POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY, POSITIVE ELECTRODE FOR LITHIUM ION SECONDARY BATTERY, AND LITHIUM ION SECONDARY BATTERY

    公开(公告)号:EP3799160A1

    公开(公告)日:2021-03-31

    申请号:EP20161840.2

    申请日:2020-03-09

    Abstract: A positive electrode material for a lithium ion secondary battery capable of obtaining a lithium ion secondary battery having a high discharge capacity and excellent cycle characteristics, a positive electrode for a lithium ion secondary battery using the positive electrode material, and a lithium ion secondary battery having the positive electrode are provided.
    Provided is the positive electrode material for a lithium ion secondary battery, including core particles and a carbonaceous film coating a surface of the core particles, in which in a Raman spectrum analysis of the carbonaceous film, in a case where a peak intensity of a spectrum in a wave number band of 1,200 to 1,400 cm -1 is set as D, a minimum intensity of 1,400 to 1,550 cm -1 is set as V, and a peak intensity of the spectrum of 1,550 to 1,700 cm -1 is set as G, an average D/G is 0.77 or more and 0.98 or less and an average V/G is 0.50 or more and 0.66 or less, and each of variation coefficients of D/G and V/G is 2% or less.

    POSITIVE ELECTRODE MATERIAL FOR LITHIUM-ION SECONDARY BATTERIES, POSITIVE ELECTRODE FOR LITHIUM-ION SECONDARY BATTERIES, AND LITHIUM-ION SECONDARY BATTERY

    公开(公告)号:EP3716368A1

    公开(公告)日:2020-09-30

    申请号:EP19200132.9

    申请日:2019-09-27

    Abstract: A positive electrode material for lithium-ion secondary batteries, wherein the positive electrode material includes a carbon-coatedpositive electrode active material which comprises primary particles, secondary particles, and a carbon film, wherein the primary particles and the secondary particles are coated with the carbon film, wherein the primary particles consists of a positive electrode active material in which a strain of the positive electrode active material, which is calculated by X-ray diffraction measurement, is 0.01% or higher and 0.1% or lower, and a ratio (B/A) of a crystallite diameter B (nm) of the positive electrode active material to an average primary particle diameter A (nm) of the carbon-coated positive electrode active material is 0.9 or higher and 1.5 or lower, wherein the particle diameter A is calculated from a specific surface area of the carbon-coated positive electrode active material, wherein the specific surface area is obtained using a BET method.

    POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY, POSITIVE ELECTRODE FOR LITHIUM ION SECONDARY BATTERY, AND LITHIUM ION SECONDARY BATTERY

    公开(公告)号:EP3799159A1

    公开(公告)日:2021-03-31

    申请号:EP20161805.5

    申请日:2020-03-09

    Abstract: A positive electrode material for a lithium ion secondary battery capable of obtaining a lithium ion secondary battery having a high discharge capacity and excellent cycle characteristics, a positive electrode for a lithium ion secondary battery using the positive electrode material, and a lithium ion secondary battery having the positive electrode are provided.
    Provided is the positive electrode material for a lithium ion secondary battery, including core particles and a carbonaceous film coating a surface of the core particles, in which in a Raman spectrum analysis of the carbonaceous film, in a case where a peak intensity of a spectrum in a wave number band of 1,200 to 1,400 cm -1 is set as D, a minimum intensity of 1,400 to 1,550 cm -1 is set as V, and a peak intensity of the spectrum of 1,550 to 1,700 cm -1 is set as G, an average D/G is 0.77 or more and 0.98 or less and an average V/G is 0.50 or more and 0.66 or less, and in a case where the average D/G is set as a and the average V/ G is set as b, X falls within a range of -0.1 ≤ X ≤ 0.1 in Expression X = a - 1.47b.

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