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    CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, AND PROPYLENE/ -OLEFIN COPOLYMER
    4.
    发明公开
    CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, AND PROPYLENE/ -OLEFIN COPOLYMER 审中-公开

    公开(公告)号：EP3623393A1

    公开(公告)日：2020-03-18

    申请号：EP18797548.7

    申请日：2018-04-26

    申请人： Toho Titanium Co., Ltd.

    发明人： HOSAKA Motoki ,  SUGANO Toshihiko

    IPC分类号： C08F4/654 ,  C08F10/06

    摘要： Provided is a catalyst for polymerization of an olefin which can prepare, with high productivity, a polymer having excellent hydrogen activity and high stereoregularity and MFR even in homopolymerization at a high temperature, and is also capable of producing a copolymer that achieves excellent hydrogen activity and copolymerization activity even in copolymerization at a high temperature and is excellent in impact resistance. The present invention provides a catalyst for polymerization of an olefin, comprising a compound represented by the general formula R 1 R 2 Si(NHR 3 ) 2 wherein R 1 is a cycloalkyl group having 3 to 12 carbon atoms or an aromatic hydrocarbon group having 6 to 12 carbon atoms; R 2 is a linear alkyl group having 1 to 10 carbon atoms or a branched alkyl group having 3 to 10 carbon atoms; the number of carbon atoms of R 1 is larger by 2 or more than that of R 2 ; and R 3 is a linear alkyl group having 2 to 6 carbon atoms, a branched alkyl group having 3 to 6 carbon atoms or a cycloalkyl group having 3 to 6 carbon atoms, as an external electron-donating compound.

    CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, AND PROPYLENE- -OLEFIN COPOLYMER
    6.
    发明公开
    CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, AND PROPYLENE- -OLEFIN COPOLYMER 审中-公开

    公开(公告)号：EP3689918A1

    公开(公告)日：2020-08-05

    申请号：EP18861839.1

    申请日：2018-08-10

    申请人： Toho Titanium CO., LTD.

    发明人： HOSAKA Motoki ,  SUGANO Toshihiko

    IPC分类号： C08F4/654 ,  C08F210/06

    摘要： Provided is a catalyst for polymerization of an olefin which is excellent in sustained polymerization activity in the polymerization of an α-olefin and is capable of preferably producing an α-olefin (co)polymer having high stereoregularity and MFR and favorable moldability. The present invention provides a catalyst for polymerization of an olefin, comprising: a solid catalyst component containing magnesium, titanium, halogen and an internal electron-donating compound; an organoaluminum compound; and external electron-donating compounds being of two types of alkoxysilane compounds having specific structures represented by the general formula (I) and the general formula (II), respectively, wherein the catalyst for polymerization of an olefin comprises 51 to 99% by mol of the external electron-donating compound represented by the general formula (I) and 1 to 49% by mol of the external electron-donating compound represented by the general formula (II) with respect to the total amount of both the external electron-donating compounds.

    PRODUCTION METHOD FOR SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFINS, CATALYST FOR POLYMERIZING OLEFINS, AND PRODUCTION METHOD FOR POLYMERIZED OLEFINS
    7.
    发明公开
    PRODUCTION METHOD FOR SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFINS, CATALYST FOR POLYMERIZING OLEFINS, AND PRODUCTION METHOD FOR POLYMERIZED OLEFINS 有权
    制造用于OLEFINPOLYMERSATION催化剂的固体催化剂组分用于烯烃FOR聚合的烯烃聚合和方法

    公开(公告)号：EP2963065A1

    公开(公告)日：2016-01-06

    申请号：EP14756572.5

    申请日：2014-02-13

    申请人： TOHO TITANIUM CO., LTD.

    发明人： HOSAKA Motoki ,  NAKAMURA Noriaki ,  YAMADA Shingo ,  SUGANO Toshihiko

    IPC分类号： C08F4/658 ,  C08F10/00

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F297/083 ,  C08F4/651 ,  C08F10/06 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2/001

    摘要： A method produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds into contact with each other to effect a reaction, followed by washing; a second step that brings one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction; and a third step that brings a tetravalent titanium halide compound and one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

    摘要翻译： 某一方法生成用于烯烃聚合的新型固体催化剂组分没有达到优良的烯烃聚合活性和活性随聚合期间相对于氢，并且可以在烯烃聚合物生产确实表现出高的MFR，高立构规整，和优异的刚性。 该方法包括：第一步骤做带来的镁化合物，四价钛卤化物，和一个或多个第一内给电子体化合物与海誓山盟接触以进行反应，然后洗涤; 做了第二步骤使一个或多个第二内部电子给体化合物与由第一工序中得到以实现反应的产物接触; 和第三步骤没带来的四价卤化钛化合物和一种或多种第三内部电子给体化合物与由第二步骤以实现反应而得到的产物接触。

    METHOD FOR PRODUCING PROPYLENE BLOCK COPOLYMER
    8.
    发明公开
    METHOD FOR PRODUCING PROPYLENE BLOCK COPOLYMER 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINES PROPYLENBASIERTEN BLOCKCOPOLYMERS

    公开(公告)号：EP2963064A1

    公开(公告)日：2016-01-06

    申请号：EP14756987.5

    申请日：2014-02-05

    申请人： TOHO TITANIUM CO., LTD.

    发明人： SUGANO Toshihiko ,  HOSAKA Motoki ,  UOZUMI Toshiya

    IPC分类号： C08F4/654 ,  C08F297/08

    CPC分类号： C08F210/06 ,  C08F297/08 ,  C08F210/16 ,  C08F2500/12 ,  C08F10/00 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6492 ,  C08F4/6465

    摘要： A method for producing a propylene-based block copolymer ensures excellent olefin polymerization activity and activity with respect to hydrogen (hydrogen response) during polymerization, and produces a propylene-based block copolymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes copolymerizing propylene and an α-olefin in the presence of a catalyst that includes (I) a solid catalyst component that includes titanium, magnesium, a halogen, and a compound represented by R 1 O-C(=O)-O-Z-OR 2 , and (II) a compound represented by R 3 p AlQ 3-p , to obtain a propylene-based block copolymer.

    摘要翻译： 丙烯类嵌段共聚物的制造方法在聚合过程中确保优异的烯烃聚合活性和相对于氢的氢活性（氢响应），并且产生显示高MFR，高立构规整性和优异刚性的丙烯基嵌段共聚物。 该方法包括在催化剂存在下共聚丙烯和α-烯烃，该催化剂包括（I）包含钛，镁，卤素和由R 1 OC（= O）-OZ-OR表示的化合物的固体催化剂组分 2和（II）由R 3 p AlQ 3-p表示的化合物，得到丙烯类嵌段共聚物。