公开(公告)号：EP2865512B1

公开(公告)日：2016-10-19

申请号：EP15151068.2

申请日：2008-07-02

Applicant: Teijin Aramid B.V.

Inventor： Weijer De, Anton Peter ,  Van De Hee, Hendrik ,  Peters, Martinus ,  Rastogi, Sanjay ,  Wang, Bing

IPC: B29C55/00 ,  B29C55/04 ,  B29K23/00

CPC classification number: B29C55/005 ,  B29C55/04 ,  B29K2023/0683 ,  D07B1/025 ,  D07B2201/2003 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10T428/249921 ,  Y10T442/10 ,  D07B2801/10

公开(公告)号：EP2014445A1

公开(公告)日：2009-01-14

申请号：EP07013377.2

申请日：2007-07-09

Applicant: Teijin Aramid B.V.

Inventor： De Weijer, Anton Peter ,  Peters, Martinus Wilhemis Maria Gemma ,  Van de Hee, Hendrik ,  Sanjay, Rastogi ,  Wang, Bing

IPC: B29C55/00 ,  B29C55/04 ,  B29K23/00

CPC classification number: B29C55/005 ,  B29C55/04 ,  B29K2023/0683 ,  D07B1/025 ,  D07B2201/2003 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10T428/249921 ,  Y10T442/10 ,  D07B2801/10

Abstract: The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 8.
The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic modulus determined directly after melting at 160°C of at most 0.9 MPa, and a Mw/Mn ratio of at most 8 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its equilibrium melting point.
The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

Abstract translation: 本发明涉及一种UHMWPE薄膜，其拉伸强度为至少2.0GPa，拉伸断裂能至少为30J / g，Mw至少为500000克/摩尔，Mw / Mn比为 该膜可以通过以下方法制造，该方法包括使重均分子量为至少500000克/摩尔的起始UHMWPE，直接在160℃下熔化至0.9MPa的弹性模量，以及 在压缩加工过程中任何时候，将其温度升高到高于其平衡熔点的值的条件下，Mw / Mn比至多为8的压实步骤和拉伸步骤。 在高拉伸强度和高能量破裂重要性的任何应用中，该膜可用作起始材料。 合适的应用包括弹道应用，绳索，电缆，网，织物和保护性应用。

公开(公告)号：EP2865512A1

公开(公告)日：2015-04-29

申请号：EP15151068.2

申请日：2008-07-02

Applicant: Teijin Aramid B.V.

Inventor： Weijer De, Anton Peter ,  Van De Hee, Hendrik ,  Peters, Martinus ,  Rastogi, Sanjay ,  Wang, Bing

IPC: B29C55/00 ,  B29C55/04 ,  B29K23/00

CPC classification number: B29C55/005 ,  B29C55/04 ,  B29K2023/0683 ,  D07B1/025 ,  D07B2201/2003 ,  D07B2201/2009 ,  D07B2205/2014 ,  Y10T428/249921 ,  Y10T442/10 ,  D07B2801/10

Abstract: The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6.
The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160°C of at most 0.9 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point.
The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

Abstract translation: 本发明涉及一种UHMWPE薄膜，其拉伸强度为至少2.0GPa，拉伸断裂能至少为30J / g，Mw至少为500000克/摩尔，Mw / Mn比为 该膜可以通过以下方法制造，该方法包括使重均分子量为至少500000克/摩尔的起始UHMWPE，直接在160℃下熔化至0.9MPa的弹性剪切模量， 并且在这样的条件下，在聚合物的加工过程中任何时候，其温度升高到高于其熔点的值的条件下，Mw / Mn比至多为6的压实步骤和拉伸步骤。 在高拉伸强度和高能量破裂重要性的任何应用中，该膜可用作起始材料。 合适的应用包括弹道应用，绳索，电缆，网，织物和保护性应用。