公开(公告)号：EP2427508A1

公开(公告)日：2012-03-14

申请号：EP10715559.0

申请日：2010-04-29

申请人： Total Petrochemicals Research Feluy ,  Centre National de la Recherche Scientifique CNRS

发明人： PANNIER, Gaëlle ,  BOISSON, Christophe ,  SPITZ, Roger

IPC分类号： C08F210/16 ,  C08F4/02 ,  C08F4/64 ,  C08F10/00

CPC分类号： C08F210/16 ,  B01J21/08 ,  B01J31/0272 ,  B01J37/0209 ,  C08F4/659 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F4/65916 ,  C08F4/025 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/24

摘要： The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a metallic salt; IV) heating the functionalised support of step c) under an inert gas or hydrogen; V) oxidising the support of step IV by treatment under N
2 O and then under oxygen; Vl) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.

公开(公告)号：EP2328939A1

公开(公告)日：2011-06-08

申请号：EP09783634.0

申请日：2009-10-01

申请人： Total Petrochemicals Research Feluy ,  Centre National de la Recherche Scientifique (C.N.R.S)

发明人： PANNIER, Gaëlle ,  BOISSON, Christophe ,  SPITZ, Roger ,  SLAWINSKI, Martine

IPC分类号： C08F4/02 ,  C08F210/16 ,  C08F4/6592 ,  C08F4/70

CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65927 ,  C08F4/70 ,  C08F4/025 ,  C08F4/65916 ,  C08F210/14

摘要： The present invention discloses activating supports based on perfluorinated boronic acids and aluminium alkyls and their use in the activation of metallocene and post- metallocene complexes for the polymerisation of ethylene and alpha-olefins.