公开(公告)号：EP2727923B1

公开(公告)日：2017-10-18

申请号：EP12804224.9

申请日：2012-06-28

申请人： Shimada, Toyoshi ,  Daicel Corporation

发明人： SHIMADA, Toyoshi

IPC分类号： C07F7/08 ,  C07H15/18 ,  C08B11/187 ,  C08B37/16 ,  C09K3/18 ,  C07H23/00 ,  C08B15/00 ,  C08J3/12 ,  C09C3/12 ,  C08K9/06 ,  C08K9/08 ,  C08B15/05 ,  C08J7/16 ,  C03C17/30

CPC分类号： C07F7/0818 ,  C03C17/30 ,  C03C2217/75 ,  C07F7/081 ,  C07F7/0812 ,  C07H23/00 ,  C08B15/05 ,  C08B37/0012 ,  C08J3/126 ,  C08J3/128 ,  C08K9/06 ,  C08K9/08 ,  C09C3/12 ,  C09K3/18

公开(公告)号：EP2727923A1

公开(公告)日：2014-05-07

申请号：EP12804224.9

申请日：2012-06-28

申请人： Shimada, Toyoshi ,  Kyoeisha Chemical Co., Ltd. ,  Daicel Corporation

发明人： SHIMADA, Toyoshi

IPC分类号： C07F7/08 ,  C07H15/18 ,  C08B11/187 ,  C08B37/16 ,  C09K3/18

CPC分类号： C07F7/0818 ,  C03C17/30 ,  C03C2217/75 ,  C07F7/081 ,  C07F7/0812 ,  C07H23/00 ,  C08B15/05 ,  C08B37/0012 ,  C08J3/126 ,  C08J3/128 ,  C08K9/06 ,  C08K9/08 ,  C09C3/12 ,  C09K3/18

摘要： Provided are: a (meth)allylsilane compound that is chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is a raw material that is used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate.
The (meth)allylsilane compound comprises a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.

公开(公告)号：EP2050776A1

公开(公告)日：2009-04-22

申请号：EP07738317.2

申请日：2007-03-12

申请人： Kyoeisha Chemical Co., Ltd. ,  Shimada, Toyoshi

发明人： SHIMADA, Toyoshi ,  TAKENAKA, Naomi ,  GOSHIMA, Gakuto ,  HOSOI, Hiroyuki

IPC分类号： C08G61/12 ,  C07C45/68 ,  C07C49/657 ,  C07C51/36 ,  C07C55/02 ,  C08F120/10 ,  C07B53/00 ,  C07B61/00 ,  C07F9/50

CPC分类号： C07F9/5027 ,  B01J31/1658 ,  B01J31/2452 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2531/0266 ,  B01J2531/822 ,  C07B53/00 ,  C07C45/69 ,  C08F222/1006 ,  C08G61/12 ,  C08G63/00 ,  C08G63/6924 ,  C08G2261/344 ,  C08G2261/413 ,  C07C49/657

摘要： A polymer having bis(diphenylphosphino)binaphthyl groups that can be used as a catalyst for an addition reaction, especially an asymmetric 1,4-addition reaction, or a reduction reaction, especially an asymmetric reduction reaction, and that can be easily recovered and recycled. The polymer having the bis(diphenylphosphino)binaphthyl groups is one resulting from repetition of a racemic or optically active 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl compound substituted at 5-position thereof with an unsaturated terminal of one (meth)acryloyl group of a compound having multiple (meth)acryloyl groups, that another 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl compound of a next unit is substituted at 5'-position thereof with an unsaturated terminal of another (meth)acryloyl group of the compound having multiple (meth)acryloyl groups so as to have a molecular weight of 1500 to 10000. The reduction catalyst comprises this polymer and a transition metal.

摘要翻译： 具有双（二苯基膦基）联萘基的聚合物，其可用作加成反应的催化剂，特别是不对称的1,4-加成反应或还原反应，特别是不对称还原反应，并且可以容易地回收和再循环 。 具有双（二苯基膦基）联萘基的聚合物是由在5-位取代的外消旋或光学活性的2,2'-双（二苯基膦基）-1,1'-联萘化合物与不饱和末端一个 具有多个（甲基）丙烯酰基的化合物的（甲基）丙烯酰基，下一单元的另一个2,2'-双（二苯基膦基）-1,1'-联萘化合物在其5'-位被不饱和 具有多个（甲基）丙烯酰基的化合物的另一（甲基）丙烯酰基的末端，以使其分子量为1500至10000.还原催化剂包含该聚合物和过渡金属。