摘要:
A negative electrode for a lithium ion secondary battery in which an electrode layer and a collector are laminated is obtained by a method comprising: mixing particles (A) composed of a substance comprising an element capable of intercalating and deintercalating lithium ions and comprising no graphite, particles (B) composed of a substance comprising graphite, carbonaceous fibers (C), and a polymer (D) comprising a polysaccharide comprising an unsubstituted or substituted glucopyranose ring or a derivative of the polysaccharide and having a viscosity in 1 mass% aqueous solution at 25°C of 300-6,000 mPa·s to obtain a granular composite in which each one of the particles (A) and each one of the carbonaceous fibers (C) have contact with each other through the polymer (D) to be integrated, thereby forming a substructure (S), at least a part of surface of each one of the particles (B) is covered with the substructure (S), and each one of the particles (B) has contact with each other through the substructure (S); mixing a liquid medium, the granular composite and a binder to obtain slurry or paste; and allowing the slurry or the paste to adhere to the collector.
摘要:
Provided is a negative electrode material for a lithium-ion secondary battery capable of providing a high capacity lithium-ion secondary battery. A negative electrode material for a lithium-ion secondary battery containing a composite (C) that contains a porous carbon (A) and a Si-containing compound (B), wherein the porous carbon (A) satisfies V 1 /V 0 > 0.80 and V 2 /V 0 when a total pore volume at the maximum value of a relative pressure P/P 0 is defined as V 0 and P 0 is a saturated vapor pressure, a cumulative pore volume at a relative pressure P/P 0 = 0.1 is defined as V 1 , and a cumulative pore volume at a relative pressure P/P 0 = 10 -7 is defined as V 2 in a nitrogen adsorption test, and has a BET specific surface area of 800 m 2 /g or more; and wherein the Si-containing compound (B) is contained in pores of the porous carbon (A).
摘要:
A negative electrode material for lithium ion secondary batteries, the negative electrode material comprising particles (A) containing an element capable of occluding/releasing lithium ions other than a carbon element; graphite particles (B) capable of occluding/releasing lithium ions and having a median value of not smaller than 1.4 and not larger than 3.0 in a number-based distribution of aspect ratios of primary particles and carbon fibers (C); wherein a three dimensional web structure is formed from one or more carbon fibers (C), the particles (A) are fusion-bonded to the structure, and the structure is fusion-bonded to at least a part of a surface of the graphite particle (B). A lithium ion secondary battery is obtained using the negative electrode material.