摘要:
An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; characterized in that the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structnre and is represented by A n+1 B n O δn+1-α F x (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; "n" is 1 or 2; "α" satisfies 0 ≤ α ≤ 3.5; and "x" satisfies 0 ≤ x ≤ 5.5) ; and the controlling portion controls charging so that a value of F/B in the cathode active material becomes more than 2/n that is in an over-charged state,
摘要:
The present invention aims to a liquid electrolyte for a fluoride ion battery having high stability with respect to a fluoride ion. The present invention attains the object by providing a liquid electrolyte for a fluoride ion battery comprising: a fluoride salt; an alkali metal amide salt having an alkali metal cation and an amide anion; and a glyme represented by general formula: R 1 -O(CH 2 CH 2 O) n -R 2 (in which R 1 and R 2 each independently represent an alkyl group with 4 or less carbon atoms or a fluoroalkyl group with 4 or less carbon atoms, and n is in the range of 2 to 10).
摘要:
The present invention aims to a liquid electrolyte for a fluoride ion battery having high stability with respect to a fluoride ion. The present invention attains the object by providing a liquid electrolyte for a fluoride ion battery comprising: a fluoride salt; an alkali metal amide salt having an alkali metal cation and an amide anion; and a glyme represented by general formula: R 1 -O(CH 2 CH 2 O) n -R 2 (in which R 1 and R 2 each independently represent an alkyl group with 4 or less carbon atoms or a fluoroalkyl group with 4 or less carbon atoms, and n is in the range of 2 to 10).
摘要:
An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; characterized in that the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structnre and is represented by A n+1 B n O ´n+1-± F x (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; "n" is 1 or 2; "±" satisfies 0 ‰¤ ± ‰¤ 3.5; and "x" satisfies 0 ‰¤ x ‰¤ 5.5) ; and the controlling portion controls charging so that a value of F/B in the cathode active material becomes more than 2/n that is in an over-charged state,
摘要:
An object of the present invention is to provide a liquid electrolyte for a lithium battery in which lowering of reactivity of a Li ion and an electrode active material due to a glyme is suppressed. In the present invention, the above object is achieved by providing a liquid electrolyte for a lithium battery comprising: a glyme represented by general formula: R 1 -O(CH 2 CH 2 O) n -R 2 (in which R 1 and R 2 each independently represent an alkyl group with 4 or less carbon atoms or a fluoroalkyl group with 4 or less carbon atoms, and n is in the range of 2 to 10); a Li amide salt having a Li ion and a sulfonylamide anion; and a fluoride salt represented by XF (in which X represents Li, Na, K, Rb, or Cs).
摘要:
A zinc anode material for secondary cells includes zinc-containing particles that are coated with a coating composition containing at least one oxide of a metal selected from titanium (Ti), zirconium (Zr), magnesium (Mg), tin (Sn) and yttrium (Y). Further, the surface localization ratio of the coating composition represented by the following Equation (1) ranges from 1.6 to 16. In Equation (1), the surface metal atomic ratio of the coating composition is represented by the following Equation (2), and the bulk metal atomic ratio of the coating composition is represented by the following Equation (3). Surface Localization Ratio of Coating Composition = Surface Metal Atomic Ratio of Coating Composition Bulk Metal Atomic Ratio of Coating Composition Surface Metal Atomic Ratio of Coating Composition = Metal Amount in Sufrace Coating Composition / mol % Metal Amount in Surface Coating Compsition + Surface Zn Amount / mol % Bulk Metal Atomic Ratio of Coating Composition = Metal Amount in Coating Composition / mol Metal Amount in Coating Composition + Zn Amount / mol