HIGH-STRENGTH POLYAMIDE FIBER
    1.
    发明公开
    HIGH-STRENGTH POLYAMIDE FIBER 失效
    高强锦纶。

    公开(公告)号:EP0649921A1

    公开(公告)日:1995-04-26

    申请号:EP94907666.5

    申请日:1994-02-23

    摘要: To provide polyamide fibers such as polyhexamethyleneadipamide fiber having high strength and excellent strength retention after vulcanization and GY fatigue life as a rubber reinforcement. This fiber is a high-strength polyamide fiber, preferably a polyhexamethyleneadipamide fiber composed of at least 95 mol % of hexamethyleneadipamide units and having a relative viscosity in a sulfuric acid of at least 3.0, and satisfies the following requirements: (a) δΔn≧-5x10⁻³-0x10⁻³, wherein δΔn is differential birefringence, (b) Dm≧105 Å and De≧90-130 Å, wherein Dm is a longperiod in the direction of fiber axis and De is one in the direction perpendicular thereto, and (c) Tα≧125 °C, wherein Tα is a principal dispersion peak temperature in the mechanical loss factor (tan δ) curve obtained by dynamic viscoelastic measurement, and preferably satisfies further the following requirements: (d) Δn≧60x10⁻³, wherein Δn is birefringence, (e) fc≧0.88, wherein fc is degree of crystalline orientation, and (f) fa = 0.70-0.85, wherein fa is degree of non-crystalline molecule orientation.