公开(公告)号：EP1913010A1

公开(公告)日：2008-04-23

申请号：EP06792770.7

申请日：2006-08-10

申请人： Solvias AG

发明人： WEISSENSTEINER, Walter ,  WANG, Yaping ,  SPINDLER, Felix ,  PUGIN, Benoît ,  FENG, Xiangdong

IPC分类号： C07F17/02 ,  C07F19/00 ,  C07B31/00 ,  B01J31/00

CPC分类号： C07F17/02

摘要： Compounds of the formula (I) in the form of racemates, mixtures of stereoisomers or optically pure stereoisomers, formula (I), where X1 and X2 are each, independently of one another, a secondary phosphino group; R1 is a halogen atom or a substituent bound via a C atom, N atom, S atom, Si atom, a P(O) group or a P(S) group to the cyclopentadienyl ring; R2 is C1-C4-alkyl or phenyl; m is from 1 to 3 and n is 0 or from 1 to 5, are ligands for complexes of transition metals as enantioselective and homogeneous catalysts. As a result of the substitution, the conversion, the stereoselectivity and/or the configuration of the adduct formed can be influenced and optimization of catalysts can be made possible in this way.