摘要:
The present invention is directed to a method and a system for separating gas components of a gas containing a plurality of gaseous components. A compressible feed stream containing at least one target compressible component and at least one non-target compressible component is mixed in a substantially co-current flow with an incompressible fluid stream comprising an incompressible fluid in which the target component(s) is/are capable of being preferentially absorbed. Rotational velocity is imparted to the mixed streams, separating an incompressible fluid in which at least a portion of the target component is absorbed from a compressible product stream containing the non-target compressible component(s). The compressible feed stream may be provided at a stream velocity having a Mach number of at least 0.1.
摘要:
The present invention is directed to a method and a system for separating gas components of a combustion gas. A compressible feed stream derived from a combustion gas that contains at least one target compressible component and at least one non-target compressible component is mixed e.g. in a substantially co-current flow with an incompressible fluid stream comprising an incompressible fluid in which the target component(s) is/are capable of being preferentially absorbed. Rotational velocity is imparted to the mixed streams, separating an incompressible fluid in which at least a portion of the target component is absorbed from a compressible product stream containing the non-target compressible component(s). The compressible feed stream may be provided at a stream velocity having a Mach number of at least 0.1.
摘要:
The present invention is directed to systems and processes of operating molten carbonate fuel cell systems. A process for operating the molten carbonate fuel cell includes providing a hydrogen-containing stream comprising molecular hydrogen from a high temperature hydrogen-separation device to a molten carbonate fuel cell, wherein the high temperature hydrogen-separation device comprises one or more high temperature hydrogen-separating membranes; mixing at least a portion of hydrocarbons to be provided to, or provided to, a first reformer with anode exhaust from the molten carbonate fuel cell; at least partially reforming some of the hydrocarbons in the first reformer to produce a steam reforming feed; and providing the steam reforming feed to a second reformer, wherein the second reformer comprises the high temperature hydrogen-separation device or the second reformer is operatively coupled to the high temperature hydrogen-separation device, and the high temperature hydrogen-separation device is configured to produce at least a portion of the stream comprising molecular hydrogen provided to the molten carbonate fuel cell.
摘要:
The present invention is directed to systems and processes for operating molten carbonate fuel cell systems. A process for operating the molten carbonate fuel cell includes providing a hydrogen-containing stream comprising molecular hydrogen to a molten carbonate fuel cell anode; heating a hydrocarbon stream, at least a majority of which is comprised of hydrocarbons that are liquid at 20 C and atmospheric pressure, with a heat source comprising an anode exhaust from the molten carbonate fuel cell anode; contacting at least a portion of the heated hydrocarbon stream with a catalyst to produce a steam reforming feed comprising gaseous hydrocarbons, hydrogen, and at least one carbon oxide; separating at least a portion of the molecular hydrogen from the steam reforming feed; and providing at least a portion of the separated molecular hydrogen to the molten carbonate fuel cell anode as at least a portion of the stream comprising molecular hydrogen.
摘要:
The present invention provides a method for recovering a natural gas contaminated with high levels of carbon dioxide. A gas containing methane and carbon dioxide is extracted from a reservoir containing natural gas, where carbon dioxide comprises greater than 40 vol.% of the extracted gas. The extracted gas is scrubbed with a wash effective to produce a washed extracted gas containing less carbon dioxide than the extracted gas and at least 20 vol.% carbon dioxide. The washed extracted gas is oxidized with an oxygen containing gas in the presence of a partial oxidation catalyst to produce an oxidation product gas containing hydrogen, carbon monoxide, and carbon dioxide. The oxidation product gas is then utilized to produce a liquid methanol product.
摘要:
The present invention is directed to low emission power plant. A compressible feed stream is provided that is derived from a power production unit, where the compressible feed stream contains at least one target compressible component and at least one non-target compressible component, is mixed in a substantially co-current flow with an incompressible fluid stream comprising an incompressible fluid in which the target component (s) is/are capable of being preferentially absorbed. Rotational velocity is imparted to the mixed streams, separating an incompressible fluid in which at least a portion of the target component is absorbed from a compressible product stream containing the non-target compressible component ( s ). The compressible feed stream may be provided at a stream velocity having a Mach number of at least 0.1.
摘要:
Processes and systems for operating molten carbonate fuel cell systems are described herein. A process for operating a molten carbonate fuel cell system includes providing a hydrogen-containing stream comprising molecular hydrogen to an anode portion of a molten carbonate fuel cell; controlling a flow rate of the hydrogen-containing stream to the anode such that molecular hydrogen utilization in the anode is less than 50%; mixing anode exhaust comprising molecular hydrogen from the molten carbonate fuel cell with a hydrocarbon stream comprising hydrocarbons, contacting at least a portion of the mixture of anode exhaust and the hydrocarbon stream with a catalyst to produce a steam reforming feed; separating at least a portion of molecular hydrogen from the steam reforming feed; and providing at least a portion of the separated molecular hydrogen to the molten carbonate fuel cell anode.
摘要:
This invention relates to a process and apparatus for the production of pure hydrogen by steam reforming. The process integrates the steam reforming and shift reaction to produce pure hydrogen with minimal production of CO and virtually no CO in the hydrogen stream, provides for CO2 capture for sequestration, employs a steam reforming membrane reactor, and is powered by heat from the convection section of a heater.
摘要:
The present invention relates to a solid oxide fuel cell system. The system includes a pre-reforming reactor, a reforming reactor, a hydrogen separation apparatus and a solid oxide fuel cell. The anode exhaust outlet of the solid oxide fuel cell is operatively connected to an inlet of the pre-reforming reactor so anode exhaust from the fuel cell may enter the pre-reforming reactor. The pre-reforming reactor also has an inlet for a hydrocarbon feed precursor. The reforming reactor is operatively coupled to the pre-reforming reactor so that a feed produced in the pre-reforming reactor from the feed precursor may be fed to the reforming reactor. The reforming reactor is operatively connected to the hydrogen separation apparatus so that hydrogen produced in the reforming reactor may be separated from the reformed product gases. The anode inlet of the solid oxide fuel cell is operatively connected to the hydrogen separation apparatus so hydrogen may be fed from the hydrogen separation apparatus as fuel to the solid oxide fuel cell.
摘要:
The present invention is directed to a solid oxide fuel cell system for generating electrical power. The system comprises a solid oxide fuel cell, a reforming reactor, a hydrogen separation apparatus, and an anode exhaust conduit. The reforming reactor includes a reforming region in which a feed comprising one or more hydrocarbons may be steam reformed to produce a reformed product gas containing hydrogen. The hydrogen separation apparatus is located in the reforming reactor positioned to separate hydrogen from the reformed product gas produced in the reforming reactor. The hydrogen separation apparatus is operatively connected to the anode of the solid oxide fuel cell to provide hydrogen to the fuel cell as a fuel to be oxidized to produce electricity. The anode exhaust conduit is located in the reforming region of the reforming reactor and is operatively connected to the anode exhaust of the fuel cell so that hot anode exhaust exiting the fuel cell may pass through the anode exhaust conduit and exchange heat with reactants in the reforming region of the reforming reactor.