includes a non-aqueous solvent; a lithium salt; and a heterocyclic compound represented by Formula 1:
wherein, in Formula 1, R 1 and R 2 are each independently selected from hydrogen, a halogen group, a cyano group, a hydroxy group, a nitro group, -C(=O)R a , - C(=O)OR a , -OCO(OR a ), -C=N(R a ), a substituted or unsubstituted C 1 -C 20 alkyl group, and a combination thereof, wherein R a is selected from hydrogen and a C 1 -C 10 alkyl group, and, provided that at least one selected from R 1 and R 2 is selected from a halogen group, a cyano group, a hydroxy group, a nitro group, -C(=O)R a , -C(=O)OR a , a substituted or unsubstituted C 1 -C 20 alkyl group, and a combination thereof.
摘要:
Provided herein is a lithium battery including: a cathode; an anode; and an electrolyte between the cathode and the anode, wherein the cathode includes a cathode active material represented by Formula 1, and the electrolyte includes a lithium salt, a non-aqueous solvent, and an unsaturated compound represented by Formula 2:
Li x Ni y M 1-y O 2-z A z
wherein definitions of x, y, z, M, A, Q 1 , and Q 2 in Formulae 1 and 2 are the same as those described in the detailed description of the present specification.
摘要:
An organic electrolyte solution includes a lithium salt; an organic solvent; and a fluorine-containing phosphate compound represented by Formula 1:
wherein, in Formula 1, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 R 11 , R 12 , R 13 , R 14 , and R 15 are each independently a hydrogen atom, a fluorine atom, a C1-C5 alkyl group substituted or not substituted with a halogen atom, a C4-C10 cycloalkyl group substituted or not substituted with a halogen atom, a C6-C10 aryl group substituted or not substituted with a halogen atom, a C2-C10 heteroaryl group substituted or not substituted with a halogen atom, or a C2-C10 alkenyl group substituted or not substituted with a halogen atom, at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , Rg, R 10 , R 11 , R 12 , R 13 , R 14 , or R 15 is a fluorine atom, and at least one phenyl group does not have a fluorine atom.
摘要:
The present invention relates to a lithium secondary battery including an electrolyte additive and method of preparing the lithium secondary battery. A lithium secondary battery includes: a positive electrode; a negative electrode; and an electrolyte between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material represented by Formula 1, and the electrolyte includes a lithium salt, a non-aqueous solvent, and a sulfone compound represented by Formula 2.
Formula 1 Li x Ni y M 1-y O 2-z A z
wherein, in Formula 1, 0.9≤x≤1.2, 0.7≤y≤0.98, 0≤z 1 and R 2 are each independently a halogen, an unsubstituted C 1 -C 10 alkyl group, or a C 1 -C 10 alkyl group substituted with a halogen, and a1 and a2 are each independently an integer from 0 to 5.
摘要:
Provided are a lithium battery including an electrolyte including an alkyl sulfonate compound represented by Formula 2 below, an electrolyte including an alkyl sulfonate compound represented by Formula 2 below and an unsaturated sulfone compound represented by Formula 3 below, and a lithium battery including the electrolyte.
wherein, in Formulae 2 and 3, Q 1 , Q 2 , Q 3 , and Q 4 are the same as defined above in the detailed description.
摘要:
Provided are a lithium battery including an electrolyte including an alkyl sulfonate compound represented by Formula 2 below, an electrolyte including an alkyl sulfonate compound represented by Formula 2 below and an unsaturated sulfone compound represented by Formula 3 below, and a lithium battery including the electrolyte.
wherein, in Formulae 2 and 3, Q 1 , Q 2 , Q 3 , and Q 4 are the same as defined above in the detailed description.
摘要:
Provided are an electrolyte additive for a lithium battery, which is a sulfone compound represented by Formula 1, an organic electrolyte solution including the same, and a lithium battery including the same:
wherein, in Formula 1, R 1 is a halogen-substituted or unsubstituted C1-C5 alkyl group, a halogen-substituted or unsubstituted C4-C10 cycloalkyl group, a halogen-substituted or unsubstituted C5-C10 aryl group, or a halogen-substituted or unsubstituted C2-C10 heteroaryl group, and R 2 is a halogen-substituted or unsubstituted C2-C10 alkenyl group.