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    METHOD FOR PREPARING SOLID NITROSYL RUTHENIUM NITRATE BY USING WASTE CATALYST CONTAINING RUTHENIUM
    2.
    发明公开
    METHOD FOR PREPARING SOLID NITROSYL RUTHENIUM NITRATE BY USING WASTE CATALYST CONTAINING RUTHENIUM 有权
    VERFAHREN ZUR HERSTELLUNG VON FESTEM NITROSYL-RUTHENIUM-NITRAT MITTELS EINES RENHENIUMHALTIGEN ABFALLKATALYSATORS

    公开(公告)号：EP2823900A1

    公开(公告)日：2015-01-14

    申请号：EP13758228.4

    申请日：2013-03-04

    申请人： Sunshine Kaidi New Energy Group Co., Ltd.

    发明人： XU, Li ,  LAI, Bo ,  SONG, Dechen ,  LIU, Qianqian ,  HAN, Yiming

    IPC分类号： B09B3/00 ,  C01G55/00

    CPC分类号： C22B11/048 ,  C01G55/00 ,  C01P2006/80 ,  C22B1/005 ,  C22B7/009 ,  Y02P10/214 ,  Y02P10/234

    摘要： Disclosed is a method for preparing solid nitrosyl ruthenium nitrate by using a waste catalyst containing ruthenium. Steps of the method are: drying and calcining a waste catalyst containing ruthenium to acquire a black solid containing ruthenium, grinding the black solid containing ruthenium into powder, feeding hydrogen for reduction to form metal ruthenium, oxidizing metal ruthenium by using mixed gas of ozone and air to produce a ruthenium tetra oxide gas, collecting the gas, feeding the gas in a nitric acid solution, adding solid sodium nitrite to prepare a solution containing nitrosyl ruthenium nitrate, and finally using diethyl ether for extraction, and evaporating diethyl ether to acquire a nitrosyl ruthenium nitrate solid. The method can effectively reclaim noble metal ruthenium in various load-type waste catalysts containing ruthenium, so as to achieve effective recycling of ruthenium resources, and has simple operation steps and does not involve the introduction of ruthenium intermediates, which ensures a high product yield. The acquired solid nitrosyl ruthenium nitrate is free of halogen, has high purity, and is capable of being directly applied to the preparation of catalysts.

    摘要翻译： 公开了通过使用含有钌的废催化剂制备固体亚硝酰钌硝酸盐的方法。 该方法的步骤是：干燥和煅烧含钌的废催化剂以获得含有钌的黑色固体，将含有钌的黑色固体粉碎成粉末，将氢气还原以形成金属钌，通过使用臭氧的混合气体氧化金属钌 空气中生成四氧化钌四氧化物气体，收集气体，在硝酸溶液中加入气体，加入固体亚硝酸钠，制备含有硝酰基硝酸钌的溶液，最后用乙醚萃取，蒸发乙醚，得到 亚硝酰硝酸钌固体。 该方法可以有效地回收含有钌的各种载荷型废催化剂中的贵金属钌，从而实现钌资源的有效再循环，操作步骤简单，不需要引入钌中间体，确保了高的产率。 获得的固体亚硝酰硝酸钌不含卤素，具有高纯度，并且能够直接用于催化剂的制备。

    PROCESS FOR THE COMPREHENSIVE RECOVERY OF METAL COBALT, RUTHENIUM AND ALUMINUM FROM WASTE CATALYST CO-RU/AL2O3 IN FISCHER-TROPSCH SYNTHESIS
    3.
    发明公开
    PROCESS FOR THE COMPREHENSIVE RECOVERY OF METAL COBALT, RUTHENIUM AND ALUMINUM FROM WASTE CATALYST CO-RU/AL2O3 IN FISCHER-TROPSCH SYNTHESIS 有权
    PROCEDURE用于金属钴，钌和铝的从废催化剂CO RU / Al2O3的AT费 - 托工艺完全恢复

    公开(公告)号：EP2824200A1

    公开(公告)日：2015-01-14

    申请号：EP13758445.4

    申请日：2013-03-04

    申请人： Sunshine Kaidi New Energy Group Co., Ltd.

    发明人： LIU, Qianqian ,  HAN, Yiming ,  SONG, Dechen ,  XU, Li ,  LAI, Bo

    IPC分类号： C22B7/00

    CPC分类号： C22B23/0446 ,  C01F7/142 ,  C01G51/00 ,  C01G51/04 ,  C01G55/004 ,  C01G55/005 ,  C01P2006/80 ,  C22B7/00 ,  C22B7/009 ,  C22B11/026 ,  C22B11/04 ,  C22B11/048 ,  C22B11/06 ,  C22B21/003 ,  C22B21/02 ,  C22B23/00 ,  C22B23/026 ,  Y02P10/214 ,  Y02P10/218 ,  Y02P10/224 ,  Y02P10/234 ,  Y02P20/129 ,  Y02P20/142

    摘要： Provided is a process for the comprehensive recovery of metal cobalt, ruthenium and aluminum from a waste catalyst Co-Ru/Al 2 O 3 in a Fischer-Tropsch synthesis. First, a waste catalyst is subjected to hydrocarbon removal, and reduction treatment, to effectively separate a cobalt slag in an alkali fusion step, and then the cobalt slag is subjected to the steps of acid leaching, cobalt precipitation with oxalic acid or ammonium oxalate, reduction of cobalt oxalate, dissolution of metal cobalt with nitric acid, etc., to obtain Co(N0 3 ) 2 ·6H 2 O. A ruthenate which is dissolved by steps such as alkali fusion, and leaching with deionized water, is subjected to the steps of reduction with ethanol, dissolution with concentrated hydrochloric acid, distillation under reduced pressure, etc., to obtain a β-RuCl 3 ·xH 2 O product with a high purity. Aluminum hydroxide is prepared from a meta-aluminate solution by CO 2 carbonation, by controlling the parameters such as reaction temperature, flow rate of CO 2 , pH value at the end point of the reaction, etc., and the aluminum hydroxide is calcined to obtain aluminum oxide with a product quality achieving the quality requirements of first-class aluminum oxide in the Chinese national standard. The resulting product has a high yield, wherein cobalt is ≥ 97%, ruthenium is ≥ 95%, and aluminum is ≥ 92%.

    摘要翻译： 本发明提供用于从废催化剂共同的Ru /的Al 2 O 3在费 - 托合成金属钴，钌和铝的综合回收的方法。 首先，将废弃物催化剂进行烃脱除，和还原处理，在超过碱熔步骤有效地分离钴炉渣，然后将钴炉渣进行酸浸出，钴沉淀的步骤用草酸或草酸铵， 减少草酸盐的钴，金属钴溶解用硝酸等，以获得的Co（NO 3）2·6H 2 O的钌所有这是由溶解的步骤：如碱熔，并与去离子水沥滤，进行 在减压下等，还原用乙醇，溶解，用浓盐酸，蒸馏的步骤，以得到一个²-的RuCl 3·XH 2 O产物具有高纯度。 氢氧化铝是由偏铝溶液通过CO 2碳酸化制备，通过控制参数：如反应温度，流量的CO 2的速率，在反应中，等，且氢氧化铝的终点PH值煅烧以 获得与产品质量实现一流的氧化铝在中国国家标准的质量要求氧化铝。 所得到的产品具有高的产率，worin钴是‰¥97％，钌是‰¥95％，铝是‰¥92％。