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1.发明授权SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES 有权分离反应产物含ORGANOPHOSPHORKOMPLEXEN的
公开(公告)号：EP1265830B1
公开(公告)日：2008-04-23
申请号：EP01918667.5
申请日：2001-03-14
发明人： ARGYROPOULOS, John, Nicholas , KANEL, Jeffrey, Scott , TULCHINSKY, Michael, Leo , MILLER, David, James , MORRISON, Donald, Lee , FOLEY, Paul , BRYANT, David, Robert , PHILLIPS, Ailene, Gardner , ROESCH, Brian, Michael , BRIGGS, John, Robert , LEE, Max, Min , MAHER, John, Michael
CPC分类号： C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：EP1360002B1
公开(公告)日：2006-12-20
申请号：EP01916655.2
申请日：2001-03-14
发明人： ARGYROPOULOS, John, Nicholas , KANEL, Jeffrey, Scott , TULCHINSKY, Michael, Leo , MILLER, David, James , MORRISON, Donald, Lee , FOLEY, Paul , BRYANT, David, Robert
IPC分类号： B01J31/00
CPC分类号： C07B63/00 , C07C67/58 , Y02P20/582 , C07C69/716
摘要： This invention relates to a process for separating one or more orgnnophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ration Ef3 which is a value greater than about 2.5.
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3.发明授权SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES 有权分离反应产物含ORGANOPHOSPHORKOMPLEXE的
公开(公告)号：EP1265831B1
公开(公告)日：2005-12-28
申请号：EP01922386.6
申请日：2001-03-14
发明人： ARGYROPOULOS, John, Nicholas , KANEL, Jeffrey, Scott , TULCHINSKY, Michael, Leo , MILLER, David, James , MORRISON, Donald, Lee , FOLEY, Paul , BRYANT, David, Robert , PHILLIPS, Ailene, Gardner , ROESCH, Brian, Michael , BRIGGS, John, Robert , LEE, Max, Min , Maher, John, Michael
CPC分类号： C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
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公开(公告)号：EP1360002A2
公开(公告)日：2003-11-12
申请号：EP01916655.2
申请日：2001-03-14
发明人： ARGYROPOULOS, John, Nicholas , KANEL, Jeffrey, Scott , TULCHINSKY, Michael, Leo , MILLER, David, James , MORRISON, Donald, Lee , FOLEY, Paul , BRYANT, David, Robert
IPC分类号： B01J31/00
CPC分类号： C07B63/00 , C07C67/58 , Y02P20/582 , C07C69/716
摘要： This invention relates to a process for separating one or more orgnnophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ration Ef3 which is a value greater than about 2.5.
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5.发明公开SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES 有权分离反应产物含ORGANOPHOSPHORKOMPLEXEN的
公开(公告)号：EP1265830A2
公开(公告)日：2002-12-18
申请号：EP01918667.5
申请日：2001-03-14
发明人： ARGYROPOULOS, John, Nicholas , KANEL, Jeffrey, Scott , TULCHINSKY, Michael, Leo , MILLER, David, James , MORRISON, Donald, Lee , FOLEY, Paul , BRYANT, David, Robert , PHILLIPS, Ailene, Gardner , ROESCH, Brian, Michael , BRIGGS, John, Robert , LEE, Max, Min , MAHER, John, Michael
CPC分类号： C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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