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1.发明授权Gas separation processes using liquid sorbents containing bimetallic salt complexes and alkylation inhibitors for use therein 失效使用含有双金属盐复合物的液体分离器和使用其的烷基化抑制剂的气体分离方法
公开(公告)号：EP0044655B1
公开(公告)日：1983-10-05
申请号：EP81303079.8
申请日：1981-07-06
申请人： Tenneco Resins, Inc.
CPC分类号： C09K15/326 , B01D53/1493 , C07C7/152 , C07C11/04 , C07C11/06
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公开(公告)号：EP0040916B1
公开(公告)日：1983-10-12
申请号：EP81301939.5
申请日：1981-05-01
申请人： Tenneco Resins, Inc.
CPC分类号： C07C7/152 , B01D53/1493 , C07C11/06 , C07C11/04
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3.发明公开Gas separation processes using liquid sorbents containing bimetallic salt complexes and alkylation inhibitors for use therein 失效气体分离方法使用含有Bimetallsalze和Alkylierungsinhibitor用于本方法中使用的液体吸收剂。
公开(公告)号：EP0044655A1
公开(公告)日：1982-01-27
申请号：EP81303079.8
申请日：1981-07-06
申请人： Tenneco Resins, Inc.
CPC分类号： C09K15/326 , B01D53/1493 , C07C7/152 , C07C11/04 , C07C11/06
摘要： In processes in which liquid sorbents which are solutions in an aromatic hydrocarbon or halogenated aromatic hydrocarbon of a bimetallic salt complex having the generic formula M I M II X n .Aromatic, wherein M, is a Group I-B metal, M II is a Group III-A metal, X is halogen, n is the sum of the valences of M I and M II and Aromatic is a monocyclic aromatic hydrocarbon or halogenated aromatic hydrocarbon are used to separate complexible ligands from a gas feedstream which comprises an olefin having 2 or 3 carbon atoms, alkylation of the aromatic hydrocarbon or halogenated aromatic hydrocarbon is inhibited by incorporating into the liquid sorbent 8.5 to 30 mole percent, based on the Group I-B metal in the liquid sorbent, of an amine-aluminium chloride adduct, such as an ammonia-aluminium chloride adduct or a pyridine-aluminium chloride adduct.
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4.发明公开The separation of complexible ligands using alkylation inhibitors 失效Abtrennung von komplexierbaren Liganden unter Anwendung von Alkylierungsinhibitoren。
公开(公告)号：EP0040916A1
公开(公告)日：1981-12-02
申请号：EP81301939.5
申请日：1981-05-01
申请人： Tenneco Resins, Inc.
CPC分类号： C07C7/152 , B01D53/1493 , C07C11/06 , C07C11/04
摘要： In processes in which liquid sorbents which are solutions in an aromatic hydrocarbon or halogenated aromatic hydrocarbon of a bimetallic salt complex having the generic formula M I M II X n ·Aromatic, wherein M I is a Group I-B metal, M II is a Group III-A metal, X is halogen, n is the sum of the valences of M I and M II and Aromatic is a monocyclic aromatic hydrocarbon or halogenated aromatic hydrocarbon, are used to separate complexible ligands from a gas feedstream comprising an olefin having 2 or 3 carbon atoms, alkylation of the aromatic hydrocarbon or halogenated aromatic hydrocarbon is inhibited by incorporating in the liquid sorbent a small amount of zinc diphenyl or triphenylboron.
摘要翻译： 在其中液体吸附剂是具有通式MIMIIXn的双金属盐络合物的芳族烃或卤代芳族烃的溶液的方法中，其中MI是IB族金属，MII是III-A族金属，X是卤素 ，n是MI和MII的价数之和，芳族是单环芳族烃或卤代芳烃，用于从包含具有2或3个碳原子的烯烃的气体进料流中分离可络合配体，芳族烃的烷基化或 通过在液体吸附剂中掺入少量的二苯基或三苯基硼来抑制卤代芳烃。
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