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    MOLDED ARTICLES HAVING A SWIRL-LIKE OR MARBLE-LIKE APPEARANCE AND COMPOSITIONS FOR PRODUCING SAME
    1.
    发明公开
    MOLDED ARTICLES HAVING A SWIRL-LIKE OR MARBLE-LIKE APPEARANCE AND COMPOSITIONS FOR PRODUCING SAME 有权
    第二十旋涡或大理石相似的外观和制备组合模具

    公开(公告)号：EP2694585A1

    公开(公告)日：2014-02-12

    申请号：EP12711546.7

    申请日：2012-03-26

    申请人： Ticona LLC

    发明人： MULHOLLAND, Bruce, M.

    IPC分类号： C08L59/02 ,  C08K3/00

    CPC分类号： C08L77/06 ,  C08L59/02 ,  C08L67/02 ,  C08L67/025 ,  C08L2207/02 ,  C08L59/00

    摘要： Polymer compositions are described that contain at least two different immiscible phases for producing molded articles having a swirl-like or marble-like appearance. The first phase, for instance, may contain one or more polyoxymethylene polymers. The second phase, on the other hand, contains one or more polymers that together have a melting point that is from about 5° to about 30° different than the melting point of the polyoxymethylene polymer. In one embodiment, the second phase may contain a thermoplastic elastomer, a glycol-modified polyethylene terephthalate, or a polyamide and may have a melting point that is higher than the melting point of the polyoxymethylene polymer. The second phase is present in the polymer composition in relatively low amounts, such as in amounts less than about 5% by weight. The second phase can contain a high concentration of colorants that creates a contrast of colors when the molded article is produced.

    STABILIZED THERMOPLASTIC COPOLYESTERS
    2.
    发明公开
    STABILIZED THERMOPLASTIC COPOLYESTERS 有权
    稳定热塑性共聚酯

    公开(公告)号：EP2170987A1

    公开(公告)日：2010-04-07

    申请号：EP08770979.6

    申请日：2008-06-13

    申请人： Ticona LLC

    发明人： MULHOLLAND, Bruce, M.

    IPC分类号： C08K5/098

    CPC分类号： C08K5/3475 ,  C08K5/0008 ,  C08K5/098 ,  C08K5/17 ,  C08K5/34924 ,  D01F6/62 ,  D10B2331/04 ,  C08L67/02

    摘要： A thermoplastic copolyester composition that is able to maintain its color and mechanical strength after exposure to full weathering is provided. More specifically, a stabilizing system is employed in the composition that contains a mixture of one or more light stabilizers (e.g., hindered amines, UV absorbers, etc.), antioxidants (e.g., sterically hindered phenols, organophosphorous compounds, etc.), and secondary amines. By selectively controlling the type and concentration of the stabilizers, the present inventor has discovered that a composition may be formed that is generally resistant to color change and crazing (i.e., micro-crack formation) upon weathering. In addition to a stabilizing system, a processing stabilizer is also employed in the copolyester resin that includes a metal salt of a fatty acid having a chain length of greater than 22 carbon atoms. The present inventor has discovered that such stabilizers are particularly effective in reducing internal stresses during fiber or film formation and thereby minimizing brittleness of the resulting article. For example, a monofilament formed from the thermoplastic copolyester resin of the present invention may exhibit an elongation at break retention percentage of from about 85% to about 150% after exposure to a Xenon arc at 2000 kJ/m2 in accordance with Test Method SAE J1960.

    STABILIZED THERMOPLASTIC COPOLYESTERS
    7.
    发明授权
    STABILIZED THERMOPLASTIC COPOLYESTERS 有权
    稳定的热塑性共聚酯

    公开(公告)号：EP2170987B1

    公开(公告)日：2010-10-20

    申请号：EP08770979.6

    申请日：2008-06-13

    申请人： Ticona LLC

    发明人： MULHOLLAND, Bruce, M.

    IPC分类号： C08K5/098

    CPC分类号： C08K5/3475 ,  C08K5/0008 ,  C08K5/098 ,  C08K5/17 ,  C08K5/34924 ,  D01F6/62 ,  D10B2331/04 ,  C08L67/02

    摘要： A thermoplastic copolyester composition that is able to maintain its color and mechanical strength after exposure to full weathering is provided. More specifically, a stabilizing system is employed in the composition that contains a mixture of one or more light stabilizers (e.g., hindered amines, UV absorbers, etc.), antioxidants (e.g., sterically hindered phenols, organophosphorous compounds, etc.), and secondary amines. By selectively controlling the type and concentration of the stabilizers, the present inventor has discovered that a composition may be formed that is generally resistant to color change and crazing (i.e., micro-crack formation) upon weathering. In addition to a stabilizing system, a processing stabilizer is also employed in the copolyester resin that includes a metal salt of a fatty acid having a chain length of greater than 22 carbon atoms. The present inventor has discovered that such stabilizers are particularly effective in reducing internal stresses during fiber or film formation and thereby minimizing brittleness of the resulting article. For example, a monofilament formed from the thermoplastic copolyester resin of the present invention may exhibit an elongation at break retention percentage of from about 85% to about 150% after exposure to a Xenon arc at 2000 kJ/m2 in accordance with Test Method SAE J1960.

    摘要翻译： 提供了一种热塑性共聚多酯组合物，其能够在暴露于全风化之后保持其颜色和机械强度。 更具体地说，在含有一种或多种光稳定剂（例如，受阻胺，UV吸收剂等），抗氧化剂（例如位阻酚，有机磷化合物等）的混合物的组合物中使用稳定体系， 仲胺。 通过选择性地控制稳定剂的类型和浓度，本发明人已经发现可以形成一种组合物，该组合物通常在风化时抵抗颜色变化和龟裂（即微裂纹形成）。 除了稳定体系之外，加工稳定剂也用于包含链长大于22个碳原子的脂肪酸的金属盐的共聚酯树脂中。 本发明人已经发现，这种稳定剂在降低纤维或成膜期间的内部应力方面特别有效，并由此使得到的制品的脆性最小化。 例如，根据测试方法SAE J1960，由本发明的热塑性共聚多酯树脂形成的单丝在暴露于2000kJ / m 2的氙弧后可表现出约85％至约150％的断裂伸长率保持百分比 。