NICKEL-BASED METAL OXIDE FOR LITHIUM SECONDARY BATTERY, NICKEL-BASED ACTIVE MATERIAL FORMED FROM THE NICKEL-BASED METAL OXIDE, METHOD OF PREPARING THE SAME, AND LITHIUM SECONDARY BATTERY INCLUDING CATHODE INCLUDING THE NICKEL-BASED ACTIVE MATERIAL

    公开(公告)号:EP4032861A1

    公开(公告)日:2022-07-27

    申请号:EP21214506.4

    申请日:2021-12-14

    IPC分类号: C01G53/00 H01M4/525

    摘要: A nickel-based metal oxide for a lithium secondary battery, a nickel-based active material obtained from the nickel-based metal oxide, a method of preparing the nickel-based metal oxide, and a lithium secondary battery including the nickel-based metal oxide as a cathode are provided. The nickel-based metal oxide for a lithium secondary battery includes a cubic composite phase, wherein the cubic composite phase includes a metal oxide phase represented by Formula 1 and a metal oxide phase represented by Formula 2:

            Formula 1     Ni 1-x-z-k M k Li x Co z O 1-y ,

    wherein, in Formula 1, M is at least one element selected from the group consisting of boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminium (Al), 0≤x≤0.1, 0≤y≤0.1, 0≤z≤0.5, and 0≤k≤0.5

            Formula 2     Ni 6-x-z-k M k Li x Co z MnO 8-y ,

    and wherein, in Formula 2, M is at least one element selected from the group consisting of boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminium (Al), 0≤x≤0.1, 0≤y≤0.1, 0≤z≤0.5, and 0≤k≤0.5, and the case where x of Formula 1 and x of Formula 2 are 0 at the same time is excluded.