公开(公告)号：EP2044089A1

公开(公告)日：2009-04-08

申请号：EP07718797.9

申请日：2007-04-27

申请人： Silverbrook Research Pty. Ltd

发明人： INDUSEGARAM, Sutharsiny ,  GONZAGA, Graciel ,  VONWILLER, Simone Charlotte ,  STARLING, Scott Matthew ,  HALL, Lachlan Everett ,  RIDLEY, Damon Donald ,  SILVERBROOK, Kia

IPC分类号： C07F5/00 ,  C09B47/04 ,  G06F17/30

CPC分类号： C09B47/0678 ,  C09B47/0673 ,  C09B47/26 ,  C09B69/04 ,  C09D11/328 ,  Y10T428/24802 ,  Y10T428/24934

摘要： There is provided an IR-absorbing naphthalocyanine dye of formula (I): wherein M is Ga(A1); A1 is an axial ligand selected from -OH, halogen, -OR3, -OC(O)R4 or -O(CH2CH2O)OR6 wherein e is an integer from 2 to 10 and R6 is H, C1-8 aIkyI or C(O)C1-8 alkyl; R1 and R2 may be the some or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(RY)(RZ); R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl; RX; Ry and RZ may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-I2 aryloxy or C5-12 arylakoxy, and each B is independently selected from a base, wherein BH+ has a pKa of between 4 and 9. The dye is particularly suitable for use in IR-absorbing inkjet inks, providing compatibility with known CMYK inks together with an optimally red-shifted λmax.

摘要翻译： 提供式（I）的吸收IR的萘酞菁染料：其中M是Ga（A1）; A 1是选自-OH，卤素，-OR 3，-OC（O）R 4或-O（CH 2 CH 2 O）OR 6的轴向配体，其中e是2至10的整数并且R 6是H，C 1-8烷基或C（O ）C 1-8烷基; R1和R2可以是一些或不同的并且选自氢或C1-12烷氧基; R3选自C1-12烷基，C5-12芳基，C5-12芳基烷基或Si（Rx）（RY）（RZ）; R4选自C1-12烷基，C5-12芳基或C5-12芳基烷基; RX; Ry和RZ可以相同或不同并且选自C 1-12烷基，C 5-12芳基，C 5-12芳基烷基，C 1-12烷氧基，C 5-12 - 芳氧基或C 5-12芳基烷氧基，并且每个B独立地选自 其中BH +的pKa在4和9之间。该染料特别适用于吸收红外线的喷墨油墨，提供与已知CMYK油墨的相容性以及最佳红移λmax。

公开(公告)号：EP2170998A1

公开(公告)日：2010-04-07

申请号：EP08733467.8

申请日：2008-05-13

申请人： Silverbrook Research Pty. Ltd

发明人： STARLING, Scott Matthew ,  VONWILLER, Simone Charlotte ,  RIDLEY, Damon Donald ,  SILVERBROOK, Kia

IPC分类号： C09B47/04 ,  C07D487/22 ,  G06F17/30 ,  B41J2/005 ,  C09D11/02

CPC分类号： C07D487/22 ,  C09B47/0678 ,  C09B69/04 ,  C09D11/36 ,  Y10T428/24802

摘要： A phthalocyanine phthalocyanine salt suitable for formulation in a solvent-based or oil-based ink vehicle is disclosed. The phthalocyanine comprises one or more sulfonate groups and a counterion of at least one sulfonate group is an ammonium cation comprising at least 15 carbon atoms. Ammonium salts of sulfonated gallium naphthalocyanines exemplify such phthalocyanine salts. Formula (5)

公开(公告)号：EP2076569A1

公开(公告)日：2009-07-08

申请号：EP07800246.6

申请日：2007-09-04

申请人： Silverbrook Research Pty. Ltd

发明人： STARLING, Scott Matthew ,  VONWILLER, Simone Charlotte ,  RIDLEY, Damon Donald ,  SILVERBROOK, Kia

IPC分类号： C09B47/04 ,  G06F17/30 ,  C07D487/22 ,  C09D11/02

CPC分类号： C09B47/0678 ,  C07D487/22 ,  C09B69/02 ,  C09D11/037

摘要： An IR-absorbing phthalocyanine dye suitable for formulation in a solvent-based or oil-based ink vehicle is disclosed. The phthalocyanine comprises one or more sulfonate groups and a counterion of at least one sulfonate group is a phosphonium cation. Phosphonium salts of sulfonated gallium naphthalocyanines exemplify such dyes.

公开(公告)号：EP2307512A1

公开(公告)日：2011-04-13

申请号：EP09771832.4

申请日：2009-05-15

申请人： Silverbrook Research Pty Ltd

发明人： VONWILLER, Simone Charlotte ,  INDUSEGARAM, Sutharsiny ,  GONZAGA, Graciel ,  RIDLEY, Damon Donald ,  SILVERBROOK, Kia

IPC分类号： C09B69/04 ,  C07C215/40 ,  C09B47/04 ,  B41J2/01 ,  C07F5/00 ,  C09D11/02 ,  C09B47/30

CPC分类号： C09B47/04 ,  B41J2/1404 ,  B41J2002/14475 ,  B41J2202/03 ,  C09B47/065 ,  C09B47/0678 ,  C09B47/24 ,  C09B69/04 ,  C09D11/328 ,  Y10T428/24802

摘要： A salt of a sulfonated dye comprising an ammonium cation as a counterion. The ammonium cation comprises at least 3 hydroxyl groups. The salt is useful in reducing kogation in thermal inkjet printheads. One example of these salts is the compound of formula (II): wherein M is Ga(OH); and each of Z1+, Z2+, Z3+ and Z4+ is protonated 2,2-bis(hydroxymethyl)- 2,2',2' '-nitrilotriethanol.

公开(公告)号：EP2044088A1

公开(公告)日：2009-04-08

申请号：EP07718796.1

申请日：2007-04-27

申请人： Silverbrook Research Pty. Ltd

发明人： INDUSEGARAM, Sutharsiny ,  GONZAGA, Graciel ,  VONWILLER, Simone Charlotte ,  STARLING, Scott Matthew ,  HALL, Lauchlan, Everett ,  RIDLEY, Damon Donald ,  SILVERBROOK, Kia

IPC分类号： C07F5/00 ,  C09B47/04 ,  G06F17/30

CPC分类号： C09D11/328 ,  C09B47/24 ,  C09B69/04 ,  G06K19/06046

摘要： There is provided an aqueous formulation comprising an IR-absorbing naphthalocyanine dye of formula (II): or a salt form thereof, wherein: M is Ga(A1); A1 is an axial ligand selected from -OH, halogen, -OR3, -OC(O)R4 or -O(CH2CH2O)eR6 wherein e is an integer from 2 to 10 and R6 is H, C1-8 alkyl or C(O)C1-8 alkyl; R1 and R2 may be the same or different and are selected from hydrogen or C1-2 alkoxy; R3 is selected from C1-2 alkyl, C5-I2 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl; and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C1-12 aryloxy or C5-12 arylalkoxy. The formulation has a pH in the range of 3,5 to 7 and is particularly suitable for use as an IR- absorbing inkjet ink, providing compatibility with known CMYK, inks together with an optimally red-shifted λmax