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    Ultraviolet ray screening agent
    1.
    发明公开
    Ultraviolet ray screening agent 失效
    紫外线过滤器Mittel。

    公开(公告)号：EP0530810A2

    公开(公告)日：1993-03-10

    申请号：EP92115097.5

    申请日：1992-09-03

    申请人： TOPY INDUSTRIES LIMITED ,  SHISEIDO COMPANY LIMITED

    发明人： Takao, Yuji ,  Ando, Akitsugu ,  Kosugi, Tetsusi ,  Suzuki, Fukuji, c/o Shiseido Research Center ,  Ohno, Kazuhisa, c/o Shiseido Research Center ,  Ogawa, Katsuki, c/o Shiseido Research Center

    IPC分类号： C09C1/40 ,  C09C1/00 ,  C09C3/06

    CPC分类号： A61Q17/04 ,  A61K8/0241 ,  A61K8/11 ,  A61K8/26 ,  A61K2800/412 ,  A61K2800/61 ,  C01B33/26 ,  C01B33/42 ,  C01B33/425 ,  C01G1/06 ,  C01G49/009 ,  C01P2002/72 ,  C01P2002/84 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/60 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/00 ,  C09C1/0081 ,  C09C1/28 ,  C09C1/405

    摘要： The object of the present invention is to provide composite synthetic mica powder having excellent ultraviolet ray screening effect.
    The composite synthetic mica powder of the present invention is characterized in that a mica fine particle layer (B) containing one or more types of elements selected from a group of Te, Bi, Pb, Ce, Fe, Mo, Nb, W, Sb, Sn, V, Mn, Ni, Co, Zn and Ti is formed on the surface of scale-like mica particles (A), whereby:
       covering ratio of said particles (A) by said particles (B) is lower than or equal to 1 and higher than or equal to 0.5; and
       ratio of particle size of said particles (B) to plane direction diameter of said particles (A) is lower than or equal to 0.1, and particle size of said particles (A) is 1 to 100 µm.
    Another object of the present invention is to provide red synthetic mica, which develops light-resistant red color closer to color of human skin and ultraviolet ray, and also to provide a method for manufacturing the same and an ultraviolet ray screening agent containing said synthetic mica.
    The synthetic mica of the present invention is characterized in that, it is expressed by the following formula (I):

    X 1/3∼1 Y 2∼3 (Z₄ O₁₀) F 2×0.75∼2×0.99    (I)

    (where X represents one or more types of ions selected from a group of Na, K, Li, Ca, Rb and Sr, Y represents one or more types of ions selected from a group of Mg, Fe, Ni, Mn, Al, Li, Co, Ti and Zn, Z represents one or more types of ions selected from a group of Al, Si, Ge, Fe, B, Co and Ti, and at least one of Y and Z represents an iron ion), molar number of iron contained in said synthetic mica is 0.01 to 3 mols, and, when said synthetic mica is measured by powder cell method, its color is given by L*=55 to 75, a*=5 to 20, and b*=5 to 20 by the CIE 1976 (L*a*b*) space.

    摘要翻译： 本发明的目的是提供具有优异的紫外线屏蔽效果的复合合成云母粉末。 本发明的复合合成云母粉末的特征在于，含有选自Te，Bi，Pb，Ce，Fe，Mo，Nb，W，Sb中的一种或多种元素的云母细粒层（B） 在鳞片状云母粒子（A）的表面形成Sn，V，Mn，Ni，Co，Zn，Ti，由此，所述粒子（B）的粒子（A）的覆盖率低于或等于 至1并且高于或等于0.5; 所述粒子（B）的粒径与所述粒子（A）的面方向直径的比例小于或等于0.1，所述粒子（A）的粒径为1〜100μm。 本发明的另一个目的是提供红色合成云母，其发展更接近人体皮肤和紫外线的颜色的耐光红色，并且还提供其制造方法和含有所述合成云母的紫外线屏蔽剂 。 本发明的合成云母的特征在于其由下式（I）表示：X1 / 3类似1 Y2类似3（Z4 O10）F2x0.75类似于2x0.99（I>（其中X表示1 或更多种选自Na，K，Li，Ca，Rb和Sr的离子，Y表示选自Mg，Fe，Ni，Mn，Al，Li，Co，Ti中的一种或多种离子 Zn，Z表示选自Al，Si，Ge，Fe，B，Co和Ti中的一种或多种离子，Y和Z中的至少一个表示铁离子），所含的铁的摩尔数 所述合成云母为0.01〜3摩尔，当通过粉末电池法测定所述合成云母时，其颜色由L * = 55〜75，a * = 5〜20，b * = 5〜20 CIE 1976（L * a * b *）空间

    Ultraviolet ray screening agent
    3.
    发明公开
    Ultraviolet ray screening agent 失效
    紫外线遮蔽剂

    公开(公告)号：EP0530810A3

    公开(公告)日：1993-06-30

    申请号：EP92115097.5

    申请日：1992-09-03

    申请人： TOPY INDUSTRIES LIMITED ,  SHISEIDO COMPANY LIMITED

    发明人： Takao, Yuji ,  Ando, Akitsugu ,  Kosugi, Tetsusi ,  Suzuki, Fukuji, c/o Shiseido Research Center ,  Ohno, Kazuhisa, c/o Shiseido Research Center ,  Ogawa, Katsuki, c/o Shiseido Research Center

    IPC分类号： C09C1/40 ,  C09C1/00 ,  C09C3/06

    CPC分类号： A61Q17/04 ,  A61K8/0241 ,  A61K8/11 ,  A61K8/26 ,  A61K2800/412 ,  A61K2800/61 ,  C01B33/26 ,  C01B33/42 ,  C01B33/425 ,  C01G1/06 ,  C01G49/009 ,  C01P2002/72 ,  C01P2002/84 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/60 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/00 ,  C09C1/0081 ,  C09C1/28 ,  C09C1/405

    摘要： The object of the present invention is to provide composite synthetic mica powder having excellent ultraviolet ray screening effect. The composite synthetic mica powder of the present invention is characterized in that a mica fine particle layer (B) containing one or more types of elements selected from a group of Te, Bi, Pb, Ce, Fe, Mo, Nb, W, Sb, Sn, V, Mn, Ni, Co, Zn and Ti is formed on the surface of scale-like mica particles (A), whereby:
       covering ratio of said particles (A) by said particles (B) is lower than or equal to 1 and higher than or equal to 0.5; and
       ratio of particle size of said particles (B) to plane direction diameter of said particles (A) is lower than or equal to 0.1, and particle size of said particles (A) is 1 to 100 µm. Another object of the present invention is to provide red synthetic mica, which develops light-resistant red color closer to color of human skin and ultraviolet ray, and also to provide a method for manufacturing the same and an ultraviolet ray screening agent containing said synthetic mica. The synthetic mica of the present invention is characterized in that, it is expressed by the following formula (I): X 1/3∼1 Y 2∼3 (Z₄ O₁₀) F 2×0.75∼2×0.99    (I)
    (where X represents one or more types of ions selected from a group of Na, K, Li, Ca, Rb and Sr, Y represents one or more types of ions selected from a group of Mg, Fe, Ni, Mn, Al, Li, Co, Ti and Zn, Z represents one or more types of ions selected from a group of Al, Si, Ge, Fe, B, Co and Ti, and at least one of Y and Z represents an iron ion), molar number of iron contained in said synthetic mica is 0.01 to 3 mols, and, when said synthetic mica is measured by powder cell method, its color is given by L*=55 to 75, a*=5 to 20, and b*=5 to 20 by the CIE 1976 (L*a*b*) space.

    摘要翻译： 本发明的目的是提供具有优异的紫外线屏蔽效果的复合合成云母粉末。 本发明的复合合成云母粉末的特征在于，含有选自Te，Bi，Pb，Ce，Fe，Mo，Nb，W，Sb中的一种以上的元素的云母微粒层（B） 在鳞片状云母颗粒（A）的表面上形成Sn，V，Mn，Ni，Co，Zn和Ti，由此，所述颗粒（B）对所述颗粒（A）的覆盖率低于或等于 为1且高于或等于0.5; 所述粒子（B）的粒径与所述粒子（A）的面方向直径之比为0.1以下，所述粒子（A）的粒径为1〜100μm。 本发明的另一个目的是提供一种红色合成云母，其发出与人体皮肤和紫外线颜色接近的耐光红色，并且还提供了一种制造该合成云母的方法以及一种含有所述合成云母的紫外线屏蔽剂 。 本发明的合成云母的特征在于它由下式（I）表示：X1 / 3〜1 Y2〜3（Z 4 O 10）F2×0.75〜2×0.99（I）（其中X代表一个 或更多种选自Na，K，Li，Ca，Rb和Sr的离子，Y代表选自Mg，Fe，Ni，Mn，Al，Li，Co，Ti中的一种或多种类型的离子 Zn，Z表示选自Al，Si，Ge，Fe，B，Co和Ti中的一种或多种离子，并且Y和Z中的至少一个表示铁离子），包含在 所述合成云母为0.01〜3摩尔，使用粉末电池法测定所述合成云母时，其颜色由L * = 55〜75，a * = 5〜20，b * = 5〜20 CIE 1976（L * a * b *）空间。

    Light-responding high color-rendering makeup cosmetic preparation
    4.
    发明公开
    Light-responding high color-rendering makeup cosmetic preparation 有权
    Lichtveränderlichekosmetische化妆品Zusammensetzung mitHöherFärbekraft

    公开(公告)号：EP0998901A1

    公开(公告)日：2000-05-10

    申请号：EP99121679.7

    申请日：1999-11-02

    申请人： SHISEIDO COMPANY LIMITED

    发明人： Ogawa, Katsuki, c/o Shiseido Research Center ,  Aso, Daisuke, c/o Shiseido Research Center ,  Sakurai, Osamu, c/o Shiseido Research Center ,  Ohno, Kazuhisa, c/o Shiseido Research Center

    IPC分类号： A61K7/00 ,  A61K7/021

    CPC分类号： A61Q1/12 ,  A61K8/29 ,  A61K2800/438 ,  A61Q1/06 ,  A61Q1/10 ,  Y10S514/937

    摘要： In order to obtain a makeup cosmetic preparation having natural color-rendering property in response to intensity of surrounding light, a light-responding high color-rendering makeup cosmetic preparation of the present invention is characterized in that titanium oxide or titanium oxide compound, which has photochromic property to darken in response to intensity of irradiated ultraviolet ray, is coated on a surface of mica and metal or metal compound exists on a surface and/or inside of said photochromic titanium oxide coated mica and color of said metal or metal compound is observed as an object color, and wherein an observation color of said photochromic titanium oxide- coated mica is changed by emphasizing an interference color generated by darkening of titanium oxide layer which is made of titanium oxide or titanium oxide compound in response to irradiation of ultraviolet ray, and wherein at least one of color tone in the cosmetic preparation is given by an observation color of said observation color changeable type photochromic titanium oxide coated mica.

    摘要翻译： 为了获得具有响应于周围光的强度的自然显色性的化妆用化妆品，本发明的光反应性高的显色性化妆品化妆品的特征在于，具有氧化钛或氧化钛化合物，其具有 光致变色性能随着照射紫外线的强度而变暗，涂覆在云母表面上，金属或金属化合物的表面和/或内部存在于所述光致变色二氧化钛被覆云母上，并观察所述金属或金属化合物的颜色 作为对象颜色，并且其中所述光致变色氧化钛涂覆的云母的观察颜色通过强调由氧化钛或氧化钛化合物响应于紫外线照射而形成的氧化钛层变暗而产生的干涉色而改变， 并且其中所述化妆品中的色调中的至少一种由所述的观察颜色给出 观察颜色变化型光致变色氧化钛涂层云母。