摘要:
Provided is a nickel-containing hydroxide capable of obtaining a positive electrode active material having excellent initial charge-discharge efficiency and a high volume capacity density. The nickel-containing hydroxide for a precursor of a positive electrode active material of a non-aqueous electrolyte secondary battery, wherein when a peak intensity of a diffraction peak appearing in the range of 2θ = 19.2 ± 1 in powder X-ray diffraction measurement using CuKα rays is defined as α, and a peak intensity of a diffraction peak appearing in the range of 2θ = 38.5 ± 1 in powder X-ray diffraction measurement using CuKα rays is defined as β, the peak intensity ratio of α/β is 0.80 or more and 1.38 or less, and the average long diameter of primary particles is 290 nm or more and 425 nm or less.
摘要:
Provided is a nickel composite hydroxide that was excellent in reactivity to a lithium compound and a positive electrode active material using the nickel composite hydroxide as a precursor. The nickel composite hydroxide, having an average diameter of pores of 50 Å or larger and 60 Å or smaller in pore distribution measurement by a nitrogen adsorption method and an integrated intensity ratio of a diffraction peak appearing in a range of 2θ = 51.9 ± 1.0°/a diffraction peak appearing in a range of 2θ = 19.1 ± 1.0° in powder X-ray diffraction using CuKα rays of 0.40 or more and 0.50 or less.
摘要:
Provided is a nickel composite hydroxide capable of reducing a calcination temperature when producing a positive electrode active material, a positive electrode active material using the nickel composite hydroxide as a precursor, and a method for producing the same. The nickel composite hydroxide for a precursor of a positive electrode active material of a non-aqueous electrolyte secondary battery, wherein when in the nickel composite hydroxide, a peak intensity of a diffraction peak on a (200) plane in powder X-ray diffraction measurement using CuKα rays is defined as α, and a peak intensity of a diffraction peak on a (013) plane in powder X-ray diffraction measurement using CuKα rays is defined as β, a value of α/β is 0.75 or more and 0.95 or less, and the nickel composite hydroxide comprises Ni, Co, Mn, and one or more additive elements M selected from the group consisting of Al, Fe, Ti and Zr.
摘要:
A positive electrode active material for a lithium secondary cell, having a layered structure and comprising at least nickel, cobalt and manganese, the positive electrode active material satisfying requirements (1), (2) and (3) below: (1) a composition represented by a composition formula: Li[Li x (Ni α Co β Mn γ M δ ) 1-x ]O 2 , wherein 0 ≦ x ≦ 0.10,0.30