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公开(公告)号：EP3224201A1
公开(公告)日：2017-10-04
申请号：EP15795083.3
申请日：2015-11-02
发明人： YUHASZ, William, M.
IPC分类号： C01G30/00 , C01G33/00 , C01G35/00 , C01G51/00 , C09C1/00 , C09C1/36 , C01G30/02 , C08K3/22 , C08K3/24
CPC分类号： C09C1/0096 , C01G30/002 , C01G30/026 , C01G33/006 , C01G35/006 , C01G51/006 , C01P2002/52 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2002/80 , C01P2002/84 , C01P2004/51 , C01P2004/61 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C04B14/30 , C04B28/02 , C04B2103/54 , C08K3/24 , C08K9/02 , C09C1/00 , C09C1/36
摘要： The present invention involves pigments derived from compounds with the LiSb0
3 -type or LiNb0
3 -type structures. These compounds possess the following formulations M
1 M
5 Z
3 , M
1 M
2 M
4 M
5 Z
6 , M
1 M
3
2 M
1 M
2 M
3 M
6 Z
6 , M
1
2 M
4 M
6 Z
6 , M
1 M
5 M
6 Z
6 , or a combination thereof. The cation M
1 represents an element with a valence of +1 or a mixture thereof, the cation M
2 represents an element with a valence of +2 or a mixture thereof, the cation M
3 represents an element with a valence of +3 or a mixture thereof, the cation M
4 represents an element with a valence of +4 or a mixture thereof, the cation M
5 represents an element with a valence of +5 or a mixture thereof, and the cation M
6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, CI, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.摘要翻译： 本发明涉及源自具有LiSbO 3型或LiNbO 3型结构的化合物的颜料。 这些化合物具有下述配方M1M5Z3，M1M2M4M5Z6，M1M32M5Z6，M1M2M3M6Z6，M12M4M6Z6，M1M5M6Z6，或它们的组合。 阳离子M1表示+1价的元素或其混合物，阳离子M2表示+2价的元素或其混合物，阳离子M3表示+3价的元素或其混合物 中，阳离子M4代表具有+4价或它们的混合物的元素，阳离子M5表示具有5价或它们的混合物的元素，并且所述阳离子M6表示具有6或一价的元素 其混合物。 阳离子M选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni，Cu，Ag，Zn，B，Al，Ga， Si，Ge，Sn，P，Sb或Te。 阴离子Z选自N，O，S，Se，Cl，F，氢氧根离子或其混合物。 除了上面提到的元素外，空位也可以位于上述配方的M或Z位置，从而保留结构类型。 上述公式还可以包括低于20原子％的M掺杂剂添加，其中掺杂剂选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr， Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni， Cu，Ag，Zn，B，Al，Ga，In，Si，Ge，Sn，P，Sb，Bi，Te或其混合物。
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公开(公告)号：EP3452550A1
公开(公告)日：2019-03-13
申请号：EP17723209.7
申请日：2017-05-02
发明人： YUHASZ, William, M.
CPC分类号： C08K3/013 , C01G51/006 , C01G53/006 , C01P2002/82 , C01P2002/84 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C08K3/01 , C09C1/00 , C09C1/0096 , C09D5/031 , C09D5/033 , C09D5/035
摘要： There are very few violet or pink colored commercial pigments that display high heat stability, resistance to acidic conditions, or good lightfastness. This technology results in pigments that fall into the above color space, but display improved chemical and weathering stability. The pigments based of this technology have the molar ratio (A2O)x(BO)y(C2O5)z(DO3)w(EO2)v, where 2x+y+2z+w+v≅100. Where A is Li or Li with one or more of Cu, Na, or K, where B is Co or Co with one or more of Ca, Cu, Fe, Mg, Mn, Ni, Sn, or Zn, where C is Nb, Sb, or combination thereof, where D is Mo, W or combination thereof, where E is Sn, Ti, Zr, or combination thereof. The above formulation may be modified with a dopant addition of Al, B, Ba, Bi, Ca, Ce, Cr, La, P, Pr, Si, Sr, Ta, V, or Y where the dopant concentration represents 5 atomic % or less of the total number of moles of components A+B+C+D+E.
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