公开(公告)号：EP0402063B1

公开(公告)日：1994-09-21

申请号：EP90306009.3

申请日：1990-06-01

申请人： UBE INDUSTRIES, LTD. ,  SODA AROMATIC COMPANY, LIMITED

发明人： Yoshida, Hiroshi, c/o Ube Research Laboratory ,  Kakeya, Noboru, c/o Ube Research Laboratory ,  Kashiwagi, Masanori, c/o Ube Research Laboratory

IPC分类号： C07D307/33

CPC分类号： C07D307/33

公开(公告)号：EP0402063A3

公开(公告)日：1991-03-13

申请号：EP90306009.3

申请日：1990-06-01

申请人： UBE INDUSTRIES, LTD. ,  SODA AROMATIC COMPANY, LIMITED

发明人： Yoshida, Hiroshi, c/o Ube Research Laboratory ,  Kakeya, Noboru, c/o Ube Research Laboratory ,  Kashiwagi, Masanori, c/o Ube Research Laboratory

IPC分类号： C07D307/33

CPC分类号： C07D307/33

摘要： Disclosed are α-(ω-Cyanoalkanoyl)-γ-butyrolactone represented by the formula:
wherein n represents an integer of 7 to 11,
and a method for producing the same, which comprises reacting ω-cyano fatty acid ester represented by the formula:
NC-(CH₂) n -COOR      (II)
wherein R represents an alkyl group having 1 to 4 carbon atoms and n has the same meaning as in the above,
with γ-butyrolactone in the presence of alkali metal alcoholate represented by the formula:
R′OM      (III)
wherein R′ represents an alkyl group having 1 to 4 carbon atoms and M represents an alkali metal.

摘要翻译： 公开了由下式表示的α-（ω-氰基烷酰基）-γ-丁内酯及其制备方法，该方法包括使由下式表示的ω-氰基脂肪酸酯： 其中R表示具有1至4个碳原子的烷基，n具有与上述相同的含义的NC-（CH 2）n -COOR（II），其中γ-丁内酯在碱金属醇盐存在下由下式表示： R'OM（III）其中R'表示具有1至4个碳原子的烷基并且M表示碱金属。

公开(公告)号：EP0402063A2

公开(公告)日：1990-12-12

申请号：EP90306009.3

申请日：1990-06-01

申请人： UBE INDUSTRIES, LTD. ,  SODA AROMATIC COMPANY, LIMITED

发明人： Yoshida, Hiroshi, c/o Ube Research Laboratory ,  Kakeya, Noboru, c/o Ube Research Laboratory ,  Kashiwagi, Masanori, c/o Ube Research Laboratory

IPC分类号： C07D307/33

CPC分类号： C07D307/33

摘要： Disclosed are α-(ω-Cyanoalkanoyl)-γ-butyrolactone represented by the formula:
wherein n represents an integer of 7 to 11,
and a method for producing the same, which comprises reacting ω-cyano fatty acid ester represented by the formula:
NC-(CH₂) n -COOR      (II)
wherein R represents an alkyl group having 1 to 4 carbon atoms and n has the same meaning as in the above,
with γ-butyrolactone in the presence of alkali metal alcoholate represented by the formula:
R′OM      (III)
wherein R′ represents an alkyl group having 1 to 4 carbon atoms and M represents an alkali metal.

摘要翻译： 公开了由下式表示的α-（ω-链烷酰基）-γ-丁内酯：其中n表示7至11的整数，及其制备方法，其包括使由以下化合物表示的ω-氰基脂肪酸酯与 式中：R表示碳原子数为1〜4的烷基，n表示与上述相同的含义，在碱金属醇化物的存在下，用γ-丁内酯代替 R min OM（III）其中R min表示碳原子数为1〜4的烷基，M表示碱金属。